C22B15/0052

Gasification or liquefaction of coal using a metal reactant alloy composition

This invention relates to a method and apparatus for gasifying or liquifying coal. In particular, the method comprises reacting a coal with a molten aluminum or aluminum alloy bath. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.

Method for obtaining non-ferrous metals, in particular black and/or raw copper, from scrap containing organic matter

A method for obtaining non-ferrous metals, in particular black and/or raw copper, from scrap containing organic matter, comprises the following steps: i) providing a melting reactor, wherein the melting reactor includes a melting region, a combustion region and a pyrolysis region; ii) supplying the melting reactor with a mixture comprising the scrap such that it first passes through the pyrolysis region and the combustion region before it reaches the melting region, and is at least partially pre-pyrolyzed and/or combusted, such that an energy-containing gas stream is formed; iii) transferring the energy-containing gas stream into a thermal post-combustion chamber, in which the energy-containing gas stream is completely combusted and thermal energy released during combustion is carried off via an energy recovery unit; and iv) melting the scrap containing organic matter at least part of which has been pre-pyrolized and/or combusted.

Method for separating copper, and nickel and cobalt

Provided is a method for separating copper from nickel and cobalt, which can efficiently and selectively separate copper from nickel and cobalt in a substance containing copper, nickel, and cobalt in a waste lithium ion battery, etc. In this method, a substance containing copper, nickel, and cobalt is sulfurated to obtain a sulfide, the obtained sulfide that contains copper, nickel, and cobalt is brought into contact with an acid solution to obtain a solid containing copper and a leachate containing nickel and cobalt. The sulfide preferably contains copper sulfide as a main component, and contains nickel metal and cobalt metal. In-addition, when bringing the sulfide into contact with the acid solution, the added amounts of the sulfide and the acid solution are preferably adjusted such that the oxidation-reduction potential of the obtained leachate is maintained at 150 mV or less where a silver/silver chloride electrode is a reference electrode.

PROCESS FOR RECOVERING LITHIUM AND TRANSITION METALS FROM WASTE CATHODE OF SPENT LITHIUM ION BATTERY
20210344058 · 2021-11-04 ·

The present invention is a process for directly recovering lithium and valuable transition metals such as cobalt, nickel and manganese from waste cathode and anode powder of spent lithium ion batteries into high grade products through a cascade reduction reaction scheme, followed by digestion and precipitation circuit using CO.sub.2 as media, and a series of physical separation procedures.

Method for recovering valuable metal
11807914 · 2023-11-07 · ·

The present invention provides a method which is capable of more strictly controlling the oxygen partial pressure required during the melting of a starting material, thereby being capable of recovering a valuable metal more efficiently. A method for recovering valuable metals (Cu, Ni, Co), said method comprising the following steps: a step for preparing, as a starting material, a charge that contains at least phosphorus (P), iron (Fe) and valuable metals; a step for heating and melting the starting material into a melt, and subsequently forming the melt into a molten material that contains an alloy and slag; and a step for recovering the alloy that contains valuable metals by separating the slag from the molten material. With respect to this method for recovering valuable metals, the oxygen partial pressure in the melt is directly measured with use of an oxygen analyzer when the starting material is heated and melted.

Gasification or Liquefaction of Coal Using a Metal Reactant Alloy Composition

This invention relates to a method and apparatus for gasifying or liquifying coal. In particular, the method comprises reacting a coal with a molten aluminum or aluminum alloy bath. The apparatus includes a reaction vessel for carrying out the reaction, as well as other equipment necessary for capturing and removing the reaction products. Further, the process can be used to cogenerate electricity using the excess heat generated by the process.

Method of continuously processing nickel-containing copper sulphide materials

A method of continuously processing nickel-containing copper sulphide materials into blister copper, waste slag, and copper-nickel alloy includes oxidizing smelting along with SiO2 and CaO-containing fluxes and coal in a conversion furnace for conversion to produce blister copper, gases with concentration of SO.sub.2, and slag with an SiO2:CaO concentration ratio of 0.4:1 to 3:1, in which the sum of the iron, nickel, and cobalt is not more than 30 wt. %, at a specific oxygen consumption in the range of 150-240 Nm.sup.3 per ton of dry sulphide material, and depleting the slag in a separate reduction furnace, using a mixture of an oxygen-containing gas and a hydrocarbon fuel at an oxygen consumption coefficient (α) in a range of 0.5 to 0.9, while supplying coal in an amount of up to 15% of weight of the slag produced by the oxidizing smelting, to produce a waste slag and a copper-nickel alloy.

System and method for recovering sulfur in copper smelting process

A system and method for recovering sulfur in a copper smelting process includes removing fine dust from high-concentration SO.sub.2 flue gas from a matte smelting furnace, introducing the flue gas into a fluidized bed carbothermic reduction tower to be reduced by a carbon-based reducing agent to obtain reducing gas, passing the reducing gas through a high temperature separator to separate down unsaturated powder coke contained in the reducing gas, and condensing the reducing gas to obtain sulfur. The saturated powder coke entrained in the reducing gas enters a desorption tower to desorb SO.sub.2 gas therein, and the desorbed powder coke enters a fluidized bed sulfur reduction tower to continue to participate in the reduction reaction. Part of the SO.sub.2 gas discharged from the desorption tower is discharged to the fluidized bed carbothermic reduction tower to produce sulfur, and the other part enters a desulfurization tower.

SYSTEM AND METHOD FOR RECOVERING SULFUR IN COPPER SMELTING PROCESS

A system and method for recovering sulfur in a copper smelting process, in which fine dust is removed from high-concentration SO.sub.2 flue gas from a matte smelting furnace, the flue gas is introduced into a fluidized bed carbothermic reduction tower and reduced by a carbon-based reducing agent to obtain reducing gas, which is introduced into a high temperature separator. The separated reducing gas contains unsaturated powder coke, and the reducing gas is condensed to obtain sulfur. The saturated powder coke entrained enters a desorption tower to desorb SO.sub.2 gas, and the desorbed powder coke enters a fluidized bed sulfur reduction tower. Part of the SO.sub.2 gas discharged from the desorption tower is discharged to the fluidized bed carbothermic reduction tower to produce sulfur, and the other part is introduced into a desulfurization tower.

METHOD FOR SEPARATING COPPER, AND NICKEL AND COBALT

Provided is a method for separating copper from nickel and cobalt, which can efficiently and selectively separate copper from nickel and cobalt in a substance containing copper, nickel, and cobalt in a waste lithium ion battery, etc. In this method, a substance containing copper, nickel, and cobalt is sulfurated to obtain a sulfide, the obtained sulfide that contains copper, nickel, and cobalt is brought into contact with an acid solution to obtain a solid containing copper and a leachate containing nickel and cobalt. The sulfide preferably contains copper sulfide as a main component, and contains nickel metal and cobalt metal. In-addition, when bringing the sulfide into contact with the acid solution, the added amounts of the sulfide and the acid solution are preferably adjusted such that the oxidation-reduction potential of the obtained leachate is maintained at 150 mV or less where a silver/silver chloride electrode is a reference electrode.