A method of suppressing corrosion of a corrodible metal surface that contacts a fluid stream in a hydrocarbon system. The method includes introducing into the fluid stream a treatment chemistry including an organometallic corrosion inhibitor having a metal and an organic carboxylic acid. The organometallic corrosion inhibitor is hydrocarbon soluble and the metal is released from the organometallic corrosion inhibitor in the presence of water or H.sub.2S.

Corrosion inhibitor compositions are provided that can include a mixture of one or more alkaline earth metals, one or more organic phosphates, one or more inorganic phosphates, optionally a dispersant, and hydroxyphosphono acetic acid and/or salts thereof and/or derivatives of hydroxyphosphono acetic acid and/or salts thereof. Methods of mitigating or inhibiting corrosion of metal surfaces are also disclosed. The methods can include the steps of adding a corrosion inhibitor composition as described in the present disclosure to a medium in contact with the metal surface and optionally to the metal surface before it is contacted by the medium.