Provided is a water-based lubricating coating agent for a metal material, capable of carrying out a chemical conversion treatment and a lubrication treatment at the same time, which makes it possible to achieve excellent lubricity even in plastic working, press molding, and the like, and at the same time, operability (e.g., process shortening, sludge reduction). The water-based lubricating coating agent having pH of 2.0 to 6.5 for a metal material is obtained by blending: at least one lubricating component other than black-based solid lubricants; and at least one chemical conversion component selected from the group consisting of a phosphoric acid compound, an oxalic acid compound, a molybdic acid compound, a zirconium compound, and a titanium compound, the concentration of the lubricating component is 5 mass % or more in mass ratio to the total solid content mass in the lubricating coating agent, and the concentration of the chemical conversion component is 0.3 to 8 mass % when the total mass of the lubricating coating agent is regarded as 100 mass %.

The present invention provides a lubricant composition which can be washed off cold and the use thereof for application to a metal strip as anti-corrosion, wash and/or forming lubricant. The composition is 50 to 90 wt % base fluid, 3 to 15 wt % sulfonate-based corrosion inhibitor, 1 to 20 wt % ester component, 0.5 to 3 wt % phosphorus source component or 1 to 10 wt % sulfur source component as high-pressure/anti-wear additive, 1 to 15 wt % emulsifier, 0.05 to 1 wt % carboxylic acid component, 0.05 to 1 wt % aminic and/or phenolic antioxidant, 0.5 to 5 wt % wax and/or thickener component, based in each case on the total weight of the composition. Further disclosed is a dry lubricant composition which can be washed off cold.

A steel sheet having a film containing an organic resin and a wax on at least one surface of the steel sheet, in which the organic resin is at least one of an acryl-based resin, an epoxy-based resin, a urethane-based resin, a phenol-based resin, a vinyl acetate-based resin, and a polyester-based resin, in which the wax is a polyolefin wax having a melting temperature of 120? C. or higher and 140? C. or lower and an average particle size of 3.0 ?m or less, in which a proportion of the wax in the film is 10 mass % or more, and in which a coating weight per side W (g/m.sup.2) of the film and an arithmetic average roughness Ra (?m) of the steel sheet satisfy relational expression (1) below.

W?0.12?Ra.sup.2+0.2(1)

The present invention addresses the problem of providing a water-soluble cutting or grinding fluid that has excellent permeability and washability, that can be widely used in cutting or grinding, and that is particularly suitable for use in superfinishing. The present invention provides a water-soluble cutting or grinding fluid that contains a glycol compound (A), at least one substance (B) selected from the group consisting of organic amines and inorganic alkalis, a surfactant (C), and water (D), the water-soluble cutting or grinding fluid having a contact angle of 2 to 15 as measured using the /2 method one second after a drop of a dilution of the water-soluble cutting or grinding fluid is dropped on an SPCC-SB plate.

The present invention provides a lubricant composition which can be washed off cold and the use thereof for application to a metal strip as anti-corrosion, wash and/or forming lubricant. The composition is 50 to 90 wt % base fluid, 3 to 15 wt % sulfonate-based corrosion inhibitor, 1 to 20 wt % ester component, 0.5 to 3 wt % phosphorus source component or 1 to 10 wt % sulfur source component as high-pressure/anti-wear additive, 1 to 15 wt % emulsifier, 0.05 to 1 wt % carboxylic acid component, 0.05 to 1 wt % aminic and/or phenolic antioxidant, 0.5 to 5 wt % wax and/or thickener component, based in each case on the total weight of the composition. Further disclosed is a dry lubricant composition which can be washed off cold.

Provided is a grease composition which is excellent in fire extinguishing performance without water and can suppress fuming, malodor, and liquefaction on burning and a method for producing the grease composition.

A grease composition contains a base oil (A), a thickener (B), and a fire retardant (C), wherein the base oil (A) contains a base oil (A1) having a 40 C. kinematic viscosity of 300 mm.sup.2/s or more, a sulfur content of 20 ppm by mass or less, and an initial boiling point of 400 C. or higher, the fire retardant (C) is at least one of aluminum hydroxide (C1) and 1,3,5-triazine-1,3,5 (2H, 4H, 6H)-tris(ethanol) (C2), and a content of the fire retardant (C) is 1.0 to 12.0 mass % based on a total amount of the grease composition.

Disclosed herein is a method of pretreatment of a metallic substrate for a subsequent metal cold forming process. The method includes at least steps (1) and (2), namely providing at least one substrate having at least one surface at least partially made of at least one metal (step (1)), contacting the at least one surface of the substrate provided in step (1) with an aqueous lubricant composition (B) (step (2)), where the aqueous lubricant composition (B) includes besides water at least constituents (b1) to (b4) and optionally (b5).

Further disclosed herein are a pretreated metallic substrate obtained by the method, a method of cold forming of a metallic substrate, and an aqueous lubricant composition (B).

A surface treated steel strip according to the present invention includes: a base steel sheet; a zinc phosphate coating film layer made of needle zinc phosphate crystals which are formed in an island shape on a surface of the base steel sheet; and a lubricating coating film layer covering the surface of the base steel sheet and a part of the zinc phosphate coating film layer, and containing at least a lubricating component, in which an area ratio of the zinc phosphate crystals exposed from a surface of the lubricating coating film layer is 25% to 90%.

Disclosed is a metalworking oil composition containing: at least one base oil (A) selected from a mineral oil and a synthetic oil; sulfurized oils and fats (B) having a kinematic viscosity at 40 C. of 60 mm.sup.2/s or more and 1,600 mm.sup.2/s or less; and a polymer (C) of an unsaturated fatty acid having a carbon number of 10 or more.

A process for surface treatment of metal substrates, including the steps of: providing a metal substrate including hydroxyl groups at its surface; bringing the metal substrate into contact with a solution of at least one organophosphorus compound to enable the reaction of the hydroxyl groups at the surface of the metal substrate with the organophosphorus compound to form a monomolecular layer over the surface and a second layer of physisorbed organophosphorus molecules at least preponderantly crystallized, the obtained treated substrate being coated with the organophosphorus compound in the form of a first monomolecular layer coating at least 15% of the surface of the substrate and in the form of a physisorbed second layer at least preponderantly crystallized. A treated metal substrate which may be obtained by the process thereof, corresponding solution and its use for treating metallic substrates to improve their tribological properties during their shaping, in particular their stamping.