Provided are: a steel sheet having a high strength and excellent hydrogen embrittlement resistance; and a method of producing the same. The steel sheet has prescribed chemical composition and structure, in which a standard deviation σ of Mn concentration satisfies σ≥0.15 Mn.sub.ave (wherein, Mn.sub.ave represents an average Mn concentration) and a region with a Mn concentration of higher than (Mn.sub.ave+1.3σ) has a circle-equivalent diameter of less than 10.0 μm. The method of producing the steel sheet includes: the hot rolling step that includes finish rolling a slab having a prescribed chemical composition under prescribed conditions; the step of coiling the thus obtained hot-rolled steel sheet at a coiling temperature of 450 to 700° C.; and the step of cold rolling the hot-rolled steel sheet and subsequently annealing this steel sheet at 800 to 900° C.

Provided is a cold-rolled steel plate for hot forming, which is excellent in corrosion-resistance and spot-weldability, contains, by weight %, C: 0.1-0.4%, Si: 0.5-2.0%, Mn: 0.01-4.0%, Al: 0.001-0.4%, P: 0.001-0.05%, S: 0.0001-0.02%, Cr: 0.5% to less than 3.0%, N: 0.001-0.02%, and a balance of Fe and inevitable impurities, satisfying formula (1) below, and includes an Si amorphous oxidation layer continuously or discontinuously formed at a thickness of 1 nm-100 nm on the surface thereof. Formula (1): 1.4≤0.4*Cr+Si≤3.2 (wherein element symbols denote measurements of respective element contents by weight %).

A high-strength steel sheet for warm working having excellent warm workability, and a method for manufacturing the steel sheet. The steel sheet has a chemical composition including, by mass %, C: 0.05% to 0.20%, Si: 3.0% or less, Mn: 3.5% to 8.0%, P: 0.100% or less, S: 0.02% or less, Al: 0.01% to 3.0%, N: 0.010% or less, one or more selected from Nb: 0.005% to 0.20%, Ti: 0.005% to 0.20%, Mo: 0.005% to 1.0%, and V: 0.005% to 1.0%. The steel sheet has a microstructure including, in terms of area ratio, 10% to 60% of retained austenite, 10% to 80% of ferrite, 10% to 50% of martensite, and 0% to 5% of bainite, in which a C content in the retained austenite is less than 0.40 mass % and the average crystal grain diameter of the retained austenite, the martensite, and the ferrite is 2.0 μm or less.

A method for producing a steel material for line pipes which has a tensile strength of 570 MPa or more, a compressive strength of 440 MPa or more, and a thickness of 30 mm or more, the method including heating a steel having a specific composition to a temperature of 1000° C. to 1200° C.; performing hot rolling such that a cumulative rolling reduction ratio in a non-recrystallization temperature range is 60% or more, a cumulative rolling reduction ratio in a temperature range of (a rolling finish temperature +20° C.) or less is 50% or more, and a rolling finish temperature is the Ar.sub.3 transformation point or more and 790° C. or less; and subsequently performing accelerated cooling from a cooling start temperature of the Ar.sub.3 transformation point or more, at a cooling rate of 10° C./s or more, until the temperature of a surface of a steel plate reaches 300° C. to 500° C.

A steel sheet has a predetermined chemical composition, in which a metallographic structure in a surface layer region ranging from a surface to a position of 20 μm from the surface in a sheet thickness direction consists of ferrite and a secondary phase having a volume fraction of 1.0% to 15.0%, the metallographic structure in an internal region ranging from a position of more than 20 μm from the surface in the sheet thickness direction to a ¼ thickness position from the surface in the sheet thickness direction consists of ferrite and a secondary phase having a volume fraction of 5.0% to 25.0%, the volume fraction of the secondary phase in the surface layer region is less than the volume fraction of the secondary phase in the internal region, and in the surface layer region, the average grain size of the secondary phase is 0.5 μm to 4.0 μm, and a texture in which an X.sub.ODF{001}/{111} as the ratio of the intensity of {001} orientation to an intensity of {111} orientation in the ferrite is 0.70 to 2.50 is included.

