A 3D printing method for an impact-resistant gradient complex part containing a hollow ceramic sphere complex, wherein the method includes the following steps: 1) designing the size and shape of the part as well as an internal layered structure; 2) providing a raw material, wherein the raw material contains a high polymer, a curing agent and hollow ceramic spheres; and 3) providing the raw material with a certain thickness according to a design, then, curing the raw material by using a heat source to form a high polymer layer containing the hollow ceramic spheres, and repeatedly printing the high polymer layer according to the design until the high polymer layer reaches the designed thickness to form the impact-resistant gradient complex part.

An object of the present invention is to provide an additive manufactured object which is free of solidification cracking due to, e.g., heat shrinkage during additive manufacturing of an aluminum alloy; which is free of anisotropy in strength, and has high strength and ductility. An aluminum alloy powder for additive manufacturing includes aluminum alloy particles in which not less than 0.01% by mass and not more than 1% by mass of a grain refiner is trapped. This grain refiner is at least one selected from the borides and carbides of group 4 elements.

An aluminum alloy powder for laser laminated manufacturing includes Si: 2.0-4.5 wt %; Mg: 0.1-1.3 wt %; Fe: 0.07-0.65 wt %; Cu: 0.35 wt % or less; Cr: 0.02-0.32 wt %; Zn: 0.23 wt % or less; Ti: 0.23 wt % or less; Mn: 0.13 wt % or less; and the rest is aluminum. The aluminum alloy powder further includes inevitable impurities.

A composite structure with an aluminum-based alloy layer containing boron carbide and a manufacturing method thereof are provided. The composite structure includes a substrate with an open hole in that surface and the aluminum-based alloy layer containing boron carbide. The aluminum-based alloy layer is disposed in the open hole and contains aluminum, boron, carbon, and oxygen, wherein the content of aluminum is between 4 at. % and 55 at. %, the content of boron is between 9 at. % and 32 at. %, the content of carbon is between 13 at. % and 32 at. %, the content of oxygen is between 2 at. % and 38 at. %, and the ratio of the content of boron to carbon is between 0.3 and 2.7.

The present invention relates to pulverulent aluminium alloys having Cu, Zn or Si/Mg as the most relevant alloying element, the alloy further having a content of 1 to 15 wt. % of metals selected from the group M1 comprising Mo, Nb, Zr, Fe, Ti, Ta, V, and lanthanides. Such aluminium alloys can be used in additive manufacturing processes such as selective laser melting for the production of high-strength and hot-crack-free three-dimensional objects. The present invention further relates to methods and devices for producing three-dimensional objects from such aluminium alloys, methods for producing such pulverulent aluminium alloys, three-dimensional objects also produced from such pulverulent aluminium alloys, and specific aluminium alloys.

An Al—Sc alloy sputtering target. The target comprising from 1.0 at % to 65 at % scandium and from 35 at % to 99 at % aluminum and having a microstructure including a first aluminum matrix phase and a second phase dispersed uniformly therethrough. The second phase comprises one or more compounds corresponding to the formula Sc.sub.xAl.sub.y, where x is from 1 to 2 and y is from 0 to 3.

A process comprising providing a metallic first powder having a plurality of first particles. The process includes adding a second material to the first powder, the second material having a plurality of second particles. The process includes combining the first powder with the second material to form a modified powder including modified powder particles having an interior portion containing an interior composition, and an outer surface portion with an outer composition different from the interior composition.

The invention relates to a method for producing a part, comprising the production of successive solid metallic layers (201 . . . 20n), each layer being produced by depositing a metal (25) called filler metal, said filler metal consisting of an aluminium alloy comprising at least the following alloying elements: Zr, in a mass fraction of 0.60 to 1.40%, Mn, in a mass fraction of 2.00 to 5.00%, Ni, in a mass fraction of 1.00 to 5.00%, Cu, in a mass fraction of 1.00 to 5.00%.

The invention also relates to a part obtained by means of the method.

The alloy used in the additive manufacturing method of the invention makes it possible to obtain parts with exceptional properties.

The invention relates to a method for producing a part, comprising the production of successive solid metallic layers (201...20n), each layer being produced by depositing a metal (25) called filler metal, said method being characterized in that the part has a specific grain structure.

The invention also relates to a part obtained by means of this method and an alternative method.

The alloy used in the additive manufacturing method of the invention makes it possible to obtain parts with exceptional properties.

A graphene and in-situ nano-ZrB.sub.2 particle-co-reinforced aluminum matrix composite (AMC) and a preparation method thereof are provided. The preparation method includes: heating an aluminum alloy for melting, adding potassium fluoroborate and potassium fluorozirconate to produce ZrB.sub.2 particles in-situ, additionally adding a mixture of pre-prepared copper-coated graphene and an aluminum powder, and stirring with an electromagnetic field for uniform dispersion; and ultrasonically treating the resulting melt to improve the dispersion of the in-situ nano-ZrB.sub.2 particles and the graphene, casting for molding to obtain a casting, and subjecting the casting to homogenization and rolling for deformation to obtain the graphene and in-situ nano-ZrB.sub.2 particle-co-reinforced AMC. The in-situ generation of the reinforcement nano-ZrB.sub.2 particles in an aluminum alloy melt increases the number of interfaces in the composite and also increases the dislocation density.