The present invention has as its object the provision of a coated steel member and coated steel sheet excellent in hydrogen embrittlement resistance in a corrosive environment and methods for manufacturing the same. The coated steel member of the present invention is provided on its surface with an Al—Fe-based coating containing Cu and one or more of Mo, Ni, Mn, and Cr in a total by mass % of 0.12% or more by heating, cooling, and manufacturing a coated steel sheet having a layer containing Cu on its surface under predetermined conditions.

A method for manufacturing a high-strength galvanized steel sheet having excellent strength-elongation balance, coating adhesiveness, and surface appearance. The method includes: (i) a first heating process of heating a steel sheet having a predetermined chemical composition, (ii) a first pickling process of pickling the steel sheet which was subjected to the first heating process in an oxidizing acidic aqueous solution, (iii) a second pickling process of pickling the steel sheet which was subjected to the first pickling process in a non-oxidizing acidic aqueous solution, (iv) a second heating process of holding the steel sheet, which was subjected to the second pickling process, at a temperature range of 700° C. or higher and 900° C. or lower in a hydrogen-containing atmosphere for 20 seconds or more and 300 seconds or less, and (v) performing a galvanizing treatment on the steel sheet which was subjected to the second heating process.

A steel sheet for electroplating includes, by mass %, C: 0.0005% to 0.0050%, Si: 0.20% to 1.0%, Mn: 0.40% to 2.5%, P: 0.05% or less, Ti: 0.010% to 0.050%, Nb: 0.010% to 0.040%, B: 0.0005% to 0.0030%, S: 0.02% or less, Al: 0.01% to 0.30%, N: 0.0010% to 0.01%, and the balance including Fe and impurities, in which when Si content is represented by [Si] and Mn content is represented by [Mn], “[Mn]+5[Si]” is 2.0 to 7.0, and the steel sheet has surface property in which an average of displacements of a measurement point obtained based on a moving average of continuous 31 points in total including 15 front points and 15 back points in a cross-sectional profile of a surface obtained by measuring the average of displacements in an evaluation length of 10 μm or more at an interval of 0.07 μm, is 0.005 μm to 0.10 μm.

An acid-resistant steel sheet according to an embodiment of the present invention includes, by wt %, equal to or less than 0.1% of C (excluding 0%) and 2.0 to 4.0% of Si, and includes a remainder of Fe and inevitable impurities, and the content of Si of the surface portion by the inward depth of up to 10 μm from the surface of the steel sheet is equal to or greater than 15 wt %.

Aspects treat and remove a layer of scale comprising iron oxide and alloying elements oxides that is formed on an advanced high strength metal surface comprising at least two (2) percent by weight of alloy. A first conditioning process compromises structural integrity of or removes iron oxide within the scale layer to expose the alloy oxide to chemical engagement with a disposed aqueous alkali salt solution that is heated to transforming one or more alkali salts within the disposed solution into a quasi-molten form. The alloy oxide is oxidized via reaction with the solution quasi molten alkali salt(s) and water, forming one or more water soluble alkali alloy compounds. A water rinse dissolves and rinses the water soluble compound(s) from the steel product surface of the advanced high strength, leaving a film of iron oxide on the surface that is removed via a final pickling process.

The present invention has as its object the provision of a steel member and steel sheet having high tensile strength and toughness and excellent in hydrogen embrittlement resistance in a corrosive environment and methods for manufacturing the same. The steel member of the present invention has predetermined chemical constituents and has a maximum value of content of Cu in a range from the surface to a depth of 0 to 30 μm of 1.4 times the content of Cu at a depth of 200 μm.

A method of manufacturing a martensitic stainless steel pipe includes: preparing a hollow shell, S1; a pickling step, S3-2, in which the hollow shell is immersed in nitrohydrofluoric acid solution at a temperature below 50° C.; after pickling step S3-2, a high-pressure water washing step, S4, in which high-pressure water is injected onto the outer surface of the hollow shell to clean the outer surface of the hollow shell; after high-pressure water washing step S4, a hot-water immersion step, S5, in which the hollow shell is immersed in hot water if necessary; and spraying gas onto the surface of the hollow shell, S6, before a lapse of 15 minutes from completion of high-pressure water washing step S4 or hot-water immersion step S5.

A method of manufacturing a metal component with an anti-microbial molecular layer may comprise: disposing the metal component in a piranha solution; washing the metal component; and grafting a surface of the metal component with a Si-Quat or hybrid Si-Quat molecular layer.

A method of manufacturing an aircraft metallic faucet with an anti-microbial coating may comprise: disposing the aircraft metallic faucet in a piranha solution; washing the aircraft metallic faucet; and coating a surface of the aircraft metallic faucet with a Si-Quat based coating. A method of manufacturing an aircraft metallic faucet with a hybrid anti-microbial coating with cross-linkers may comprise: disposing the aircraft metallic faucet in a piranha solution; washing the aircraft metallic faucet; coating a surface of the aircraft metallic faucet with a hybrid Si-Quat coating with crosslinkers; and curing the hybrid Si-Quat coating at a temperature between 60° C. (140° F.) and 100° C. (212° F.).

A high-strength steel sheet includes a predetermined chemical composition, a microstructure contains, by volume percentage, 95% or more of tempered martensite and bainite in total, and a remainder consists of ferrite and pearlite, the microstructure contains 5.0×10.sup.9 pieces/mm or more of, per unit volume, precipitate having an equivalent circle diameter of 5.0 nm or less and containing Ti, Hvs/Hvc which is a ratio of an average hardness Hvs at a position of a depth of 20 μm from a surface to an average hardness Hvc at a position of 0.20 to 0.50 mm from the surface is 0.85 or more, a tensile strength is 980 MPa or more, and a product of the tensile strength and elongation is 12,000 MPa×% or more.