Patent classifications
C23C2/0222
Hot-dip galvanized steel sheet having excellent low-temperature adhesion and workability
Provided is a hot-dip galvanized steel sheet having excellent low-temperature adhesion and workability, and a manufacturing method therefor, the hot-dip galvanized steel sheet comprising: an inhibition layer formed on a base steel sheet and comprising an Fe—Al-based intermetallic alloy phase; a hot-dip galvanized layer formed on the inhibition layer; and an Al—Mn-based alloy phase discontinuously formed between the inhibition layer and the hot-dip galvanized layer.
METAL-COATED STEEL STRIP
A method of forming an Al—Zn—Si—Mg alloy coating on a steel strip includes dipping steel strip into a bath of molten Al—Zn—Si—Mg alloy and forming a coating of the alloy on exposed surfaces of the steel strip. The method also includes controlling conditions in the molten coating bath and downstream of the coating bath so that there is a uniform Al/Zn ratio across the surface of the coating formed on the steel strip. An Al—Zn—Mg—Si coated steel strip includes a uniform Al/Zn ratio on the surface or the outermost 1-2 μm of the Al—Zn—Si—Mg alloy coating.
PLATED STEEL SHEET
A plated steel sheet includes: a steel sheet; and a plating layer that is formed on at least a part of a surface of the steel sheet, in which a chemical composition of the plating layer includes, by mass %, Al: more than 5.00% and 35.00% or less, Mg: 3.00% to 15.00%, Si: 0% to 2.00%, Ca: 0% to 2.00%, and a remainder of Zn and impurities, in which in a cross section of the plating layer in a thickness direction, the area ratio of a lamellar structure in which an (Al—Zn) phase and a MgZn.sub.2 phase are arranged in layers is 10% to 90%, a lamellar spacing of the lamellar structure is 2.5 μm or less, and the area ratio of an (Al—Zn) dendrite is 35% or less.
ZINC-COATED STEEL SHEET WITH HIGH RESISTANCE SPOT WELDABILITY
A method for producing a zinc or zinc-alloy coated steel sheet with a tensile strength higher than 900 MPa, for the fabrication of resistance spot welds containing in average not more than two Liquid Metal Embrittlement cracks per weld having a depth of 100 μm or more, with steps of providing a cold-rolled steel sheet, heating cold-rolled steel sheet up to a temperature T1 between 550° C. and Ac1+50° C. in a furnace zone with an atmosphere (A1) containing from 2 to 15% hydrogen by volume, so that the iron is not oxidized, then adding in the furnace atmosphere, water steam or oxygen with an injection flow rate Q higher than (0.07%/h×α), α being equal to 1 if said element is water steam or equal to 0.52 if said element is oxygen, at a temperature T≥T1, so to obtain an atmosphere (A2) with a dew point DP2 between −15° C. and the temperature Te of the iron/iron oxide equilibrium dew point, then heating the sheet from temperature T.sub.1 up to a temperature T.sub.2 between 720° C. and 1000° C. in a furnace zone under an atmosphere (A2) of nitrogen containing from 2 to 15% hydrogen and more than 0.1% CO by volume, with an oxygen partial pressure higher than 10.sup.−21 atm., wherein the duration to of heating of the sheet from temperature T.sub.1 up to the end of soaking at temperature T.sub.2 is between 100 and 500 s, soaking the sheet at T.sub.2, then cooling the sheet at a rate between 10 and 400° C./s, then coating the sheet with zinc or zinc-alloy coating.
Low-density hot dip galvanized steel and manufacturing method therefor
Low-density hot dip galvanized steel, comprising a steel substrate (1) located at a core portion and a coating layer (3) located on the surface. An interface layer is disposed between the steel substrate (1) and the coating layer (3), the interface layer comprises an iron particle layer (4), iron particles dispersed on the steel substrate (1) and covering the steel substrate (1) are disposed in the iron particle layer (4), and the iron particles are covered by a first inhibition layer (5). The low-density hot dip galvanized steel contains element Al in a mass percentage of 3.0% to 7.0%. Correspondingly, the present invention also comprises a manufacturing method for the low-density hot dip galvanized steel. The low-density hot dip galvanized steel has a low density, a high strength and high galvanizability and coating layer adhesion.
Plated steel sheet
A plated steel sheet having excellent chemical convertibility includes: a steel; and a plating layer that is provided on a surface of the steel, in which the plating layer includes, by mass %, Al: 5.00% to 35.00%, Mg: 2.50% to 13.00%, Fe: 5.00% to 35.00%, Si: 0% to 2.00%, Ca: 0.03% to 2.00%, and a remainder consisting of Zn and impurities, and in a surface of the plating layer, the area fraction of a Fe—Al phase is 0% to 30%, the area fraction of a rod-like lamellar structure of Zn and MgZn.sub.2 is 5% to 90%, the area fraction of a massive MgZn.sub.2 phase is 10% to 70%, and the area fraction of a remainder is 10% or less.
PLATED STEEL SHEET
A plated steel sheet having excellent chemical convertibility includes: a steel; and a plating layer that is provided on a surface of the steel, in which the plating layer includes, by mass %, Al: 5.00% to 35.00%, Mg: 2.50% to 13.00%, Fe: 5.00% to 35.00%, Si: 0% to 2.00%, Ca: 0.03% to 2.00%, and a remainder consisting of Zn and impurities, and in a surface of the plating layer, the area fraction of a Fe—Al phase is 0% to 30%, the area fraction of a rod-like lamellar structure of Zn and MgZn.sub.2 is 5% to 90%, the area fraction of a massive MgZn.sub.2 phase is 10% to 70%, and the area fraction of a remainder is 10% or less.
PLATED STEEL
A plated steel includes: a steel; and a plating layer that is provided on a surface of the steel, in which the plating layer includes, by mass %, Al: 5.00% to 35.00%, Mg: 2.50% to 13.00%. Fe: 5.00% to 40.00%, Si: 0% to 2.00%, Ca: 0% to 2.00%, and a remainder of Zn and impurities, and in a cross section of the plating layer, the area fraction of a Zn solid-solution Fe.sub.2Al.sub.5 phase in which 5% or more of Zn is solid-soluted is 10% to 60% and the area fraction of a MgZn.sub.2 phase is 10% to 90%.
High-strength hot-dip zinc plated steel material having excellent plating properties and method for preparing same
Provided are a hot-dip zinc plated steel material and a method for preparing same, the hot-dip zinc plated steel material comprising: base iron comprising 0.01-1.6 wt % of Si and 1.2-3.1 wt % of Mn; a Zn—Al—Mg alloy plating layer; and an Al-rich layer formed on the interface of the base iron and Zn—Al—Mg alloy plating layer, wherein the rate of occupied surface area of the Al-rich layer is 70% or higher (including 100%).
Ferritic stainless steel sheet and method of producing same, and al or al alloy coated stainless steel sheet
A ferritic stainless steel sheet comprises a chemical composition containing, in mass %, C: 0.030% or less, Si: 3.0% or less, Mn: 1.0% or less, P: 0.040% or less, S: 0.010% or less, Cr: 11.0% to 30.0%, Al: 8.0% to 20.0%, Ni: 0.05% to 0.50%, N: 0.020% or less, and at least one selected from the group consisting of Zr: 0.01% to 0.20% and Hf: 0.01% to 0.20%, with a balance consisting of Fe and inevitable impurities.