An electrochemical process implements, in a decoupled manner, a first step of electrolysis of an electrolyte to produce gaseous oxygen in a chamber and a second step of electrochemical conversion of H+ ions into gaseous hydrogen in a chamber which contains a liquid phase and a gas phase not dissolved in the liquid phase. Gaseous hydrogen produced in the conversion step is partly present in the gaseous headspace of chamber and as bubbles in the electrolyte, and partly dissolved in the electrolyte which is saturated with hydrogen. The electrolyte has at least one redox pair (A/B) forming at least one intermediate vector enabling the decoupling of the first and second steps. The interface between the gas and liquid phases is increased during the second step to accelerate the diffusion, from liquid phase to gas phase, of the dissolved hydrogen able to supersaturate the electrolyte. Pressurized gaseous hydrogen is then collected.

A hydrogen production power supply system is provided by the present disclosure, wherein two stage conversion modules are arranged between the power supplies, and each output end of the second stage conversion module is connected to a power supply end of each hydrogen production device, respectively, so that independent power supply is provided for each hydrogen production device, which eliminates the loss of gas production caused by the non-uniform load among the hydrogen production devices. In addition, being different from the conventional technology, it is unnecessary for the hydrogen production power supply system to adapt the voltage by using a customized power frequency converter in the present disclosure. Therefore, the path loss issue can be avoided.

A hydrogen production power supply system is provided by the present disclosure, wherein two stage conversion modules are arranged between the power supplies, and each output end of the second stage conversion module is connected to a power supply end of each hydrogen production device, respectively, so that independent power supply is provided for each hydrogen production device, which eliminates the loss of gas production caused by the non-uniform load among the hydrogen production devices. In addition, being different from the conventional technology, it is unnecessary for the hydrogen production power supply system to adapt the voltage by using a customized power frequency converter in the present disclosure. Therefore, the path loss issue can be avoided.

Provided herein, are anode and/or cathode pan assemblies comprising unique ribs and welds configurations; electrochemical cell and/or electrolyzer containing the anode and/or the cathode pan assemblies; and methods to use and manufacture the same.

A system and method for co-producing ultra-high purity oxygen and ultra-high purity hydrogen from a water electrolysis unit is provided. The presently disclosed system and method includes upgrading the crude oxygen stream coming from the water electrolysis unit by means of a small, stand-alone cryogenic distillation system wherein the refrigeration for such cryogenic distillation system is supplied by a nitrogen recycle refrigeration loop.

A system and method for co-producing ultra-high purity oxygen and ultra-high purity hydrogen from a water electrolysis unit is provided. The presently disclosed system and method includes upgrading the crude oxygen stream coming from the water electrolysis unit by means of a small, stand-alone cryogenic distillation system wherein the refrigeration for such cryogenic distillation system is supplied by a nitrogen recycle refrigeration loop.

An electrochemical hydrogen pump includes: at least one hydrogen pump unit including an electrolyte membrane, an anode, a cathode, an anode separator, and a cathode separator; an anode end plate disposed on the anode separator positioned in a first end in a stacking direction, the first end is one end and the second end is another end; a cathode end plate disposed on the cathode separator positioned in a second end in the stacking direction; a fixing member that prevents at least members from the cathode end plate to the cathode separator positioned in the second end from moving in the stacking direction; a first gas flow channel through which hydrogen generated in the cathode is supplied to a first space disposed between the cathode end plate and the cathode separator positioned in the second end; and a first pressure transmitting member disposed in the first space.

An electrochemical hydrogen pump includes: at least one hydrogen pump unit including an electrolyte membrane, an anode, a cathode, an anode separator, and a cathode separator; an anode end plate disposed on the anode separator positioned in a first end in a stacking direction, the first end is one end and the second end is another end; a cathode end plate disposed on the cathode separator positioned in a second end in the stacking direction; a fixing member that prevents at least members from the cathode end plate to the cathode separator positioned in the second end from moving in the stacking direction; a first gas flow channel through which hydrogen generated in the cathode is supplied to a first space disposed between the cathode end plate and the cathode separator positioned in the second end; and a first pressure transmitting member disposed in the first space.

The present invention realizes industrially excellent effects such that when electric power having a large output fluctuation, such as renewable energy, is used as a power source, electrolysis performance is unlikely to be deteriorated and excellent catalytic activity is retained stably over a longer period of time, and in addition, the present invention provides a technique that enables forming a catalyst layer of an oxygen generation anode, which gives such excellent effects, with a more versatile materials and by a simple electrolysis method. Provided are an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing a hybrid nickel-iron hydroxide nanosheet (NiFe-ns) being a composite of a metal hydroxide and an organic substance to an anode chamber and a cathode chamber, and using the electrolyte for electrolysis in each chamber in common, an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing the NiFe-ns to an anode chamber and a cathode chamber, and performing electrolytic deposition of the NiFe-ns in the electrolytic cell during operation to electrolytically deposit the NiFe-ns on a surface of an electrically conductive substrate having a catalyst layer formed on a surface of an oxygen generation anode, thereby recovering and improving electrolysis performance, and an alkaline water electrolysis anode.

The present invention realizes industrially excellent effects such that when electric power having a large output fluctuation, such as renewable energy, is used as a power source, electrolysis performance is unlikely to be deteriorated and excellent catalytic activity is retained stably over a longer period of time, and in addition, the present invention provides a technique that enables forming a catalyst layer of an oxygen generation anode, which gives such excellent effects, with a more versatile materials and by a simple electrolysis method. Provided are an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing a hybrid nickel-iron hydroxide nanosheet (NiFe-ns) being a composite of a metal hydroxide and an organic substance to an anode chamber and a cathode chamber, and using the electrolyte for electrolysis in each chamber in common, an alkaline water electrolysis method including supplying an electrolyte obtained by dispersing a catalyst containing the NiFe-ns to an anode chamber and a cathode chamber, and performing electrolytic deposition of the NiFe-ns in the electrolytic cell during operation to electrolytically deposit the NiFe-ns on a surface of an electrically conductive substrate having a catalyst layer formed on a surface of an oxygen generation anode, thereby recovering and improving electrolysis performance, and an alkaline water electrolysis anode.