A grain oriented electrical steel sheet includes: by mass %, 0.010% or less of C; 2.50 to 4.00% of Si; 0.0010 to 0.0100% of acid soluble Al; 0.012% or less of N; 1.00% or less of Mn; 0.02% or less of S; and a balance consisting of Fe and impurities, and has a tension-insulation coating at steel sheet surface and a SiO.sub.2 intermediate oxide film layer with an average thickness of 1.0 nm to 1.0 μm at an interface between the tension-insulation coating and the steel sheet surface. In the grain oriented electrical steel, a time differential curve f.sub.M(t) of a glow discharge optical emission spectrum of a metallic element M (Al) in the SiO.sub.2 intermediate oxide film layer satisfies a predetermined condition.

A grain-oriented electrical steel sheet according to one embodiment of the present invention includes a steel sheet and an insulation coating, in which the insulation coating contains a first metal phosphate, which is a metal phosphate of one or two more metals selected from Al, Fe, Mg, Mn, Ni, and Zn; a second metal phosphate, which is a metal phosphate of one or two more metals selected from Co, Mo, V, W, and Zr; and colloidal silica, the insulation coating does not contain chromate, and an elution amount of phosphoric acid of the insulation coating as determined by boiling the grain-oriented electrical steel sheet in a boiled pure water for 10 minutes, then measuring an elution amount of phosphoric acid into the pure water, and dividing the amount of phosphoric acid by the area of the insulation coating of the boiled grain-oriented electrical steel sheet is 30 mg/m.sup.2 or less.

Provided are: an oriented electromagnetic steel sheet with outstanding coating adhesion and magnetic properties after stress relief annealing; and a method for manufacturing the oriented electromagnetic steel sheet. The oriented electromagnetic steel sheet comprises: a steel sheet; a non-oxide ceramic coating disposed on the steel sheet and containing a non-oxide; and an insulating tensile coating disposed on the non-oxide ceramic coating and containing an oxide. The thickness of the non-oxide ceramic coating is 0.020-0.400 μm. The thickness of the insulating tensile coating is at least 1.0 μm. The chromium content on the steel plate side of the non-oxide ceramic coating is less than 25 atomic %, and the chromium content on the insulating tensile coating side of the non-oxide ceramic coating is at least 25 atomic %.

Provided is an oriented electrical steel sheet including: a forsterite film formed on one side or both sides of an oriented electrical steel sheet substrate; and a ceramic layer formed on an entire or partial region of the forsterite film. Provided is a manufacturing method for an oriented electrical steel sheet including: preparing an oriented electrical steel sheet having a forsterite film formed on one surface or both surfaces thereof; and forming a ceramic layer by spraying ceramic powder on the forsterite film.

A method for refining magnetic domains of a grain-oriented electrical steel sheet according to an exemplary embodiment of the present invention includes: a step of preparing a grain-oriented electrical steel sheet; and a step of forming a groove by irradiating a quasi-continuous laser beam of which a duty is from 98.0 to 99.9% on a surface of the grain-oriented electrical steel sheet.

A grain oriented electrical steel sheet includes: by mass %, 0.010% or less of C; 2.50 to 4.00% of Si; 0.010% or less of acid soluble Al; 0.012% or less of N; 1.00% or less of Mn; 0.020% or less of S; and a balance consisting of Fe and impurities, and has a tension-insulation coating at steel sheet surface and a SiO.sub.2 intermediate oxide film layer with an average thickness of 1.0 nm to 1.0 μm at an interface between the tension-insulation coating and the steel sheet surface. In the grain oriented electrical steel, when a surface of the intermediate oxide film layer is analyzed by an infrared reflection spectroscopy, a peak intensity I.sub.A at 1250 cm.sup.−1 and a peak intensity I.sub.B at 1200 cm.sup.−1 satisfy I.sub.B/I.sub.A≥0.010.

Disclosed is a manufacturing method for a high silicon grain oriented electrical steel sheet, the silicon content of the high silicon grain oriented electrical steel is greater than 4 wt %, comprising the steps of: (1) performing decarburization annealing of a cold-rolled steel plate; (2) allowing high silicon alloy particles in a completely solid state to collide at a high speed with the surface of the decarburization annealed steel plate to be sprayed, thus forming a high silicon alloy coating on the surface of the steel plate to be sprayed; (3) coating a release agent and drying; and (4) annealing. The manufacturing method for the high silicon grain oriented electrical steel sheet of the present invention is inexpensive, and, the high silicon grain oriented electrical steel sheet produced is of stable quality and is provided with great magnetic performance.

Provided is a method for producing a grain-oriented electrical steel sheet with which it is possible to obtain a grain-oriented electrical steel sheet exhibiting excellent magnetic properties. This method for prod producing a grain-oriented electrical steel sheet involves subjecting a surface of a grain-oriented electrical steel sheet which does not have a forsterite film thereon to a film formation treatment, and performing the film formation treatment while imparting tension to the grain-oriented electrical steel sheet which does not have a forsterite film thereon.

A grain-oriented electrical steel sheet includes: a base steel sheet including, as a chemical composition, by mass %, C: 0.010% or less, Si: 2.50% to 4.00%, Mn: 0.050% to 1.000%, S+Se: 0.005% or less in total, Sol. Al: 0.005% or less, N: 0.005% or less, Bi+Te+Pb: 0% to 0.0300% in total, Sb: 0% to 0.50%, Sn: 0% to 0.50%, Cr: 0% to 0.50%, Cu: 0% to 1.0%, and a remainder of Fe and impurities; and a tension-applying insulation coating provided on a surface of the base steel sheet, in which, on the surface of the base steel sheet, an arithmetic average roughness Ra along a rolling 90 direction that is a direction perpendicular to a rolling direction is 0.60 m or less, and when a cross section of the base steel sheet is observed along the rolling 90 direction, recessed parts having a depth of 0.1 m or more and 2.0 m or less are present on the surface of the base steel sheet in 1.0/100 m or more and 6.0/100 m or less.

An insulating coating-attached electrical steel sheet has, on at least one surface, an insulating coating including an insulating tensile coating layer A. A tension applied to the steel sheet by an insulating tensile coating layer having a coating weight of M/2 from a surface of the insulating tensile coating layer A is 0.80.sub.A or more, where M is a weight of the insulating tensile coating layer A, and .sub.A is the tension applied to the steel sheet by the insulating tensile coating layer A. The insulating coating-attached electrical steel sheet has excellent adhesion of the insulating coating. A method for manufacturing the insulating coating-attached electrical steel sheet is also provided.