C25B1/46

Electrode for Electrolysis
20220349075 · 2022-11-03 · ·

The present technology relates to an electrode for electrolysis which has a coating layer containing an ytterbium oxide, wherein the electrode for electrolysis of the present technology is characterized by exhibiting excellent durability and improved overvoltage. Further, the present technology relates to a method of preparing an electrode for electrolysis which includes: applying a coating composition on at least one surface of a metal base, and coating by drying and heat-treating the metal base on which the coating composition has been applied, wherein the coating composition includes a ruthenium precursor and an ytterbium precursor.

Electrolysis device

An electrolysis device for the electrolytic treatment of liquids has an anode chamber and a cathode chamber which are separated from one another via an ion exchange membrane. The chambers are provided with an inlet opening and an outlet opening for the flowing electrolyte, each with one electrode. The inner space of the anode chamber and/or of the cathode chamber are/is subdivided by webs or ribs extending transversely with respect to the electrodes. The webs or ribs are provided at least regionally with holes or cut outs. The webs or ribs include at least one lower region free of holes or cut outs. The electrolysis device provides sufficient mixing in the upper foam phase in the longitudinal direction and also at the same time the airlift pump effect is maintained by way of ascending gas bubbles in the lower region.

Electrolysis device

An electrolysis device for the electrolytic treatment of liquids has an anode chamber and a cathode chamber which are separated from one another via an ion exchange membrane. The chambers are provided with an inlet opening and an outlet opening for the flowing electrolyte, each with one electrode. The inner space of the anode chamber and/or of the cathode chamber are/is subdivided by webs or ribs extending transversely with respect to the electrodes. The webs or ribs are provided at least regionally with holes or cut outs. The webs or ribs include at least one lower region free of holes or cut outs. The electrolysis device provides sufficient mixing in the upper foam phase in the longitudinal direction and also at the same time the airlift pump effect is maintained by way of ascending gas bubbles in the lower region.

ELECTRODE ASSEMBLY AND ELECTROLYSER

The present invention relates to an electrode assembly and an electrolyser using one or more of said assemblies, in particular the present invention provides an electrode assembly for the production of hydrogen comprising: i) an anode structure which comprises an anode located within an electrolysis compartment, ii) a cathode structure which comprises a cathode located within an electrolysis compartment containing a solution of an alkali metal hydroxide, characterised in that the cathode comprises: a) An electrically conductive metal substrate, and b) An electrocatalytic layer on the substrate and comprising a, at least one metal selected from platinum group metals, rhenium, nickel, cobalt and molybdenum and b. at least 50% by volume of an electrically conductive support material, wherein the electrically conductive support material is formed from particles having an average particle size of less than 5 microns (5 μm) and which are not metallic particles.

METHOD FOR PRODUCING LITHIUM HYDROXIDE

A method for producing lithium hydroxide that allows reducing a load of removing divalent or more ions with an ion-exchange resin is provided. The method for producing lithium hydroxide includes steps (1) to (3) below. (1) a neutralization step: a step of adding an alkali to a first lithium chloride containing liquid to obtain a post-neutralization liquid, (2) an ion-exchange step: a step of bringing the post-neutralization liquid into contact with an ion-exchange resin to obtain a second lithium chloride containing liquid, and (3) a conversion step: a step of electrodialyzing the second lithium chloride containing liquid to obtain a lithium hydroxide containing liquid. Since this producing method allows roughly removing divalent or more ions in the neutralization step, a load of metal removal with the ion-exchange resin is reducible.

ELECTROLYSIS CELL HAVING RESILIENT HOLDING ELEMENTS

An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a cathode, and a cathode current distributor. The anode, the ion-exchange membrane, the cathode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.

ELECTROLYSIS CELL HAVING RESILIENT HOLDING ELEMENTS

An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a cathode, and a cathode current distributor. The anode, the ion-exchange membrane, the cathode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.

INTEGRALLY COMBINED CURRENT CARRIER CIRCULATION CHAMBER AND FRAME FOR USE IN UNIPOLAR ELECTROCHEMICAL DEVICES

Disclosed is an integrally combined electrical current carrier, circulation chamber and frame (CCF) formed as a single or double part (CCF) for use in unipolar electrochemical devices, such as a filter press electrolyser apparatus. The CCF is structured to define an internal circulation chamber for circulation of electrolyte, products, and reactants as well as apertures which form flow passageways when the filter press device is assembled. Affixed on opposed surfaces of the CCFs are electrically conductive planar electroactive structures which are in electrical contact with the CCF. The circulation chamber is formed by the depth of the CCF itself between opposing electroactive structures. Multiple CCFs are assembled and compressed together to form the filter press electrolyser apparatus. The flow passageway apertures within the assembled filter press electrolyser are aligned to form flow pathways, located above and below the circulation chambers. Reactants and electrolyte are input along the bottom flow pathways. When power is applied to the CCFs and electroactive structures, the reactants, once they flow into the circulation chamber with the electrolyte, undergo redox reactions to produce the products which are then collected and exit the electrolyser in the upper flow pathways.

ELECTRODE STRUCTURE FOR ELECTROLYZER

Disclosed are an electrode structure including: an electrode plate; and a flow path guide disposed on one side of the electrode plate along the circumference of the electrode plate, and an electrolyzer including the electrode structure.

ELECTRODE STRUCTURE FOR ELECTROLYZER

Disclosed are an electrode structure including: an electrode plate; and a flow path guide disposed on one side of the electrode plate along the circumference of the electrode plate, and an electrolyzer including the electrode structure.