A Ni steel has a chemical composition within a predetermined range, in which a metallographic structure of a thickness middle portion contains 2.0 vol % to 20.0 vol % of an austenite phase, an average grain size of prior austenite grains is 3.0 μm to 12.0 μm, an average aspect ratio of the prior austenite grains is 2.6 to 10.0, a plate thickness is 4.5 mm to 20 mm, a yield stress at room temperature is 590 MPa to 710 MPa, and a tensile strength at the room temperature is 690 MPa to 810 MPa, when the plate thickness is more than 16 mm, the Ni steel contains Ni: 11.5% or more, and when the plate thickness is 16 mm or less and the Ni steel contains Ni: less than 11.5%, the average grain size of the prior austenite grains is 6.0 μm or less.

A Ni steel has a chemical composition within a predetermined range, in which a metallographic structure of a thickness middle portion contains 2.0 vol % to 20.0 vol % of an austenite phase, an average grain size of prior austenite grains is 3.0 μm to 12.0 μm, an average aspect ratio of the prior austenite grains is 2.6 to 10.0, a plate thickness is 4.5 mm to 20 mm, a yield stress at room temperature is 590 MPa to 710 MPa, and a tensile strength at the room temperature is 690 MPa to 810 MPa, when the plate thickness is more than 16 mm, the Ni steel contains Ni: 11.5% or more, and when the plate thickness is 16 mm or less and the Ni steel contains Ni: less than 11.5%, the average grain size of the prior austenite grains is 6.0 μm or less.

The present disclosure relates to a steel for pressure vessels used in a hydrogen sulfide atmosphere, and relates to a steel material for pressure vessels having excellent resistance to hydrogen induced cracking (HIC) and a manufacturing method thereof.

The present disclosure relates to a steel for pressure vessels used in a hydrogen sulfide atmosphere, and relates to a steel material for pressure vessels having excellent resistance to hydrogen induced cracking (HIC) and a manufacturing method thereof.

Disclosed is, as a high-strength steel plate of API X80 grade or higher with a thickness of 38 mm or more, a thick steel plate for structural pipes or tubes that exhibits high strength in the rolling direction and excellent Charpy properties at its mid-thickness part without addition of large amounts of alloying elements. The thick steel plate for structural pipes or tubes disclosed herein has: a specific chemical composition; a microstructure at its mid-thickness part that is a dual-phase microstructure of ferrite and bainite with an area fraction of the ferrite being less than 50%, and that contains ferrite grains with a grain size of 15 μm or less in an area fraction of 80% or more with respect to the whole area of the ferrite; a tensile strength of 620 MPa or more; and a Charpy absorption energy vE.sub.−20+ C. at −20° C. at the mid-thickness part of 100 J or more.

Disclosed is, as a high-strength steel plate of API X80 grade or higher with a thickness of 38 mm or more, a thick steel plate for structural pipes or tubes that exhibits high strength in the rolling direction and excellent Charpy properties at its mid-thickness part without addition of large amounts of alloying elements. The thick steel plate for structural pipes or tubes disclosed herein has: a specific chemical composition; a microstructure at its mid-thickness part that is a dual-phase microstructure of ferrite and bainite with an area fraction of the ferrite being less than 50%, and that contains ferrite grains with a grain size of 15 μm or less in an area fraction of 80% or more with respect to the whole area of the ferrite; a tensile strength of 620 MPa or more; and a Charpy absorption energy vE.sub.−20+ C. at −20° C. at the mid-thickness part of 100 J or more.

To provide an austenitic stainless steel material having a high creep strength and a high creep ductility even in a high-temperature environment at 800° C. or more. An austenitic stainless steel material according to the present disclosure has a chemical composition that includes, in mass %: C: 0.060% or less; Si: 1.0% or less; Mn: 2.00% or less; P: 0.0010 to 0.0400%; S: 0.010% or less; Cr: 10 to 25%; Ni: 25 to 45%; Nb: 0.2 to 2.0%; W: 2.5 to 6.0%; B: 0.0010 to 0.0100%: Al: 2.5 to 4.5%; and the balance being Fe and impurities, and satisfies Formulae (1) and (2), and the sum of the content of dissolved Nb and the content of dissolved W is 3.2 mass % or more.
(W/184+Nb/93)/(C/12)≥5.5  (1)
(W/184+Nb/93)/(B/11)≤450  (2) In Formulae (1) and (2), the content in mass % of the corresponding element is substituted for each symbol of element.

To provide an austenitic stainless steel material having a high creep strength and a high creep ductility even in a high-temperature environment at 800° C. or more. An austenitic stainless steel material according to the present disclosure has a chemical composition that includes, in mass %: C: 0.060% or less; Si: 1.0% or less; Mn: 2.00% or less; P: 0.0010 to 0.0400%; S: 0.010% or less; Cr: 10 to 25%; Ni: 25 to 45%; Nb: 0.2 to 2.0%; W: 2.5 to 6.0%; B: 0.0010 to 0.0100%: Al: 2.5 to 4.5%; and the balance being Fe and impurities, and satisfies Formulae (1) and (2), and the sum of the content of dissolved Nb and the content of dissolved W is 3.2 mass % or more.
(W/184+Nb/93)/(C/12)≥5.5  (1)
(W/184+Nb/93)/(B/11)≤450  (2) In Formulae (1) and (2), the content in mass % of the corresponding element is substituted for each symbol of element.

A metal powder having a composition including the following elements, expressed in content by weight: 6.5%≤Si≤10%, 4.5%≤Nb≤10%, 0.2%≤B≤2.0%, 0.2%≤Cu≤2.0%, C≤2% and optionally containing Ni≤10 wt % and/or Co≤10 wt % and/or Cr≤7 wt % and/or Zr as a substitute for any part of Nb on a one-to-one basis and/or Mo as a substitute for any part of Nb on a one-to-one basis and/or P as a substitute for any part of Si on a one-to-one basis, the balance being Fe and unavoidable impurities resulting from the elaboration, the metal powder having a microstructure including at least 5% in area fraction of an amorphous phase, the balance being made of crystalline ferritic phases with a grain size below 20 μm and possible precipitates, the metal powder having a mean sphericity SPHT of at least 0.80.

A metal powder having a composition including the following elements, expressed in content by weight: 6.5%≤Si≤10%, 4.5%≤Nb≤10%, 0.2%≤B≤2.0%, 0.2%≤Cu≤2.0%, C≤2% and optionally containing Ni≤10 wt % and/or Co≤10 wt % and/or Cr≤7 wt % and/or Zr as a substitute for any part of Nb on a one-to-one basis and/or Mo as a substitute for any part of Nb on a one-to-one basis and/or P as a substitute for any part of Si on a one-to-one basis, the balance being Fe and unavoidable impurities resulting from the elaboration, the metal powder having a microstructure including at least 5% in area fraction of an amorphous phase, the balance being made of crystalline ferritic phases with a grain size below 20 μm and possible precipitates, the metal powder having a mean sphericity SPHT of at least 0.80.