Patent classifications
C21D8/1266
GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND MANUFACTURING METHOD THEREFOR
A manufacturing method of a grain-oriented electrical steel sheet according to an embodiment of the present invention includes: manufacturing a cold-rolled sheet; forming a groove in the cold-rolled sheet; removing an Fe—O oxide formed on a surface of the cold-rolled sheet; primary recrystallization annealing the cold-rolled sheet; and applying an annealing separating agent to the primary recrystallized cold-rolled sheet, and secondary recrystallization annealing it, wherein a close contacting property coefficient calculated by Formula 1 below is 0.016 to 1.13.
close contacting property coefficient (S.sub.ad)=(0.8×R)/H.sub.hill-up [Formula 1] (In Formula 1, R represents the average roughness (μm) of the surface of the cold-rolled sheet after the removing of the oxide, and H.sub.hill-up represents the average height (μm) of the hill-up present on the surface of the cold-rolled sheet after the removing of the oxide.)
ORIENTED ELECTRICAL STEEL SHEET AND MANUFACTURING METHOD THEREOF
An oriented electrical steel sheet according to an exemplary embodiment of the present invention includes C: 0.01% or less (excluding 0%), Si: 2.0%-4.0%, Mn: 0.01%-0.20%, acid soluble Al: 0.040% or less (excluding 0%), N: 0.008% (excluding 0%), S: 0.008% (excluding 0%), Se: 0.0001-0.008%, Cu: 0.002-0.1%, Ni: 0.005-0.1%, Cr: 0.005-0.1%, P: 0.005%-0.1% and Sn: 0.005%-0.20%, one or more among Sb: 0.0005%-0.10%, Ge: 0.0005%-0.10%, As: 0.0005%-0.10%, Pb: 0.0001%-0.10%, Bi: 0.0001%-0.10% and Mo: 0.001-0.1% as wt %, and consisting of the balance of Fe and other inevitable impurities, and after final secondary recrystallization, a magnetic flux density B8 is 1.92 Tesla or more.
GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND METHOD FOR MANUFACTURING SAME
This grain-oriented electrical steel sheet includes a base steel sheet, a forsterite-based primary film disposed on a surface of the base steel sheet, and a phosphate-based tension-imparting film containing no chromium, which is disposed on a surface of the primary film. In a case where a Ti content and a S content are respectively expressed as XTi and XS, by mass %, the forsterite-based primary film satisfies Expression (1) and Expression (2). A strain-introduced magnetic domain control is performed on the grain-oriented electrical steel sheet.
0.10≤XTi/XS≤10.00 Expression (1)
XTi+XS≥0.10 mass %. Expression (2)
METHOD FOR PRODUCING NON-ORIENTED ELECTRICAL STEEL SHEET
A non-oriented electrical steel sheet is produced by subjecting a steel slab containing, in mass %, C: not more than 0.0050%, Si: 1.0 to 6.5%, Mn: 0.05 to 2.0%, S: not more than 0.0050%, Al: not more than 0.01%, N: not more than 0.0050%, Ti: not more than 0.0030%, Nb: not more than 0.0030% and O: not more than 0.0050% to a hot rolling, a cold rolling and a finish annealing, the finish annealing conducted under conditions that a soaking temperature T (° C.) satisfies the following equation (1):
and an atmosphere in the finish annealing is a mixed gas composed of one or more selected from nitrogen, hydrogen and noble gas with a nitrogen content of not more than 50 vol % and a dew point of not higher than −20° C., whereby a non-oriented electrical steel sheet achieving a high magnetic flux density and a low iron loss is produced.
METHOD FOR PRODUCING GRAIN-ORIENTED ELECTRICAL STEEL SHEET
A grain oriented electrical steel sheet is produced by heating a steel slab containing, by mass %, C:0.02-0.10%, Si:2.0-5.0%, Mn:0.01-1.00%, sol. Al:0.01-0.04%, N:0.004-0.020% and S+Se:0.002-0.040% to a temperature of higher than 1280° C., and subjecting the sheet to a hot rolling, a hot-band annealing, a single cold rolling or two or more cold rollings having an intermediate annealing between each cold rolling and a primary recrystallization annealing combined with a decarburization annealing, applying an annealing separator onto a steel sheet surface, and subjecting the sheet to a finish annealing and a flattening annealing, a rapid cooling is conducted at an average cooling rate of not less than 200° C./s from 800° C. to 300° C. in the cooling process from a maximum achieving temperature in at least one annealing of the hot-band annealing and the intermediate annealing.