A high-strength, manganese-containing steel, in particular for producing a flexibly rolled flat steel product in the form of a hot or cold strip, includes the following chemical composition (in wt. %): C: 0.005 to 0.6; Mn: 4 to 10; Al: 0.005 to 4; Si: 0.005 to 2; P: 0.001 to 0.2; S: up to 0.05; N: 0.001 to 0.3; with the remainder being iron including unavoidable steel-associated elements, with optional alloying of one or more of the following elements (in wt. %): Sn: 0 to 0.5; Ni: 0 to 2; Cu: 0.005 to 3; Cr: 0.1 to 4; V: 0.005 to 0.9; Nb: 0.005 to 0.9; Ti: 0.005 to 0.9; Mo: 0.01 to 3; W: 0.1 to 3; Co: 0.1 to 3; B: 0.0001 to 0.05; Zr: 0.005 to 0.5; Ca: 0.0002 to 0.1 which has a good combination of strength, expansion and deformation properties.

A press hardening steel by a thin slab and having a tensile strength of 1900 MPa or more includes following components by weight: C: 0.31-0.40%, Si: 0.36-0.44%, Mn: 1.6-2.0%, P≤0.006%, S≤0.004%, Als: 0.015-0.060%, Cr: 0.36-0.49%, Ti: 0.036-0.045% or Nb: 0.036-0.045% or V: 0.036-0.045% or a mixture of any two or more of the above in any proportion, B: 0.004-0.005%, Mo: 0.26-0.35%, and N≤0.005%. A method for producing the press hardening steel includes following steps: molten iron desulphurization; smelting and refining by an electric furnace or converter; continuous casting; descaling treatment before entering a soaking furnace; heating and soaking; high pressure water descaling before entering a rolling mill; hot rolling; cooling; coiling; austenitizing; die deforming and quenching.

In a method for producing a flat steel product made of high-strength manganese steel, a hot or cold strip is provided with an alloy composition containing (in wt %): C: 0.0005 to 0.9; Mn: 4 to 12; Al: up to 10; P: <0.1; S: <0.1; N: <0.1; the remainder being iron, including unavoidable steel-alloying elements, with optional addition of one or more of the following elements (in wt %): Si: up to 6; Cr: up to 6; Nb: up to 1; V: up to 1.5; Ti: up to 1.5; Mo: up to 3; Sn: up to 0.5; Cu: up to 3; W: up to 5; Co: up to 8; Zr: up to 0.5; Ta: up to 0.5; Te: up to 0.5, B: up to 0.15. The hot or cold strip is flexibly rolled to a final thickness at a temperature of 60° C. to below Ac3 prior to a first rolling step.

A press hardening steel by a thin slab casting and direct rolling has a tensile strength of 1500 MPa or more. The press hardening steel has a components by weight percent: C: 0.21-0.25%, Si: 0.26-0.30%, Mn: 1.0-1.3%, P≤0.01%, S≤0.005%, Als: 0.015-0.060%, Cr: 0.25-0.30%, Ti: 0.026-0.030% or Nb: 0.026-0.030% or V: 0.026-0.030%, or a mixture of two or more of the above in any proportion; B: 0.003-0.004%, and N≤0.005%. A method for producing the press hardening steel includes following steps: hot metal desulphurization; electric-furnace or converter smelting and refining; continuous casting; descaling, then entering a soaking furnace; heating and soaking; high-pressure water descaling, then entering a rolling mill; hot rolling; cooling; coiling; austenitizing; die deforming and quenching.

A roll-bonded clad metal sheet and a method for producing a roll-bonded clad metal sheet is provided. The roll-bonded clad sheet includes a metallic base material layer and a metallic cladding material layer which are joined to one another by a metallurgical bond. The metallic cladding material layer includes a nickel-based material whose chemical composition includes, in % by mass, a proportion of more than 50% of Ni and a proportion of 3.1% of Nb. The metallurgical bond is obtained by a thermomechanical rolling process including a first rolling phase for prerolling, a second rolling phase for final forming and a cooling time between the first rolling phase and the second rolling phase, wherein a final rolling temperature of the second rolling phase is set to a value equal to or less than 880 C.