Polycrystalline material comprising a plurality of nano-grains of a crystalline phase of an iron group element and a plurality of crystalline grains of material including carbon (C) or nitrogen (N); each nano-grain having a mean size less than 10 nanometres.

A thermal spray powder is provided that contains, as constituent elements, a first element selected from W and Mo; a second element selected from Co, Ni, and Fe; a third element selected from C and B; and a fourth element selected from Al and Mg. The amount of the second element in the thermal spray powder is 20% by mole or greater. The mole ratio of the fourth element to the second element in the thermal spray powder is 0.05 or greater and 0.5 or less. The thermal spray powder has a crystal phase containing Co, Ni, or Fe; W; and C or a crystal phase containing Co, Ni, or Fe; W or Mo; and B. In an X-ray diffraction spectrum of the thermal spray powder, the peak intensity attributed to Co, Ni, or Fe is at most 0.1 times the largest peak intensity in the same X-ray diffraction spectrum.

A method for manufacturing a wear resistant component, includes the steps of: providing a mould defining at least a portion of the component; providing a powder mixture comprising a first powder of tungsten carbide and a second powder of a cobalt-based alloy, wherein the powder mixture comprises 30-70 vol % of the first powder of tungsten carbide and 70-30 vol % of the second powder of the cobalt-based alloy and the second powder of cobalt-based alloy comprises 20-35 wt % Cr, 0-20 wt % W, 0-15 wt % Mo, 0-10 wt % Fe, 0.05-4 wt % C and balance Co, wherein the amounts of W and Mo fulfills the requirement 4<W+Mo<20; filling the mould with the powder mixture; and subjecting the mould to Hot Isostatic Pressing (HIP) at a predetermined temperature, a predetermined isostatic pressure and for a predetermined time so that the particles of the powder mixture bond metallurgically to each other.

A method for manufacturing a wear resistant component, includes the steps of: providing a mould defining at least a portion of the component; providing a powder mixture comprising a first powder of tungsten carbide and a second powder of a cobalt-based alloy, wherein the powder mixture comprises 30-70 vol % of the first powder of tungsten carbide and 70-30 vol % of the second powder of the cobalt-based alloy and the second powder of cobalt-based alloy comprises 20-35 wt % Cr, 0-20 wt % W, 0-15 wt % Mo, 0-10 wt % Fe, 0.05-4 wt % C and balance Co, wherein the amounts of W and Mo fulfills the requirement 4<W+Mo<20; filling the mould with the powder mixture; and subjecting the mould to Hot Isostatic Pressing (HIP) at a predetermined temperature, a predetermined isostatic pressure and for a predetermined time so that the particles of the powder mixture bond metallurgically to each other.

A powder metal compact is disclosed. The powder metal compact includes a cellular nanomatrix comprising a nanomatrix material. The powder metal compact also includes a plurality of dispersed particles comprising a particle core material that comprises an Mg—Zr, Mg—Zn—Zr, Mg—Al—Zn—Mn, Mg—Zn—Cu—Mn or Mg—W alloy, or a combination thereof, dispersed in the cellular nanomatrix.

A powder metal compact is disclosed. The powder metal compact includes a cellular nanomatrix comprising a nanomatrix material. The powder metal compact also includes a plurality of dispersed particles comprising a particle core material that comprises an Mg—Zr, Mg—Zn—Zr, Mg—Al—Zn—Mn, Mg—Zn—Cu—Mn or Mg—W alloy, or a combination thereof, dispersed in the cellular nanomatrix.

Provided is a hard sintered body which exhibits excellent high temperature oxidation resistance and has a high hardness at a high temperature. In the hard sintered body, a binder phase is contained at from 8.8 to 34.4 mol % and the balance is composed of a hard phase and inevitable impurities. The binder phase contains iron aluminide containing FeAl as a main component and alumina that is dispersed in iron aluminide and has a particle size of 1 μm or less. The hard phase is composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table, and solid solutions of these. This hard sintered body is obtained by mixing and pulverizing a binding particle powder containing an iron aluminide powder composed of at least one kind selected from FeAl.sub.2, Fe.sub.2Al.sub.5 and FeAl.sub.3 and a hard particle powder composed of at least one kind selected from carbides, nitrides, carbonitrides and borides of Group 4 metals, Group 5 metals and Group 6 metals in the periodic table and then sintering a mixed powder thus obtained.

A cutting tool comprises a base material which includes particles including a tungsten carbide (WC) as a main component, a binder phase including cobalt (Co) as a main component, and particles including a carbide or a carbonitride of at least one selected from the group consisting of Group 4a, 5a, and 6a elements, or a solid solution thereof; and a hard film formed on the base material, wherein the hard film comprises at least an alumina layer, a cubic phase free layer (CFL), in which the carbide or the carbonitride is not formed, is formed from a surface of the base material to a depth of 10 μm to 50 μm, and a Co content of a surface of the CFL is 80% or more of a maximum Co content of the CFL.

A cemented carbide comprises particles including a tungsten carbide (WC) as a main component; a binder phase including cobalt (Co) as a main component; and particles including a carbide or a carbonitride of at least one selected from the group consisting of Group 4a, 5a, and 6a elements, or a solid solution thereof, wherein a cubic phase free layer (CFL), in which the carbide or the carbonitride is not formed, is formed from a surface of the cemented carbide to a depth of 5 μm to 50 μm.

A cemented carbide comprises particles including a tungsten carbide (WC) as a main component; a binder phase including cobalt (Co) as a main component; and particles including a carbide or a carbonitride of at least one selected from the group consisting of Group 4a, 5a, and 6a elements, or a solid solution thereof, wherein a cubic phase free layer (CFL), in which the carbide or the carbonitride is not formed, is formed from a surface of the cemented carbide to a depth of 5 μm to 50 μm.