An additive manufacturing method may involve: Providing a first material in powder form and a second material as a consumable electrode; forming the first material into a first layer on a base; placing an end of the second material in close proximity to a portion of the first layer; operating a power supply connected to the base and the second material to provide electrical energy sufficient to initiate a chemical reaction between the first and second materials and form a reaction product; feeding additional amounts of the second material while moving the end of the second material along a desired pattern adjacent the first layer, additional reaction products forming additional portions of the article; providing additional quantities of the first material over the first layer to form a subsequent layer; and operating the power supply to form additional portions of the article in the subsequent layer.

An additive manufacturing method may involve: Providing a first material in powder form and a second material as a consumable electrode; forming the first material into a first layer on a base; placing an end of the second material in close proximity to a portion of the first layer; operating a power supply connected to the base and the second material to provide electrical energy sufficient to initiate a chemical reaction between the first and second materials and form a reaction product; feeding additional amounts of the second material while moving the end of the second material along a desired pattern adjacent the first layer, additional reaction products forming additional portions of the article; providing additional quantities of the first material over the first layer to form a subsequent layer; and operating the power supply to form additional portions of the article in the subsequent layer.

Provided is a corrosion, erosion and wear resistant cemented carbide for high demand applications including, for example, use as a component within oil and gas production. The cemented carbide includes a hard phase and a binder phase. The cemented carbide may include, for example. Ni, Cr and Mo. The binder phase content of the cemented carbide is between 7 to 11 wt %. The WC of the cemented carbide may have an average grain size of from 0.1 to 2 μm.

Provided is a corrosion, erosion and wear resistant cemented carbide for high demand applications including, for example, use as a component within oil and gas production. The cemented carbide includes a hard phase and a binder phase. The cemented carbide may include, for example. Ni, Cr and Mo. The binder phase content of the cemented carbide is between 7 to 11 wt %. The WC of the cemented carbide may have an average grain size of from 0.1 to 2 μm.

A sintered ball having: a chemical composition such that, in percentages by mass based on the mass of the ball: 89%≤W≤97%; 5%≤C≤8%; Co≤0.5%; Ni≤0.5%; Elements other than W, C, Co, and Ni, or “Other elements”: ≤3%; a tungsten carbide(s) content greater than 55% in percentage by mass based on the crystallized phases; a bulk density greater than or equal to 14 g/cm.sup.3.

A sintered ball having: a chemical composition such that, in percentages by mass based on the mass of the ball: 89%≤W≤97%; 5%≤C≤8%; Co≤0.5%; Ni≤0.5%; Elements other than W, C, Co, and Ni, or “Other elements”: ≤3%; a tungsten carbide(s) content greater than 55% in percentage by mass based on the crystallized phases; a bulk density greater than or equal to 14 g/cm.sup.3.

A polycrystalline diamond sintered material tool includes: a cemented carbide substrate, which is mainly composed of WC and includes Co; and a diamond layer containing a metal catalyst made of Co provided on the cemented carbide substrate. The average layer thickness of a Co rich layer formed in an interface between the cemented carbide substrate and the diamond layer is 30 μm or less. C.sub.MAX/C.sub.DIA is 2 or less when C.sub.DIA is an average content of Co included in the diamond layer and C.sub.MAX is a peak value of a Co content in the Co rich layer. D/D.sub.O is less than 2 when D is an average grain size of WC particles in a region from the interface between the cemented carbide substrate and the diamond layer to 50 μm toward an inside of the cemented carbide substrate; and D.sub.O is an average grain size of WC particles.

A polycrystalline diamond sintered material tool includes: a cemented carbide substrate, which is mainly composed of WC and includes Co; and a diamond layer containing a metal catalyst made of Co provided on the cemented carbide substrate. The average layer thickness of a Co rich layer formed in an interface between the cemented carbide substrate and the diamond layer is 30 μm or less. C.sub.MAX/C.sub.DIA is 2 or less when C.sub.DIA is an average content of Co included in the diamond layer and C.sub.MAX is a peak value of a Co content in the Co rich layer. D/D.sub.O is less than 2 when D is an average grain size of WC particles in a region from the interface between the cemented carbide substrate and the diamond layer to 50 μm toward an inside of the cemented carbide substrate; and D.sub.O is an average grain size of WC particles.

A composite cemented carbide roll comprising an inner layer made of an iron-based alloy, and an outer layer made of cemented carbide which is metallurgically bonded to an outer peripheral surface of the inner layer; the cemented carbide of the outer layer comprising 55-90 parts by mass of WC particles and 10-45 parts by mass of an Fe-based binder phase having a particular composition; a shaft member and a shaft end member being metallurgically bonded to at least one axial end of the inner layer; the inner layer being made of an iron-based alloy containing 2.0% or more in total by mass of at least one selected from the group consisting of Cr, Ni and Mo; and the shaft member and the shaft end member being made of an iron-based alloy containing 1.5% or less in total by mass of at least one selected from the group consisting of Cr, Ni and Mo.

A composite cemented carbide roll comprising an inner layer made of an iron-based alloy, and an outer layer made of cemented carbide which is metallurgically bonded to an outer peripheral surface of the inner layer; the cemented carbide of the outer layer comprising 55-90 parts by mass of WC particles and 10-45 parts by mass of an Fe-based binder phase having a particular composition; a shaft member and a shaft end member being metallurgically bonded to at least one axial end of the inner layer; the inner layer being made of an iron-based alloy containing 2.0% or more in total by mass of at least one selected from the group consisting of Cr, Ni and Mo; and the shaft member and the shaft end member being made of an iron-based alloy containing 1.5% or less in total by mass of at least one selected from the group consisting of Cr, Ni and Mo.