Disclosed is a system for treating a surface of a multi-metal article. The system includes first and second and/or third conversion compositions for contacting at least a portion of the surface. The first conversion composition includes phosphate ions and zinc ions and is substantially free of fluoride. The second conversion composition includes a lanthanide series metal cation and an oxidizing agent. The third conversion composition includes an organophosphate compound, an organophosphonate compound, or combinations thereof that optionally may include at least one transition metal. Methods of treating a multi-metal article using the system also are disclosed. Also disclosed are substrates treated with the system and method.

Described are aluminum alloy products that generally have a microstructure and composition that resists corrosion. This corrosion resistance, in turn, allows the aluminum alloy products to exhibit favorable bond durability performance, such as when adhesively bonded to another product. The corrosion resistance can be achieved by controlling the composition of the aluminum alloy, including the presence and/or concentration of certain intermetallic particles, such as α-phase intermetallic particles and β-phase intermetallic particles.

Described are aluminum alloy products that generally have a microstructure and composition that resists corrosion. This corrosion resistance, in turn, allows the aluminum alloy products to exhibit favorable bond durability performance, such as when adhesively bonded to another product. The corrosion resistance can be achieved by controlling the composition of the aluminum alloy, including the presence and/or concentration of certain intermetallic particles, such as α-phase intermetallic particles and β-phase intermetallic particles.

Aluminum alloy products having a bulk and a micro-grained subsurface structure are described. The aluminum alloy products may exhibit superior bonding character and may comprise or have a silicon-containing layer thereon. The bulk may include a matrix including grains of an aluminum alloy and may comprise aluminum and one or more alloying elements such as zinc, magnesium, copper, chromium, silicon, iron, or manganese. The micro-grained subsurface structure may be substantially devoid of one or more defects (e.g., voids, transfer cracks, or fissures) or organics, oils, hydrocarbons, soils, inorganic residues, rolled-in oxides, or anodic oxides, which may commonly be present in rolled near-surface microstructures. The micro-grained subsurface structure may include or have thereon a first oxide layer having a thickness of from 1 nm to 20 nm. Methods of making aluminum alloy products are also described.

In order to provide a device and a method for treating workpieces (102), in which an optimized workpiece treatment is possible, it is proposed that a treatment station (114) comprise a treatment chamber (136) that can be flooded for workpiece treatment.

Improved aluminum can end stock (CES) is disclosed. The CES includes an adhered polymer coating exhibiting low feathering and high performance in various acid tests. The low feathering and resistance to acid tests is accomplished by incorporating a copolymer adhesion promoter film to an aluminum alloy before lamination. In some cases, the metal strip is pretreated with a conversion layer, which can include compounds of trivalent chromium (Cr(III)) and phosphates or titanium and zirconium.

Improved aluminum can end stock (CES) is disclosed. The CES includes an adhered polymer coating exhibiting low feathering and high performance in various acid tests. The low feathering and resistance to acid tests is accomplished by incorporating a copolymer adhesion promoter film to an aluminum alloy before lamination. In some cases, the metal strip is pretreated with a conversion layer, which can include compounds of trivalent chromium (Cr(III)) and phosphates or titanium and zirconium.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.

A hot stamped steel includes a base material that is formed of steel, a plated layer that is formed on a surface of the base material, and a phosphate coating that is formed on a surface of the plated layer; chemical composition of the plated layer contains 20.00 to 45.00 mass % of Al, 10.00 to 45.00 mass % of Fe, 4.50 to 15.00 mass % of Mg, 0.10 to 3.00 mass % of Si, 0.05 to 3.00 mass % of Ca, 0 to 0.50 mass % of Sb, 0 to 0.50 mass % of Pb, 0 to 1.00 mass % of Cu, 0 to 1.00 mass % of Sn, 0 to 1.00 mass % of Ti, 0 to 0.50 mass % of Sr, 0 to 1.00 mass % of Cr, 0 to 1.00 mass % of Ni, and 0 to 1.00 mass % of Mn with a remainder of Zn and impurities; the phosphate coating consists of zinc phosphate crystals containing 5.0 to 50.0 mass % of Mg and 0.5 to 5.0 mass % of Ca; and the adhesion amount of the phosphate coating per one surface is in a range of 0.1 to 10.0 g/m.sup.2.

An insulation layer formation method comprises: a first step in which a surface treatment is applied to a base material to form thereon a high-resistance layer having high electric resistivity; a second step in which metal plating parts are formed on the base material that has undergone the first step in such a manner as to allow a high-resistance layer to be formed thereon; and a third process in which a high-resistance layer is formed on the base material that has undergone the second step.