ELECTRICAL STEEL SHEET AND METHOD FOR MANUFACTURING SAME
This electrical steel sheet contains, as a chemical composition, by mass %, C: 0.0035% or less, Si: 2.00% to 3.50%, Mn: 2.00% to 5.00%, P: 0.050% or less, S: 0.0070% or less, Al: 0.15% or less, N: 0.0030% or less, Ni: 0% to 1.00%, Cu: 0% to 0.10%, and a remainder: Fe and impurities, in which an X-ray random intensity ratio in a {100} <011> crystal orientation on a sheet surface is 15.0 to 50.0, and magnetic flux densities in 0°, 22.5°, and 45° directions from a rolling direction each satisfy [1.005×(B.sub.50 (0°)+B.sub.50 (45°))/2≥B.sub.50 (22.5°)].
METHOD FOR PRODUCING NON-ORIENTED ELECTRICAL STEEL SHEET
A method for producing a non-oriented electrical steel sheet used as an iron core material for a motor or transformer and having excellent magnetic properties including subjecting a raw steel material including, by mass %, C: not more than 0.005%, Si: 1.0 to 5.0%, Mn: 0.04 to 3.0%, sol. Al: not more than 0.005%, P: not more than 0.2%, S: not more than 0.005%, N: not more than 0.005% and the remainder being Fe and impurities forming a hot-rolled sheet, subjecting the hot-rolled sheet to hot-band annealing and a single or two or more cold rollings including an intermediate annealing between each rolling forming a cold-rolled sheet having a final sheet thickness and subjecting the cold-rolled sheet to a finish annealing, wherein at least one pass in the final cold rolling at a friction coefficient μ of not less than 0.030 and a rolling reduction of not less than 15%.
Laser-scribed grain-oriented silicon steel resistant to stress-relief annealing and manufacturing method therefor
A laser-scribed grain-oriented silicon steel resistant to stress-relief annealing and a manufacturing method therefor. Parallel linear grooves (20) are formed on one or both sides of grain-oriented silicon steel (10) by laser etching. The linear grooves (20) are perpendicular to, or at an angle to, the rolling direction of the steel plate. A maximum height of edge protrusions of the linear grooves (20) does not exceed 5 μm, and a maximum height of spatters in etch-free regions between adjacent linear grooves (20) does not exceed 5 μm, and the proportion of an area occupied by spatters in the vicinity of the linear grooves (20) does not exceed 5%. The steel has low manufacturing costs, and the etching effect of the finished steel is retained during a stress-relief annealing process. The steel is suitable for manufacturing of wound iron core transformers.
GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND PRODUCTION METHOD THEREFOR
Provided is a grain-oriented electrical steel sheet having a film that is effective for the magnetic properties of the steel sheet and particularly effective for iron loss reduction and has favorable adhesion. In a grain-oriented electrical steel sheet, an insulating film partially enters into a steel substrate to form an anchor part, a depth of the anchor part from the surface of the steel substrate is 3.5 μm or less, and a number of neck parts of 5 μm.sup.2 or less in area is 0.06/μm.sup.2 or less and a number of neck parts of 10 μm.sup.2 to 40 μm.sup.2 in area is 0.005/μm.sup.2 or more and 0.011/μm.sup.2 or less, where each neck part is a remaining part of the insulating film on the surface of the steel substrate when peeling the insulating film from the steel substrate in a bend test for the grain-oriented electrical steel sheet.
Method of producing grain-oriented electrical steel sheet
To provide a grain-oriented electrical steel sheet that has better magnetic property than conventional ones without requiring high-temperature slab heating, in the case of not performing intermediate annealing, the hot rolled steel sheet obtained by a predetermined step is subjected to hot band annealing, and, in a heating process in the hot band annealing, heating is performed at a heating rate of 10° C./s or less for 10 sec or more and 120 sec or less in a temperature range of 700° C. or more and 950° C. or less, and in the case of performing the intermediate annealing, in a heating process in final intermediate annealing, heating is performed at a heating rate of 10° C./s or less for 10 sec or more and 120 sec or less in a temperature range of 700° C. or more and 950° C. or less.