Provided is an aluminum-resin bonded body that expresses excellent bonding strength and does not show a reduction in the strength after a durability test, thus being able to keep the excellent bonding strength over a long period of time. The aluminum-resin bonded body includes: an aluminum substrate formed of aluminum or an aluminum alloy; an oxygen-containing film containing oxygen, the oxygen-containing film being formed on a surface of the aluminum substrate; and a resin molded body formed of a thermoplastic resin composition containing a thermoplastic resin and an additive, the resin molded body being bonded onto the oxygen-containing film, in which the thermoplastic resin composition contains any one or both of: a thermoplastic resin containing an element having an unshared electron pair in a repeat unit and/or at an end; and an additive containing an element having an unshared electron pair.

Provided are: an AlMgSi-based aluminum alloy material including an aluminum alloy including 0.10 to 1.50 mass % (hereinafter, %) Si and 0.10 to 2.00% of Mg, in which an oxide coating film mainly containing aluminum is formed on a surface of the aluminum alloy material, a MgSi-based crystallized product having an equivalent circle diameter of 0.1 to 5.0 m is contained at 100 to 150,000 particles/mm.sup.2, a MgSi-based crystallized product having an equivalent circle diameter of more than 5.0 m and 10.0 m or less is contained at 5 particles/mm.sup.2 or less, and the oxide coating film includes Si at a maximum concentration of 0.1 to 40.0% and Mg at a maximum concentration of 0.1 to 20.0%; a method for producing the aluminum alloy material; and an aluminum alloy clad material, in which the aluminum alloy material is clad on at least one surface of an aluminum core material.

Provided are: an AlMgSi-based aluminum alloy material including an aluminum alloy including 0.10 to 1.50 mass % (hereinafter, %) Si and 0.10 to 2.00% of Mg, in which an oxide coating film mainly containing aluminum is formed on a surface of the aluminum alloy material, a MgSi-based crystallized product having an equivalent circle diameter of 0.1 to 5.0 m is contained at 100 to 150,000 particles/mm.sup.2, a MgSi-based crystallized product having an equivalent circle diameter of more than 5.0 m and 10.0 m or less is contained at 5 particles/mm.sup.2 or less, and the oxide coating film includes Si at a maximum concentration of 0.1 to 40.0% and Mg at a maximum concentration of 0.1 to 20.0%; a method for producing the aluminum alloy material; and an aluminum alloy clad material, in which the aluminum alloy material is clad on at least one surface of an aluminum core material.

It has been found that the chemical reactivity of the metal surface of heat exchangers with coolants in presence of nitrites can be reduced by the addition of additives such as phosphonates or phosphinates. Aluminum, other Group III metals, as well as other metals commonly used in cooling systems, such as those of automobile engines, may thus be effectively protected.

It has been found that the chemical reactivity of the metal surface of heat exchangers with coolants in presence of nitrites can be reduced by the addition of additives such as phosphonates or phosphinates. Aluminum, other Group III metals, as well as other metals commonly used in cooling systems, such as those of automobile engines, may thus be effectively protected.

A corrosion-resistant coating on an aluminum-containing substrate such as an aluminum substrate, an aluminum alloy substrate (e.g., AA 2024, AA 6061, or AA7075), or other aluminum-containing substrate includes a corrosion inhibitor-incorporated ZnAl layered double hydroxide (LDH) layer and a sol-gel layer. A zinc salt and a corrosion inhibitor (e.g., a salt of an oxyanion of a transition metal such as a vanadate) is dissolved to form a zinc-corrosion inhibitor solution, and the substrate is immersed in or otherwise contacted with the solution to form the corrosion inhibitor-incorporated ZnAl LDH layer on the substrate. A sol-gel composition is applied on the corrosion inhibitor-incorporated ZnAl LDH layer of the substrate to form a sol-gel layer, and the sol-gel layer is cured.

A corrosion-resistant coating on an aluminum-containing substrate such as an aluminum substrate, an aluminum alloy substrate (e.g., AA 2024, AA 6061, or AA7075), or other aluminum-containing substrate includes a corrosion inhibitor-incorporated ZnAl layered double hydroxide (LDH) layer and a sol-gel layer. A zinc salt and a corrosion inhibitor (e.g., a salt of an oxyanion of a transition metal such as a vanadate) is dissolved to form a zinc-corrosion inhibitor solution, and the substrate is immersed in or otherwise contacted with the solution to form the corrosion inhibitor-incorporated ZnAl LDH layer on the substrate. A sol-gel composition is applied on the corrosion inhibitor-incorporated ZnAl LDH layer of the substrate to form a sol-gel layer, and the sol-gel layer is cured.

The invention relates to a method of forming an aluminosilicate zeolite layer on an aluminium-containing metallic substrate composed of metallic aluminium or an aluminium alloy which is introduced into an alkalized aqueous reaction dispersion in which silicon and optionally aluminium are present as network-forming elements, where, irrespective of whether or not aluminium is present in the aqueous reaction dispersion, the molar ratio between the aluminium in the aqueous reaction dispersion and the sum total of the network-forming elements present in the aqueous reaction dispersion is below 0.5, where, when aluminium is not present in the aqueous reaction solution, the deficiency molar ratio is 0, and the alkalized aqueous reaction dispersion containing the aluminium-containing metallic substrate is heated and aluminium is removed from the aluminium-containing metallic substrate for the aluminosilicate zeolite formation process and the layer of an aluminosilicate zeolite is formed on the aluminium-containing metallic substrate by in situ crystallizative application. In the course of this, an aluminium complexing agent with anchoring oxygen atoms is incorporated into the alkalized aqueous reaction dispersion. The invention further relates to the advantageous use of the method product in sorption-based fields of application.

The invention relates to a method of forming an aluminosilicate zeolite layer on an aluminium-containing metallic substrate composed of metallic aluminium or an aluminium alloy which is introduced into an alkalized aqueous reaction dispersion in which silicon and optionally aluminium are present as network-forming elements, where, irrespective of whether or not aluminium is present in the aqueous reaction dispersion, the molar ratio between the aluminium in the aqueous reaction dispersion and the sum total of the network-forming elements present in the aqueous reaction dispersion is below 0.5, where, when aluminium is not present in the aqueous reaction solution, the deficiency molar ratio is 0, and the alkalized aqueous reaction dispersion containing the aluminium-containing metallic substrate is heated and aluminium is removed from the aluminium-containing metallic substrate for the aluminosilicate zeolite formation process and the layer of an aluminosilicate zeolite is formed on the aluminium-containing metallic substrate by in situ crystallizative application. In the course of this, an aluminium complexing agent with anchoring oxygen atoms is incorporated into the alkalized aqueous reaction dispersion. The invention further relates to the advantageous use of the method product in sorption-based fields of application.

Provided is a coated aluminum material having a coating film on a surface of an aluminum material, and capable of exerting excellent corrosion resistance even under severe use conditions while being chromium-free. The coating film is formed on a surface of the aluminum material with a silica-containing film including a water dispersible silica, a phosphorus compound, and a silane coupling agent provided therebetween. The silica-containing film includes 0.5 to 35 mass % of a silane coupling agent, and has Si and P contents of 2 to 60, and 0.1 to 6.0 mg/m.sup.2, respectively, and a P/Si mass ratio of P content and Si content of 0.02 to 0.15. Further, provided is a method for producing such a coated aluminum material.