The present invention relates to a method for the manufacture of a coated steel sheet comprising the following successive steps: A. the coating of the steel sheet with a first coating consisting of nickel and having a thickness between 600 nm and 1400 nm, the steel sheet having the following composition in weight: 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<3.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0%, and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.010%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B. the recrystallization annealing at a temperature between 820 to 1200° C., C. the coating with a second coating based on zinc not comprising nickel.

The entirety or a part of this hot stamped product includes, as a chemical composition, by mass %, C: 0.001% or more and less than 0.080%, Si: 2.50% or less, Mn: 0.01% or more and less than 0.50%, P: 0.200% or less, S: 0.0200% or less, sol.Al: 0.001% to 2.500%, N: 0.0200% or less, Cr: 0.30% or more and less than 2.00%, and a remainder: Fe and impurities, in which a metallographic structure contains, by vol %, ferrite: more than 60.0%, martensite: 0% or more and less than 10.0%, and bainite: 0% or more and less than 20.0%, a tensile strength is less than 700 MPa, and ΔTS, which is a decrease in the tensile strength after a heat treatment at 170° C. for 20 minutes, is 100 MPa or less.

The present disclosure relates to a high-strength hot-dip galvanized steel sheet having excellent surface quality and electrical resistance spot weldability, and a method for manufacturing the same. A galvanized steel sheet according to an aspect of the present disclosure is a galvanized steel sheet including a base steel sheet and a zinc-based plating layer formed on a surface of the base steel sheet, wherein a ratio (a/b) of a hardness of a surface layer portion (a) to a hardness of an internal portion (b) of the base steel sheet may be less than 0.95.

A steel sheet has a predetermined chemical composition containing, in mass %, C: more than 0.18% and less than 0.30%, Mn: more than 2.50% and 4.00% or less, and other elements. The steel micro-structure at a position at a depth of ¼ of the sheet thickness from the surface in an L cross section of the steel sheet is, in area %, tempered martensite: 25 to 90%, ferrite: 5% or less, retained austenite: 10 to 50%, and bainite: 5% or less. At a position at a depth of ¼ of the sheet thickness from the surface of the L cross section, the proportion of a total area of retained austenite grains having an area of 1 μm.sup.2 or more and having a grain shape circularity of 0.1 or more is less than 50% with respect to the entire area of retained austenite. The steel sheet satisfies the formula C.sub.Mnγ/C.sub.Mnα≥1.2.

A method for producing a steel strip containing, in addition to iron as the main component and unavoidable impurities, one or more of the following oxygen-affine elements in wt. %: Al: more than 0.02, Cr: more than 0.1, Mn: more than 1.3 or Si: more than 0.1, where the surface of the steel strip is cleaned, oxidation-treated and annealed. The treated and annealed steel strip is subsequently coated with a hot-dip coat. In order to be less cost-intensive and to achieve uniform, reproducible adhesion conditions for the coat, the steel strip is oxidation-treated prior to the annealing at temperatures below 200° C., where on the surface of the steel strip, with the formation of oxides with iron from the steel strip, an oxide layer is formed, which contains iron oxide and is reduction-treated during the course of the annealing under a reducing atmosphere to achieve a surface consisting substantially of metallic iron.

The invention relates to a method and a device for rapidly cooling a metal strip and removing residues present on the strip after this cooling, wherein the residues are formed during a cooling of said metal strip by a non-oxidizing liquid solution for the metal strip and a stripping liquid solution for the oxides present on the surface of the strip, or by a mixture of this liquid solution and a gas.

The present invention relates to a zinc plated steel sheet having excellent surface quality and spot weldability, and a manufacturing method therefore. A zinc plated steel sheet according to one aspect of the present invention comprises a base steel sheet and a zinc-based plating layer formed on the surface of the base steel sheet, wherein the GDOES profile of oxygen, which is measured in the depth direction from the surface of the base steel sheet, has a form in which a local minimum point and a local maximum point alternately appear in the depth direction from the surface, and the difference (a local maximum value—a local minimum value) between the oxygen concentration (a local minimum value) at the local minimum point and the oxygen concentration (a local maximum value) at the local maximum point can be 0.1 wt % or more.

Equipment for the continuous hot dip-coating of a metal strip 9 including an annealing furnace, a tank 2 containing a liquid metal bath 3, a snout connecting the annealing furnace and tank 2, through which the metal strip 9 runs in a protective atmosphere and the lower part of the snout, the sabot 5, is at least partly immersed in the liquid metal bath 3 in order to define with the surface of the bath, and inside this snout, a liquid seal 6, an overflow 7 not connected to the snout, the overflow 7 including at least one tray 8, placed in the vicinity of the strip 9 when entering the liquid metal bath 3 and encompassed by liquid seal 6.

Provided is a method for manufacturing a high-strength galvanized steel sheet. Heating in a first half of oxidizing treatment is performed at a temperature of 400° C. to 750° C. in an atmosphere having a particular O.sub.2 concentration and a particular H.sub.2O concentration, and heating in a second half of the oxidizing treatment is performed at a temperature of 600° C. to 850° C. in an atmosphere having a particular O.sub.2 concentration and a particular H.sub.2O concentration. Subsequently, heating in a heating zone for reduction annealing is performed to a temperature of 650° C. to 900° C. at a particular heating rate in an atmosphere having a particular H.sub.2 concentration and a particular H.sub.2O concentration with the balance being N.sub.2 and inevitable impurities, and soaking in a soaking zone for the reduction annealing is performed in an atmosphere having a particular H.sub.2 concentration and a particular H.sub.2O concentration with the balance being N.sub.2 and inevitable impurities.

A high-strength galvanized steel sheet includes a steel sheet containing a predetermined component element, a mass ratio of a content amount of Si to a content amount of Mn in the steel (Si/Mn) being 0.2 or more, and a steel structure in which an average grain size of inclusions existing in an area extending from a surface to a position of ⅓ of a sheet thickness is 50 μm or less, and an average nearest distance between ones of the inclusions is 20 μm or more; and a galvanized layer provided on a surface of the steel sheet, in which an amount of diffusible hydrogen contained in the steel is less than 0.25 mass ppm, oxides containing predetermined elements in an outer layer portion of the steel sheet account for 0.010 g/m.sup.2 or more per one surface, and a tensile strength is 1100 MPa or more.