A method for forming a vertically cracked thermal barrier coating is disclosed including positioning an article relative to a heat source. The article includes a thermal barrier coating disposed on a first surface of a substrate, and the substrate includes a second surface distal across the substrate from the first surface. Heat is applied locally to at least one discrete portion of the second surface of the substrate. At least one vertical crack in the thermal barrier coating is formed disposed over the at least one discrete portion. An article is disclosed including a substrate and a vertically-cracked thermal barrier coating disposed on the substrate. The vertically cracked thermal barrier coating includes at least one vertical crack in the thermal barrier coating and at least one of a low density of less than 85% of a theoretical density for the thermal barrier coating and a selective crack distribution.

A ceramic coating according to at least one embodiment of the present disclosure includes: a bond coat layer formed on a substrate; and a ceramic layer formed on the bond coat layer. The ceramic layer has a first region in contact with an interface between the ceramic layer and the bond coat layer and a second region father away from the interface than the first region from the interface. In a cross-section along a thickness direction of the ceramic layer, the number of crack intersection points at which two or more cracks intersect per unit area in the ceramic layer is larger in the first region than in the second region.

A hearth roll for a continuous annealing furnace, the hearth roll comprising a thermal spray coating on a surface of the hearth roll, wherein the thermal spray coating comprises main components consisting of a Co-based alloy, a carbide of a transition metal, and a double oxide; and impurities, the double oxide consists of one or two types of a first double oxide consisting of Al and a rare earth element and a second double oxide consisting of a transition metal and a rare earth element, and when the main components are 100 mass %, a content of the Co-based alloy is 25 mass % or more and 50 mass % or less, a content of the carbide is 5 mass % or more and 30 mass % or less, and a content of the double oxide is 20 mass % or more and 45 mass % or less.

A hearth roll for a continuous annealing furnace, the hearth roll comprising a thermal spray coating on a surface of the hearth roll, wherein the thermal spray coating comprises main components consisting of a Co-based alloy, a carbide of a transition metal, and a double oxide; and impurities, the double oxide consists of one or two types of a first double oxide consisting of Al and a rare earth element and a second double oxide consisting of a transition metal and a rare earth element, and when the main components are 100 mass %, a content of the Co-based alloy is 25 mass % or more and 50 mass % or less, a content of the carbide is 5 mass % or more and 30 mass % or less, and a content of the double oxide is 20 mass % or more and 45 mass % or less.

Methods for forming a coating on a surface of a substrate are provided. The method can include: preheating the surface of the substrate; spraying a slurry suspension onto the surface of the substrate to form a coating, wherein the slurry composition comprises a rare earth compound, a sintering agent, and a solvent, wherein the rare earth compound has the formula: A.sub.1-bB.sub.bZ.sub.1-dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to 0.5; and M is Ta, Nb, or a mixture thereof; and thereafter, heat treating the coating to densify the coating from an initial porosity to a sintered porosity.

Methods for forming a coating on a surface of a substrate are provided. The method can include: preheating the surface of the substrate; spraying a slurry suspension onto the surface of the substrate to form a coating, wherein the slurry composition comprises a rare earth compound, a sintering agent, and a solvent, wherein the rare earth compound has the formula: A.sub.1-bB.sub.bZ.sub.1-dD.sub.dMO.sub.6 where A is Al, Ga, In, Sc, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Fe, Cr, Co, Mn, Bi, or a mixture thereof; b is 0 to 0.5; Z is Hf, Ti, or a mixture thereof; D is Zr, Ce, Ge, Si, or a mixture thereof; d is 0 to 0.5; and M is Ta, Nb, or a mixture thereof; and thereafter, heat treating the coating to densify the coating from an initial porosity to a sintered porosity.

In an exemplary embodiment, an upper electrode is disposed in a processing chamber to face a susceptor and provided with a plate-like member and an electrode part. In an exemplary embodiment, the plate-like member is formed with a gas distribution hole that distributes a processing gas used for a plasma processing. The electrode part is formed in a film shape by thermally spraying silicon onto a surface of the plate-like member where an outlet of the gas distribution hole is formed.

In an exemplary embodiment, an upper electrode is disposed in a processing chamber to face a susceptor and provided with a plate-like member and an electrode part. In an exemplary embodiment, the plate-like member is formed with a gas distribution hole that distributes a processing gas used for a plasma processing. The electrode part is formed in a film shape by thermally spraying silicon onto a surface of the plate-like member where an outlet of the gas distribution hole is formed.

Method for manufacturing a fire-resistant part of an air conditioning system for an air or rail transport vehicle, characterized in that it includes at least the following steps: a step of obtaining a part including at least one aluminum alloy surface portion, and a step of treating the aluminum alloy surface portion by use of micro-arc oxidation in order to produce a ceramic coating on the surface portion.

An article may include a substrate, such as a silicon-containing ceramic matrix composite, an environmental barrier coating (EBC) layer on the substrate, and a CMAS-resistant EBC layer on the EBC layer. The EBC layer may include at least one rare-earth disilicate (REDS). The CMAS-resistant EBC layer may include at least one rare-earth monosilicate (REMS) configured to react with CMAS to form crystalline reaction products. The CMAS-resistant EBC layer may include a plurality of vertical cracks extending from a surface of the CMAS-resistant EBC layer at least partially into the CMAS-resistant EBC layer. Additionally, or alternatively, the EBC layer may include a plurality of vertical cracks extending from a surface of the EBC layer into at least a portion of the EBC layer.