Patent classifications
C22B34/345
LEACHING AGENT COMPOSITION AND METHOD OF REMOVING METAL FROM CATALYST MATERIAL
A leaching agent composition, and a method of using the leaching acid composition to remove metal from catalyst material, are provided in which the leaching agent composition comprises oxidized disulfide oil (ODSO). Active phase metals and/or contaminant metals are removed, for example after typical oil removal and drying steps. Advantageously, ODSO, which is derived from a refinery waste stream, is used to replace and/or supplement commonly used leaching acid such as sulfuric or nitric acid to remove metals used in catalyst preparation or contaminant metals deposited onto the catalyst surface.
Method of separating and recovering valuable metal from remanufacturing solution of spent desulfurization catalyst containing vanadium
The disclosure describes a method of separating and recovering valuable metals from remanufacturing solution of a spent desulfurization catalyst containing vanadium, and more particularly, to a method of separating and recovering a valuable metal from remanufacturing solution of a spent desulfurization catalyst containing vanadium, which includes: adding organic acid to a spent hydrodesulfurization catalyst after collecting the spent hydrodesulfurization catalyst in order to prepare the remanufacturing solution of the spent hydrodesulfurization catalyst; adding an extracting agent and a diluent to the remanufacturing solution to extract molybdenum and extracting vanadium from an extracted filtrate to obtain an organic phase; and adding a stripping agent to the organic phase to strip and recover vanadium.
METHOD FOR RECOVERING VALUABLE METALS FROM SPENT CATALYSTS
A method for recovering valuable metals is disclosed. The method includes: a spent catalyst preparation step in which a spent catalyst is prepared; and a leaching step in which a first inorganic compound containing VO.sub.3.sup. is leached from the spent catalyst at a temperature of less than 100 C. under normal pressure.
Methods for reprocessing used catalysts
The following invention relates to methods for reprocessing SCR catalysts. In a first embodiment, the invention relates to a method for reprocessing SCR catalysts, wherein an oxygen-containing compound of titanium and tungsten or molybdenum is removed from the catalyst and is then reacted with a vanadium compound. In a second embodiment, the invention relates to a method for removing titanium oxide and vanadium, molybdenum, and tungsten compounds from SCR catalysts and to a method for reusing these compounds in such catalysts.
METHODS FOR REPROCESSING USED CATALYSTS
The following invention relates to methods for reprocessing SCR catalysts. In a first embodiment, the invention relates to a method for reprocessing SCR catalysts, wherein an oxygen-containing compound of titanium and tungsten or molybdenum is removed from the catalyst and is then reacted with a vanadium compound. In a second embodiment, the invention relates to a method for removing titanium oxide and vanadium, molybdenum, and tungsten compounds from SCR catalysts and to a method for reusing these compounds in such catalysts.
Process for the selective recovery of transition metals from organic residues
There is a process for the selective recovery of transition metals from an organic stream containing transition metals. The organic stream and possibly a first extractor if solid, are melted up to the liquid state. The extractor consists of an ionic liquid or a mixture of two or more ionic liquids and the ionic liquid contains an ammonium salt as cation and as anion an anion with chelating properties. A melted organic stream and a first extractor, optionally melted, are fed to a first liquid-liquid extraction unit working at a temperature of at least 150 C. where the liquid-liquid extraction is carried out obtaining a liquid mixture containing an ionic liquid, or a mixture of two or more ionic liquids, and metals. After extraction, the liquid mixture is cooled at a temperature between 0 C. and 70 C. and becomes biphasic; then the cooled mixture is sent to a first separation unit, to separate a liquid phase that contains ionic liquids and metals, and a metal-depleted solid phase. After the first separation, the separated metal-depleted solid phase is optionally sent to a washing unit to which a solvent is fed, so as to eliminate the residual ionic liquid by transferring it into the solvent and obtaining a metal-depleted solid phase. Then the separate liquid phase containing ionic liquids and metals is sent into a liquid-liquid precipitation and separation unit, adding a counter-solvent, thereby obtaining a solid phase containing the metals and a liquid stream containing counter-solvent and ionic liquids.