Systems and methods for production of hydrogen peroxide, such as high-test peroxide, are disclosed. Representative systems and methods also include aerospace systems and space exploration missions implementing systems and methods for production of hydrogen peroxide. A representative system for making hydrogen peroxide can include: a water electrolyzer for receiving water and separating at least some of the water into hydrogen and oxygen; a proton-exchange membrane cell for receiving water, hydrogen from the water electrolyzer, and oxygen from the water electrolyzer and for combining the hydrogen, the oxygen, and the water into a first hydrogen peroxide solution having a first concentration of hydrogen peroxide in water; and a hydrogen peroxide concentrator for removing at least some of the water from the first hydrogen peroxide solution to yield a second hydrogen peroxide solution that has a second concentration of hydrogen peroxide in water that is greater than the first concentration.

Catalysts for selective production of hydrogen peroxide and methods of making and using thereof have been developed. The catalysts include an alloyed or doped metal oxide which permits tuning of the catalytic properties of the catalysts for selection of a desired pathway to a product, such as hydrogen peroxide. The catalysts may be incorporated into electrochemical or photochemical devices.

Catalysts for selective production of hydrogen peroxide and methods of making and using thereof have been developed. The catalysts include an alloyed or doped metal oxide which permits tuning of the catalytic properties of the catalysts for selection of a desired pathway to a product, such as hydrogen peroxide. The catalysts may be incorporated into electrochemical or photochemical devices.

Systems and methods for electrochemically producing chemical products are provided. In certain cases, the systems and methods described herein are capable of producing chemical products such as hydrogen peroxide in solutions with relatively low concentrations of electrolyte or other dissolved species at high efficiencies and/or low energetic cost. In some cases, redox mediators are used to spatially decouple direct electrochemical processes from the production of the chemical product.

Systems and methods for electrochemically producing chemical products are provided. In certain cases, the systems and methods described herein are capable of producing chemical products such as hydrogen peroxide in solutions with relatively low concentrations of electrolyte or other dissolved species at high efficiencies and/or low energetic cost. In some cases, redox mediators are used to spatially decouple direct electrochemical processes from the production of the chemical product.

A fuel oxidation system including an inlet in fluid communication with an interior of a sealed container, and the sealed container is holding permeated gas released from a pressure vessel within the sealed container. Another inlet is in fluid communication with an environment surrounding the sealed container, and the environment includes oxygen gas (O.sub.2). An oxidation module is in fluid communication with the inlet and the other inlet, and the oxidation module is combining the permeated gas received by the inlet with the oxygen gas (O.sub.2) received by the other inlet to form a preferred substance.

A fuel oxidation system including an inlet in fluid communication with an interior of a sealed container, and the sealed container is holding permeated gas released from a pressure vessel within the sealed container. Another inlet is in fluid communication with an environment surrounding the sealed container, and the environment includes oxygen gas (O.sub.2). An oxidation module is in fluid communication with the inlet and the other inlet, and the oxidation module is combining the permeated gas received by the inlet with the oxygen gas (O.sub.2) received by the other inlet to form a preferred substance.

The present disclosure broadly relates to a process for preparing aqueous solutions of vanadium sulfates or aqueous solutions of transition metal sulfates. More specifically, but not exclusively, the present disclosure relates to a direct electrochemical process in which a suspension, obtained by slurrying transition metals oxides such as oxides of vanadium, oxides of iron, oxides of cobalt, oxides of nickel, oxides of chromium, oxides of manganese, oxides of titanium, oxides of cerium, oxides of praseodymium, oxides of europium, oxides of terbium, oxides of uranium, oxides of plutonium, or their mixtures thereof with sulfuric acid as carrier fluid, is reduced electrochemically inside the cathode compartment of an electrolyzer to produce an aqueous solution of vanadium sulfates or of transition metal sulfates. Simultaneously, oxidizing co-products are produced in the anode compartment.

An electrolysis device may include: a housing comprising a container having an open end, the container configured to contain a liquid when the container is oriented in an upright position; and an electrolysis circuit comprising: a power source; a plurality of electrodes disposed within the container and electrically coupled to the power source; an orientation switch electrically coupled to the power source, coupled to the housing, and oriented to switch when the container is oriented in the upright position; and a control circuit electrically coupled to the power source, the electrodes, and the orientation switch, wherein the electrolysis circuit is configured to operate when the electrodes pass an electric current above a predetermined current threshold and the container is oriented in the upright position.

The present application provides a method for recovering metal from metal-containing material by leaching, the method comprising providing aqueous solution containing leaching agent precursor, providing one or more source(s) of external energy comprising a source of electric current connected to one or more non-metallic electrode(s) comprising carbon material(s) selected from graphite, graphene and derivatives thereof, and carbon nanomaterial(s) selected from carbon nanofibers, carbon nanotubes and carbon nanobuds, treating the aqueous solution with the external energy, which is electric current providing electrochemical reactions, to form hydrogen peroxide from oxygen in the aqueous solution, reacting the leaching agent precursor with the formed hydrogen peroxide to form a leaching agent and to obtain a leaching solution, providing metal-containing material, reacting the metal-containing material with the leaching solution to obtain soluble metal complexes, and recovering the soluble metal complexes. The present application also discloses a device for recovering metal from metal-containing material by leaching.