This invention provides a method for shortening operation shutdown time of high pressure acid leach equipment in a hydrometallurgical process, wherein the high pressure acid leach equipment comprises (i) means to transfer an ore slurry into the high pressure acid leach equipment;(ii) means to increase temperature and pressure of an ore slurry before leaching; (iii) means to add sulfuric acid into the high pressure acid leach equipment and to leach the ore slurry to obtain a leached slurry at high temperature under high pressure; (iv) means to adjust the pressure of the leached slurry; and (v) means to discharge the leached from the high pressure acid leach equipment; wherein, upon operation shutdown of the high pressure acid leach equipment, the leached slurry is subjected to self-circulation inside the high pressure acid leach equipment.

Provided is a method for inhibiting extractant degradation in the DSX process through the manganese extraction control, the method comprising: (a) stirring DSX solvent and DSX feed solution, which is a solution containing a valuable metal from which iron has been removed in an agitator, in which soda ash (Na.sub.2CO.sub.3) is further added to maintain a constant pH; and (b) scrubbing the manganese from the DSX solvent, extracted in step (a).

Disclosed is a method for anaerobically cracking a power battery, which includes the following steps: disassembling a waste power battery to obtain a battery cell; taking out a diaphragm from the battery cell for later use, and pyrolyzing the battery cell to obtain electrode powder; extracting nickel, cobalt and manganese elements from the electrode powder with an extraction buffer, filtering, taking the filtrate, then adjusting the filtrate with a nickel solution, a cobalt solution and a manganese solution to obtain a solution A, adding the solution A dropwise into ammonium hydroxide under stirring, and then adding an alkali solution under stirring to obtain a solution B; subjecting the solution B to a hydrothermal reaction, filtering, and roasting to obtain a catalyst, such that a chemical formula of the catalyst is Ni.sup.2+.sub.1-x-yCo.sup.2+.sub.xMn.sup.2+.sub.yO, where 0.25≤x<0.45, 0.25≤y<0.45.

A manganese-lithium separation process and a pre-extraction solution preparation process in comprehensive recovery of ternary battery wastes, and a method for comprehensive recovery of cobalt, nickel, manganese and lithium elements from the ternary battery wastes, relates to a method for recycling battery wastes. According to the present disclosure, cobalt and nickel ions are separated from an impurity-removed solution by a hydrolysis method; manganese, lithium and other ions in the impurity-removed solution are free from an extraction procedure, so that most manganese ions are separated and removed by a wet method before extraction, to prevent the manganese ions from entering the extraction system; nickel ions are free from an extraction procedure of full extraction and full back-extraction; and nickel hydroxide is directly precipitated after related impurities are removed by extraction.

A method of manufacturing a cobalt-nickel-containing solution including: preparing a crude nickel hydroxide and/or a crude cobalt hydroxide as a starting material, the crude nickel or cobalt hydroxide containing cobalt and nickel and elements except the cobalt and nickel as impurities, the crude nickel hydroxide containing the nickel more than the cobalt, and the crude cobalt hydroxide containing the cobalt more than the nickel; a water-washing process for obtaining a post-water-washing crude hydroxide from the starting material; a leaching process for obtaining a post-leaching solution from the post-water-washing crude hydroxide; a neutralization process of subjecting the post-leaching solution to neutralization and solid-liquid-separation to remove the impurities as a post-neutralization residue containing one or more of iron, silicon, aluminum, and chromium, thereby obtaining a post-neutralization solution; and an extraction process of subjecting the post-neutralization solution to solvent extraction to obtain a post-extraction solution containing cobalt and nickel with the impurities reduced.

There is provided a process for treating particulate scrap material. The process includes emplacing the particulate scrap material and a reagent material within a calcining zone with effect that a reactive process is effected such that a calcined metal material product is obtained, and carbonylating a carbonylation precusor material with effect that a carbonylated product is obtained, wherein the carbonylation precursor material is derived from the calcined metal material product.

A process for removal of aluminium and iron in the recycling of rechargeable batteries comprising providing a leachate from black mass, adding phosphoric acid (H.sub.3PO.sub.4) to said leachate and adjusting the pH to form iron phosphate (FePO.sub.4) and aluminium phosphate (AlPO.sub.4), precipitating and removing the formed FePO.sub.4 and AlPO.sub.4, and forming a filtrate for further recovery of cathode metals, mainly NMC-metals and lithium.

The present invention describes systems and methods of a novel hydrometallurgical process to perform reductive-acid leaching and separation of constituent compounds from solid material generated from the electrodes of lithium-ion batteries, or other source material containing target high-value materials. The process method involves the initial reductive-acid leaching with sulfur dioxide and sulfuric acid of the source material which may be performed in a single or a multi-step embodiment. In a single-step embodiment, the reductive-acid leaching results in two outlet streams, a leachate solution and a bulk solid, such as graphite. In a two-step embodiment, a dilute reductive-acid leaching results in a lithium brine that may be bled as a product stream. The resulting liquor, or leachate, can be subjected to precipitation and oxidation steps to remove other compounds except, for example lithium, cobalt, and nickel. Electrowinning may then be used to separate and recover cobalt and nickel alloys among other high value compounds from a lithium brine.

Provided is a method for leaching nickel from a nickel oxide ore that enables a nickel sulfate production method which is easily carried out with a small amount of waste generation. The method for leaching nickel into an organic phase disclosed here includes the step of bringing a nickel ore into contact with an organic phase. The organic phase contains a hydrophobic deep eutectic solvent including a hydrogen bond donor and a hydrogen bond acceptor, and an organic acid. The hydrogen bond donor is an acidic hydrogen bond donor. The organic acid is a strong acid.

Process for the recovery of transition metal from cathode active materials containing nickel and lithium, wherein said process comprises the steps of (a) treating a lithium containing transition metal oxide material with a leaching agent (preferably an acid selected from sulfuric acid, hydrochloric acid, nitric acid, methanesulfonic acid, oxalic acid and citric acid), (b) adjusting the pH value to 2.5 to 8, and (c) treating the solution obtained in step (b)with metallic nickel, cobalt or manganese or a combination of at least two of the foregoing.