Provided is a ferritic stainless steel in which cracking is unlikely to be caused in the vicinity of a weld zone by the stress due to expansion, contraction, and deformation due to the thermal effect of welding in the case of performing welding after deep drawing and which is excellent in corrosion resistance in the vicinity of the weld zone. The ferritic stainless steel has a composition containing C: 0.001% to 0.020%, Si: 0.01% to 0.30%, Mn: 0.01% to 0.50%, P: 0.04% or less, S: 0.01% or less, Cr: 18.0% to 24.0%, Ni: 0.01% to 0.40%, Mo: 0.30% to 3.0%, Al: 0.01% to 0.15%, Ti: 0.01% to 0.50%, Nb: 0.01% to 0.50%, V: 0.01% to 0.50%, Co: 0.01% to 6.00%, B: 0.0002% to 0.0050%, and N: 0.001% to 0.020% on a mass basis, the remainder being Fe and inevitable impurities. The composition satisfies 0.30%≤Ti+Nb+V≤0.60%.

The disclosed martensitic stainless steel is defined in its composition is by specified ranges of weight percentages of C; Mn; Si; ≤Mn+Si; ≤S; 10,000×Mn×S; P; Cr, with [Cr−10.3−80*(C+N).sup.2]≤(Mn+Ni); Ni; Mo; Mo+2W; Cu; Ti; V; Zr; Al; O; Ta; Nb; (Nb+Ta)/(C+N); Nb; N; Co; Cu+Co; Cu+Co+Ni; B; rare earths+Y; Ca; the remainder being iron and impurities resulting from processing. Its microstructure includes at least 75% martensite, at most 20% ferrite and at most 0.5% carbides, the size of the ferrite grains being between 4 and 80 μm, preferably between 5 and 40 μm. Also disclosed is a method of manufacturing such steel.

A precipitation hardenable, martensitic stainless steel is disclosed. The alloy has the following broad composition in weight percent. TABLE-US-00001 Ni 10.5-12.5 Co 1.0-6.0 Mo 1.0-4.0 Ti 1.5-2.0 Cr  8.5-11.5 Al Up to 0.5 Mn  1.0 max. Si 0.75 max. B 0.01 max.
The balance of the alloy is iron and the usual impurities found in commercial grades of precipitation hardenable martensitic stainless steels as known to those skilled in the state of the art in melting practice for such steels. A method of making parts from the alloy and an article of manufacture made from the alloy are also described.

A precipitation hardenable, martensitic stainless steel is disclosed. The alloy has the following broad composition in weight percent. TABLE-US-00001 Ni 10.5-12.5 Co 1.0-6.0 Mo 1.0-4.0 Ti 1.5-2.0 Cr  8.5-11.5 Al Up to 0.5 Mn  1.0 max. Si 0.75 max. B 0.01 max.
The balance of the alloy is iron and the usual impurities found in commercial grades of precipitation hardenable martensitic stainless steels as known to those skilled in the state of the art in melting practice for such steels. A method of making parts from the alloy and an article of manufacture made from the alloy are also described.

The invention relates to a steel material which allows for components to be formed with low residual stress via additive manufacturing without pre- or post-heating. The steel material consists of a steel with the following composition, in wt. %: C: 0.28-0.65%, Co: <10.0, Cr: 3.5-12.5%, optionally Mo: 0.5-12.5%, wherein the sum of the content of Cr and Mo is 4-16%, the Ni equivalent Ni_eq calculated according to the formula Ni_eq [%]=30% C+% Ni+0.5% Mn from the C-content % C, the Ni-content % Ni, the Mn-content % Mn fulfills the condition (1) 10%≤Ni eq≤20%, and alongside C, optionally respectively up to 9% Mn and up to 4.5% Ni are provided to fulfill condition (1), wherein the Cr equivalent Cr_eq calculated according to the formula Cr_eq [mass]=% Cr+% Mo+1.5% S+0.5% Nb+2% XX from the CR-content Cr %, the Mo-content Mo %, the Si-content Si %, the Nb-content % Nb and the sum % XX of the contents of at least one element of the group “Sc, Y, Ti, Zr, Hf, V, Ta” fulfills the condition (2) 4% Cr_eq 16%, and optionally respectively up to 2% Si, up to 2% Nb or at least one element from the group “Sc, Y, Ti, Zr, Hf, V, Ta” are provided to fulfill condition (2), wherein the total proportion of elements of this group is at most equal to the mass fraction of 2%, which Ti must not exceed if Ti is the only element selected from the group consisting of “Sc, Y, Ti, Zr, Hf, V, Ta”, and wherein the rest of the steel consists of Fe and <0.5% impurities, including 0.025% P and 50.025% S. The steel material is suited, in particular as a powder, for LPBF or LMD methods and as wire for the WAAM method.

