A method and apparatus for producing direct reduced iron (DRI), including: generating a reducing gas in a coal gasifier using coal, oxygen, steam, and a first coke oven gas (COG) stream as inputs to the coal gasifier; and delivering the reducing gas to a shaft furnace and exposing iron ore agglomerates to the reducing gas to form metallic iron agglomerates. The method further includes delivering a second COG stream directly to the shaft furnace.

Producing direct reduced iron (DRI) having chemically-combined carbon includes providing DRI at a temperature above 400 C., providing a first gas stream including hydrogen and carbon monoxide, passing the first gas stream through a methane forming process to yield a second gas stream containing a higher concentration of methane than the first gas stream; and contacting the second gas stream with the DRI. A system for producing the DRI includes a vessel for containing DRI at a temperature above 400 C., a methane forming reactor containing a catalyst bed for producing methane from a first gas stream containing hydrogen and carbon monoxide, a first conduit to feed a gas stream including hydrogen and carbon monoxide to the methane forming reactor, and a second conduit to feed the second gas stream to the vessel containing the DRI.

The present invention relates to a waterless system and method for cooling a metallurgical processing furnace. Supercritical carbon dioxide (sCO.sub.2) is used as a coolant, as opposed to water, which provides several advantages. For example, sCO.sub.2 can be used at higher temperatures, the risk of an explosion (with use of water) is eliminated, there are no problems with regard to reverse solubility of water at higher temperatures that can foul passageways, and smaller cooling passages can be used thus reducing the cost of cooling panels. A system is disclosed which uses a reservoir to store the sCO.sub.2, a compressor or pump to cause the delivery of the sCO.sub.2 to cooling passages in the furnace, a pressure reducing valve or a turbine to decrease the pressure of the sCO.sub.2, and a heat exchanger to cool the sCO.sub.2 to a liquid state as the sCO.sub.2 travels back to the reservoir.

A method and apparatus for producing direct reduced iron using a pre-treated make-up gas as a reducing agent in a direct reduced iron reactor are provided. The method involves pre-treating a stream of make-up gas containing heavy hydrocarbons by subjecting the stream to low temperature adiabatic reforming at a temperature between 300 C. and 600 C., prior to using the stream of make-up gas as a reducing agent for producing direct reduced iron. The method also involves adjusting the humidity content of the stream of make-up gas after the low temperature adiabatic reforming by bypassing the stream to selectively split it into a first part of the stream of make-up gas and a second part of the stream of make-up gas, subjecting the first part to water separation, and then mixing the first part with the second part to obtain a reducing stream to be sent to direct reduced iron production.

A method for operating a blast furnace for producing of pig iron, comprising the steps of including heating a stream of hydrocarbon gas and a stream of steam in a first heater to provide a heated stream of hydrocarbon gas and steam, feeding and partially reforming the heated stream of hydrocarbon gas and steam in a pre-reformer to provide a stream of partially reformed syngas, heating a first stream of blast furnace gas from the blast furnace and the stream of partially reformed syngas in a second heater, before or after their mixing together, to provide a heated carbon feed stream, reforming the heated carbon feed stream in a secondary reformer to provide a second stream of syngas, and feeding said second stream of syngas to the shaft of the blast furnace.

The present blast furnace and method for operating a blast furnace are able to reduce CO.sub.2 production and the amount of applied additives and heating material. The method for metal production of metal ores comprising the following steps: reducing a metal ore, particularly a metal oxide, and thereby producing furnace gas containing CO.sub.2 in a blast furnace shaft; discharging the furnace gas from the blast furnace shaft; directing at least a portion of the furnace gas into a CO.sub.2 converter and reducing the CO.sub.2 in the furnace gas into CO; directing at least a portion of the CO from the CO.sub.2 converter into the blast furnace shaft. The method produces CO as a gaseous reduction agent which may be easily introduced into the blast furnace shaft. Further, a blast furnace for metal production by reducing a metal ore designed for operating according to the method is described.

The disclosure relates to a process for the production of sponge iron from iron ore that includes the steps: charging iron ore into a direct reduction shaft; introducing a hydrogen-rich reducing gas into the direct reduction shaft in order to reduce the iron ore and produce sponge iron; removing a top gas from the direct reduction shaft; dividing the top gas into a recycle stream and a bleed-off stream; processing the bleed-off stream through a separation unit to provide a hydrogen-enriched off-stream and an inert-enriched off-stream; and introducing the recycle stream and the hydrogen-enriched off-stream as constituent parts of the hydrogen-rich reducing gas to the direct reduction shaft. The disclosure further relates to a system for the production of sponge iron.

A process for producing solid carbon and gaseous oxygen from CO.sub.2 via electrolysis using an electrolysis apparatus is disclosed. The apparatus includes a chamber with an electrolyte inlet, an electrolyte outlet, a liquid electrolyte containing CO.sub.2 in the chamber, at least one cathode-anode pair, with the cathode including a liquid metal capable of catalysing reduction of CO.sub.2 to solid carbon at a selected operating temperature of the process. The process includes causing the electrolyte to flow from the inlet to the outlet in fluid communication with the cathode-anode pair, applying a voltage between the cathode-anode pair and causing solid carbon to form on the cathode from CO.sub.2 in the electrolyte and gaseous oxygen to be evolved at the anode from CO.sub.2 in the electrolyte.

A process for reducing metal ore may include: carrying out a reaction between a stream of carbon dioxide and a stream of at least one hydrocarbon, at pressure greater than or equal to 0.5 atmospheres (atm) and less than or equal to 100 atm and at temperature greater than or equal to 800 C. and less than or equal to 1,350 C., to produce a reducing gaseous stream comprising at least H.sub.2, CO, CO.sub.2, and water vapor; and/or reducing at least one metal ore using the reducing gaseous stream so as to obtain at least one reduced metal material and at least one exhausted gaseous stream comprising at least CO.sub.2 and water vapor.

A method for reducing metal oxide containing charge materials (1): reducing the metal oxide containing charge materials (1) in at least two fluidized bed units (RA,RE) by means of a reduction gas (2), wherein at least some of the resulting off-gas (3) is recycled and wherein the metal oxide containing charge materials (1) are conveyed into the fluidized bed unit RE by a propellant gas. Also, apparatus for carrying out the method according to the invention is disclosed.