The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 represents an alkyl group having 1 to 22 carbon atoms, R.sup.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and “a” represents a number from 1 to 10. In the formulae (3) and (4), R.sup.8 to R.sup.11 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.12 and R.sup.13 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “b” and “c” each independently represent a number from 1 to 8, provided that at least one of R.sup.12 or R.sup.13 represents an alkyl group having 1 to 3 carbon atoms. ##STR00001##

The present invention relates to provision of an extreme pressure agent-containing grease composition using, as a thickener, a urea-based thickener, the grease composition being excellent in both torque transmitting efficiency and leakage prevention performance and also excellent in wear resistance and load resistance. The grease composition contains a base oil (A), a urea-based thickener (B), and an extreme pressure agent (C), wherein particles containing the urea-based thickener (B) in the grease composition satisfies the following requirement (I): Requirement (I): an arithmetic average particle diameter of the particles on an area basis as measured by the laser diffraction/scattering method is 2.0 μm or less, and the extreme pressure agent (C) is at least one selected from an organic metal-based extreme pressure agent, a sulfur-based extreme pressure agent, a phosphorus-based extreme pressure agent, and a sulfur-phosphorus-based extreme pressure agent.

A gear lubricant composition includes at least 97% by weight, based on the total weight of the lubricant composition, of at least one hydrocarbon-based oil that includes a weight content of isoparaffins ranging from 90 to 0%, a weight content of normal paraffins ranging from 0 to 10% and a carbon content of biological origin greater than or equal to 90% relative to the total weight of the oil, at least 0.01% by weight, based on the total weight of the lubricant composition, of at least one additive selected among the anti-wear additives, extreme pressure additives, anti-corrosion additives, additives having metal-deactivating properties, anti-foam additives, anti-oxidant additives selected among the phenolic anti-oxidants, and the mixtures thereof.

The present invention provides a lubricating oil additive, including: a molybdenum compound (A) represented by the following general formula (1); and a sulfur-based composition (B) containing a sulfur-based compound (b-1) represented by the following general formula (2) and at least one kind of sulfur-based compound (b-2) represented by the following general formula (3) or (4), and a lubricating oil composition containing the additive. In the formula (1), R.sup.1 to R.sup.4 each represent alkyl groups having 6 to 18 carbon atoms, the groups being identical to or different from each other, and X.sup.1 to X.sup.4 each independently represent an oxygen atom or a sulfur atom. In the formula (2), R.sup.5 represents an alkyl group having 1 to 22 carbon atoms, R.sup.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R.sup.7 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, and “a” represents a number from 1 to 10. In the formulae (3) and (4), R.sup.8 to R.sup.11 each represent alkylene groups having 1 to 28 carbon atoms, the groups being identical to or different from each other, R.sup.12 and R.sup.13 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and “b” and “c” each independently represent a number from 1 to 8, provided that at least one of R.sup.12 or R.sup.13 represents an alkyl group having 1 to 3 carbon atoms.

##STR00001##

A grease composition for a constant-velocity joint includes a mineral oil, a thickener, a molybdenum dithiocarbamate, a potassium borate hydrate, and a zinc dialkyldithiophosphate, wherein a content of the molybdenum dithiocarbamate is 1.2% by mass or more and 8% by mass or less, a content of the zinc dialkyldithiophosphate is 0.3% by mass or more and 2.0% by mass or less, and a content of the potassium borate hydrate is 0.28% by mass or more and 1.9% by mass or less, and wherein a mass ratio of the content of the molybdenum dithiocarbamate to the content of the potassium borate hydrate (molybdenum dithiocarbamate/potassium borate hydrate) is 2 or more and 13 or less, and a mass ratio of the content of the zinc dialkyldithiophosphate to the content of the potassium borate hydrate (zinc dialkyldithiophosphate/potassium borate hydrate) is 0.5 or more and 3.6 or less.

A lubricating composition including: a base oil, a lubricant additive composition including, as a component (A), an organic molybdenum compound of the formula (1) described in the specification, and as a component (B), an amine compound of the formula (2) described in the specification, and a specific metal-based cleaner, wherein a content of the component (B) is 2.9 to 18.6 parts by mass relative to 100 parts by mass of molybdenum atoms of the component (A), and a content of the metal-based cleaner is 0.1% to 10% by mass relative to a total amount of the lubricating composition, wherein the lubricating composition does not include tetraalkyl thiuram disulphide, and wherein the component (A) in terms of the amount of molybdenum atoms is 400 to 1200 ppm by mass relative to a total amount of the lubricating composition.

There is provided a method of planning irrigation, comprising: performing for a certain interval of time: computing a value of a crop evapotranspiration parameter indicative of an amount of water consumed by a reference crop, computing a value of a potential evapotranspiration parameter indicative of weather conditions associated with the field of the reference crop, computing a value of a dynamic crop coefficient for the reference crop based on the crop evapotranspiration parameter and the potential evapotranspiration parameter, and providing the dynamic crop coefficient computed for the certain time interval of time of the reference crop that corresponds to a target time interval of a target growing season of the target crop, wherein the target crop is growing in a target field which is geographically distinct from the reference field, and outputting instructions for irrigation of the target crop according to an irrigation plan based on the dynamic crop coefficient.

The invention provides a lubricant composition for an eccentrically oscillating speed reducer of planetary gear type, which is capable of extending the life of the speed reducer under high temperatures and keeping low input torque at low temperatures, and includes (a) a base oil containing a synthetic oil, (b) a hydrocarbon wax, and (c) at least one calcium salt selected from the group consisting of a calcium salt of petroleum sulfonic acid, a calcium salt of alkyl aromatic sulfonic acid, a calcium salt of oxidized wax, an overbasic calcium salt of petroleum sulfonic acid, an overbasic calcium salt of alkyl aromatic sulfonic acid, and an overbasic calcium salt of oxidized wax.

The present invention provides a compound represented by formula (1) (in formula (1), R.sup.1 and R.sup.2 each independently represent a group represented by formula (2) or NHR.sup.0 (where R.sup.1 and R.sup.2 are not simultaneously NHR.sup.0), R.sup.0 represents any one of hydrogen, an alkyl group having 1-20 carbon atoms, an alkenyl group having 2-30 carbon atoms, an aryl group having 6-30 carbon atoms, an alkylaryl group having 7-30 carbon atoms, and an arylalkyl group having 7-30 carbon atoms, each R.sup.3 independently represents hydrogen or a hydrocarbon group having 1-30 carbon atoms, l represents an integer of 0-4, m represents an integer of 1-4 (where m is an integer of 2-4 in the case where R.sup.1 and R.sup.2 are a group represented by formula (2)), and each n independently represents an integer of 0-4, and, in formula (2), R.sup.4 represents a hydrocarbon group having 6-24 carbon atoms, and X.sup.1 and X.sup.2 each independently represent an oxygen atom or a sulfur atom).

##STR00001##

Lubricant grease compositions comprising a silicone base stock oil having a kinematic viscosity of from 20,000 to 100,000 mm.sup.2/s at 25° C., a metal salt of a fatty acid wherein the metal is selected from the group of lithium, calcium, aluminium, barium titanium, zinc, magnesium and/or sodium; and a suitable anti-wear additive.