The invention relates to a steel material which allows for components to be formed with low residual stress via additive manufacturing without pre- or post-heating. The steel material consists of a steel with the following composition, in wt. %: C: 0.28-0.65%, Co: <10.0, Cr: 3.5-12.5%, optionally Mo: 0.5-12.5%, wherein the sum of the content of Cr and Mo is 4-16%, the Ni equivalent Ni_eq calculated according to the formula Ni_eq [%]=30% C+% Ni+0.5% Mn from the C-content % C, the Ni-content % Ni, the Mn-content % Mn fulfills the condition (1) 10%≤Ni eq≤20%, and alongside C, optionally respectively up to 9% Mn and up to 4.5% Ni are provided to fulfill condition (1), wherein the Cr equivalent Cr_eq calculated according to the formula Cr_eq [mass]=% Cr+% Mo+1.5% S+0.5% Nb+2% XX from the CR-content Cr %, the Mo-content Mo %, the Si-content Si %, the Nb-content % Nb and the sum % XX of the contents of at least one element of the group “Sc, Y, Ti, Zr, Hf, V, Ta” fulfills the condition (2) 4% Cr_eq 16%, and optionally respectively up to 2% Si, up to 2% Nb or at least one element from the group “Sc, Y, Ti, Zr, Hf, V, Ta” are provided to fulfill condition (2), wherein the total proportion of elements of this group is at most equal to the mass fraction of 2%, which Ti must not exceed if Ti is the only element selected from the group consisting of “Sc, Y, Ti, Zr, Hf, V, Ta”, and wherein the rest of the steel consists of Fe and <0.5% impurities, including 0.025% P and 50.025% S. The steel material is suited, in particular as a powder, for LPBF or LMD methods and as wire for the WAAM method.

A method for producing an austenitic heat resistant steel in which a difference between a content of Nb and an amount of Nb analyzed as extraction residues satisfies [0.170≤Nb−Nb.sub.ER≤0.480], the method including: a forming step of machining and forming a steel having a predetermined chemical composition into a product shape; a solution heat treatment step of performing, after the forming step, heat treatment under conditions including a heat treatment temperature satisfying [−250Nb+1200≤T≤−100Nb+1290] and a soaking time satisfying [405−0.3T≤t≤2475−1.5T]; and a cooling step of performing cooling after the solution heat treatment step.

A method for producing an austenitic heat resistant steel in which a difference between a content of Nb and an amount of Nb analyzed as extraction residues satisfies [0.170≤Nb−Nb.sub.ER≤0.480], the method including: a forming step of machining and forming a steel having a predetermined chemical composition into a product shape; a solution heat treatment step of performing, after the forming step, heat treatment under conditions including a heat treatment temperature satisfying [−250Nb+1200≤T≤−100Nb+1290] and a soaking time satisfying [405−0.3T≤t≤2475−1.5T]; and a cooling step of performing cooling after the solution heat treatment step.

The present invention relates to an additive manufacturing wire, containing, in terms of % by mass, 0%<Si≤2.0%, 0%<Mn≤6.0%, 3.0%≤Ni≤15.0%, 20.0%≤Cr≤30.0%, 1.0%≤Mo≤5.0%, 0%<N≤0.50%, with a balance being Fe and unavoidable impurities, in which C≤0.10% is satisfied, and 27<A<67 is satisfied, when Cr.sub.eq is defined as Cr+Mo+1.5Si+0.5(Nb+W)+2(Ti+Al), Ni.sub.eq is defined as Ni+30C+20N+0.5(Mn+Cu+Co), and A is defined as −16.2+6.3Cr.sub.eq−9.3Ni.sub.eq, here, in the definition of Cr.sub.eq and Ni.sub.eq, each element symbol indicates a content of the each element in units of % by mass.

The present invention relates to an additive manufacturing wire, containing, in terms of % by mass, 0%<Si≤2.0%, 0%<Mn≤6.0%, 3.0%≤Ni≤15.0%, 20.0%≤Cr≤30.0%, 1.0%≤Mo≤5.0%, 0%<N≤0.50%, with a balance being Fe and unavoidable impurities, in which C≤0.10% is satisfied, and 27<A<67 is satisfied, when Cr.sub.eq is defined as Cr+Mo+1.5Si+0.5(Nb+W)+2(Ti+Al), Ni.sub.eq is defined as Ni+30C+20N+0.5(Mn+Cu+Co), and A is defined as −16.2+6.3Cr.sub.eq−9.3Ni.sub.eq, here, in the definition of Cr.sub.eq and Ni.sub.eq, each element symbol indicates a content of the each element in units of % by mass.