Disclosed in the present invention is a manufacturing method for a carbon steel and austenitic stainless-steel rolling clad plate, comprising the steps of: (1) obtaining a blank material of a carbon steel layer and a blank material of a stainless-steel layer; (2) assembling blank materials; (3) cladding and rolling; (4) cold rolling; (5) first annealing; and (6) second annealing. The carbon steel and austenitic stainless-steel rolling clad plate has two unique annealing processes, so that the clad plate has the performance advantages of the austenitic stainless-steel and the carbon steel. In addition, further disclosed in the present invention is a carbon steel and austenitic stainless-steel rolling clad plate manufactured by this method.

Disclosed in the present invention is a manufacturing method for a carbon steel and austenitic stainless-steel rolling clad plate, comprising the steps of: (1) obtaining a blank material of a carbon steel layer and a blank material of a stainless-steel layer; (2) assembling blank materials; (3) cladding and rolling; (4) cold rolling; (5) first annealing; and (6) second annealing. The carbon steel and austenitic stainless-steel rolling clad plate has two unique annealing processes, so that the clad plate has the performance advantages of the austenitic stainless-steel and the carbon steel. In addition, further disclosed in the present invention is a carbon steel and austenitic stainless-steel rolling clad plate manufactured by this method.

The present invention provides a tin blackplate for processing and a method for manufacturing the same.

The tin blackplate according to an exemplary embodiment of the present invention comprises: in % by weight, 0.0005 to 0.005% of carbon (C), 0.15 to 0.60% of manganese (Mn), 0.01 to 0.06% of aluminum (AI), 0.0005 to 0.004% of nitrogen (N), 0.0005 to 0.003% of boron (B), 0.01 to 0.035% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfies the following Formula 1.

4.8≤([Ti]+[Al])/[N]−[B]≤12.5  [Equation 1]

In this case, in Equation 1, [Ti], [Al], [N], and [B] mean each value obtained by dividing the content (% by weight) of Ti, Al, N, and B in the blackplate by each atomic weight thereof.

The present invention provides a tin blackplate for processing and a method for manufacturing the same.

The tin blackplate according to an exemplary embodiment of the present invention comprises: in % by weight, 0.0005 to 0.005% of carbon (C), 0.15 to 0.60% of manganese (Mn), 0.01 to 0.06% of aluminum (AI), 0.0005 to 0.004% of nitrogen (N), 0.0005 to 0.003% of boron (B), 0.01 to 0.035% of titanium (Ti), and the balance being iron (Fe) and inevitable impurities, and satisfies the following Formula 1.

4.8≤([Ti]+[Al])/[N]−[B]≤12.5  [Equation 1]

In this case, in Equation 1, [Ti], [Al], [N], and [B] mean each value obtained by dividing the content (% by weight) of Ti, Al, N, and B in the blackplate by each atomic weight thereof.

The present disclosure discloses a preparation method of a multi-functional marine engineering alloy. Through the coupling of a multi-principal alloy structure, structural entropy, and temperature and powder metallurgy and heat treatment, mutual solubility between elements and free energy of an alloy system are regulated, Cu grain boundary segregation is eliminated, and uniform and dispersed nano-precipitation of the anti-fouling element Cu in corrosion-resistant and high-plasticity multi-principal alloys is realized. The preparation method is simple and controllable to operate, and the prepared material has plasticity higher than 75%, high yield strength, excellent corrosion resistance and anti-fouling property, and has important application prospects in the field of marine engineering.

The present disclosure discloses a preparation method of a multi-functional marine engineering alloy. Through the coupling of a multi-principal alloy structure, structural entropy, and temperature and powder metallurgy and heat treatment, mutual solubility between elements and free energy of an alloy system are regulated, Cu grain boundary segregation is eliminated, and uniform and dispersed nano-precipitation of the anti-fouling element Cu in corrosion-resistant and high-plasticity multi-principal alloys is realized. The preparation method is simple and controllable to operate, and the prepared material has plasticity higher than 75%, high yield strength, excellent corrosion resistance and anti-fouling property, and has important application prospects in the field of marine engineering.

Disclosed is a duplex ferritic austenitic stainless steel of 40-60 volume % ferrite and 40-60 volume % austenite, with improved cold workability and impact toughness. It contains less than 0.07% carbon (C), 0.1-2.0% silicon (Si), 3-5% manganese (Mn), 19-23% chromium (Cr), 1.1-1.9% nickel (Ni), 1.1-3.5% copper (Cu), 0.18-0.30% nitrogen (N), optionally molybdenum (Mo) and/or tungsten (W) according to the formula (Mo+½W)<1.0%. It optionally contains 0.001-0.005% boron (B), up to 0.03% of each of cerium (Ce) and/or calcium (Ca), with the balance being iron (Fe) and impurities where the chromium equivalent (Cr.sub.eq) and the nickel equivalent (Ni.sub.eq): 20<Cr.sub.eq<24.5 and Ni.sub.eq>10, where Cr.sub.eq=Cr+1.5Si+Mo+2Ti+0.5Nb Ni.sub.eq=Ni+0.5Mn+30(C+N)+0.5(Cu+Co).

Disclosed is a duplex ferritic austenitic stainless steel of 40-60 volume % ferrite and 40-60 volume % austenite, with improved cold workability and impact toughness. It contains less than 0.07% carbon (C), 0.1-2.0% silicon (Si), 3-5% manganese (Mn), 19-23% chromium (Cr), 1.1-1.9% nickel (Ni), 1.1-3.5% copper (Cu), 0.18-0.30% nitrogen (N), optionally molybdenum (Mo) and/or tungsten (W) according to the formula (Mo+½W)<1.0%. It optionally contains 0.001-0.005% boron (B), up to 0.03% of each of cerium (Ce) and/or calcium (Ca), with the balance being iron (Fe) and impurities where the chromium equivalent (Cr.sub.eq) and the nickel equivalent (Ni.sub.eq): 20<Cr.sub.eq<24.5 and Ni.sub.eq>10, where Cr.sub.eq=Cr+1.5Si+Mo+2Ti+0.5Nb Ni.sub.eq=Ni+0.5Mn+30(C+N)+0.5(Cu+Co).

Provided herein is a dual-phase stainless steel having excellent carbon dioxide corrosion resistance, excellent sulfide stress corrosion cracking resistance, and excellent sulfide stress cracking resistance. The dual-phase stainless steel contains, in mass %, C: 0.03% or less, Si: 1.0% or less, Mn: 0.10 to 1.5%, P: 0.030% or less, S: 0.005% or less, Cr: 20.0 to 30.0%, Ni: 5.0 to 10.0%, Mo: 2.0 to 5.0%, Cu: 2.0 to 6.0%, N: less than 0.07%, and the balance Fe and unavoidable impurities, and has a structure that is 20 to 70% austenite phase, and 30 to 80% ferrite phase in terms of a volume fraction.

Provided herein is a dual-phase stainless steel having excellent carbon dioxide corrosion resistance, excellent sulfide stress corrosion cracking resistance, and excellent sulfide stress cracking resistance. The dual-phase stainless steel contains, in mass %, C: 0.03% or less, Si: 1.0% or less, Mn: 0.10 to 1.5%, P: 0.030% or less, S: 0.005% or less, Cr: 20.0 to 30.0%, Ni: 5.0 to 10.0%, Mo: 2.0 to 5.0%, Cu: 2.0 to 6.0%, N: less than 0.07%, and the balance Fe and unavoidable impurities, and has a structure that is 20 to 70% austenite phase, and 30 to 80% ferrite phase in terms of a volume fraction.