The present invention discloses polythiol compositions containing monothiotricyclodecenes, dithiotricyclodecanes, and intermolecular sulfide compounds, as well as mining chemical collector compositions containing such polythiol compositions. Flotation processes for recovering metals, such as copper and molybdenum, from ores using the mining chemical collector compositions also are disclosed.

The present disclosure discloses a system for preparing new energy NiCoMn raw material from laterite nickel Ore. The system includes a raw auxiliary material supply module, a leaching reaction module, a neutralization and purification module, a neutralization and purification module, a NiCoMn mixed hydroxide synthesis module, a valuable metal recovery module, a crystal manufacturing module, a ternary precursor manufacturing module, and a ternary positive material manufacturing module. The present disclosure overcomes the defects of prior art and process, and is a green technology and process for simultaneous extraction of nickel, cobalt and manganese from low-grade laterite nickel ore, which not only realizes simultaneous and efficient extraction of nickel, cobalt and manganese, but also adopts energy-saving and emission reduction green technology and clean production technology to effectively recycle and safely dispose of waste water, waste residue and waste gas.

A method and apparatus are presented for recovering a target metal from a feed material. The method includes: contacting the feed material with a lixiviant adapted to leach target metal from a feed material feed stream in a leaching circuit having a plurality of leaching vessels V1, V2, Vn in series, establishing a countercurrent flow in the leaching circuit by delivering feed material feed stream to leaching vessel V1 and moving the feed material feed stream through the leaching circuit in a first direction toward leaching vessel Vn and delivering the lixiviant to the leaching vessel Vn and moving the lixiviant through the leaching circuit in a second direction toward leaching vessel V1, determining, by a controller, a reagent consumption rate for each of the leaching vessels V1, V2, Vn so as to validate performance, minimize left over reagent discharged from leaching vessel V1 and maximize target metal recovery from leaching vessel Vn and recovering the target metal from the lixiviant.

The present disclosure relates to the use of carbonaceous matter and a reagent comprising a thiocarbonyl functional group, for example, in a method for extracting a base metal such as copper from a material comprising the base metal. Such methods can comprise contacting the material under acidic conditions with the carbonaceous matter and the reagent comprising the thiocarbonyl functional group; and optionally recovering the base metal.

This method for leaching an electrode material is a method for subjecting an electrode material of a lithium ion secondary battery to acid leaching, the method including a leaching step of reacting the electrode material of a lithium ion secondary battery with sulfuric acid to obtain a leachate in which metals contained in the electrode material are leached, in which the leaching step includes a sulfuric acid adding step of adding the sulfuric acid to the electrode material to obtain a sulfuric acid-added electrode material, a kneading step of kneading the sulfuric acid-added electrode material to form a leaching paste, and a diluting step of diluting the leaching paste with water.

A method for recovering components of an energy storage device includes leaching a black mass recovered from the energy storage device using an acid to form an acidic aqueous solution; filtering insoluble components from the acid aqueous solution; increasing the pH of the acidic aqueous solution within a range of 7 to 9 using a base to precipitate tungsten hydroxide; filtering the tungsten hydroxide to provide a filtered aqueous solution; increasing the pH of the filtered aqueous solution to within a range of 9 to 10 to precipitate lithium hydroxide; and filtering the lithium hydroxide from the aqueous solution.

A process for leaching minerals that contain metal sulphides and one or more precious metals or precious metal compounds, the process comprising the steps of a first leaching step to leach the minerals under oxidative conditions at a pH of less than 4 to form a slurry or pulp, the slurry or pulp comprising a solid phase containing unreacted components, solid reaction products and elemental sulphur, and subjecting the slurry or pulp or solid residue from the first leaching step to a second leaching step comprising oxidative leaching at pH of at least 9.0 to thereby form thiosulphate, whereby the thiosulphate leaches precious metal from the solid residue.

A process for separating one or more elements among the rare-earth elements from other metals in columns 4 to 14 of the Periodic Table of the Elements, in admixture in aqueous solution. The process uses a polyethyleneimine-CS2 adduct in the form of a salt and involves liquid/solid separation to obtain a solid predominantly containing the rare-earth elements.

Methods are provided for removing impurities from recycled battery black mass. The method includes mixing a delithiated black mass with a first solution to form a pre-leached delithiated black mass and a pre-leach solution, separating the pre-leached delithiated black mass from the pre-leach solution, mixing the separated pre-leached delithiated black mass and a second aqueous solution to form a mixture comprising graphite and a leachate solution, and separating the graphite and the leachate solution. The pre-leach solution is comprised of a first group of impurity ions while the leachate solution is comprised of a second group of impurity ions and cathode metal ions.

An oxidative bioleaching process for leaching a base metal from an ore that includes an ore agglomeration step, an ore stacking step wherein agglomerated ore is stacked to form a heap, a curing step, a rinse step, an inoculation step and a leach step, and wherein, during the ore agglomeration step, the ore is contacted with an acid solution containing nitrate or nitrite thereby to accelerate the leaching rate in the leach step.