The invention relates to a method for producing a gas product containing oxygen, wherein a feedstock containing water is subjected to electrolysis to obtain a raw anode gas, which is rich in oxygen and contains hydrogen, and a raw cathode gas, which is low in oxygen and rich in hydrogen. The raw anode gas is at least partially subjected to a catalytic conversion of hydrogen to water to obtain a first mixture with depleted hydrogen content. A first part of the first mixture is returned to the raw anode gas downstream of the electrolysis and upstream of the catalytic conversion, and the gas product containing oxygen is formed using at least a second part of the first mixture. The invention also relates to a plant for carrying out a method of this type.

The invention relates to a method for producing a gas product containing oxygen, wherein a feedstock containing water is subjected to electrolysis to obtain a raw anode gas, which is rich in oxygen and contains hydrogen, and a raw cathode gas, which is low in oxygen and rich in hydrogen. The raw anode gas is at least partially subjected to a catalytic conversion of hydrogen to water to obtain a first mixture with depleted hydrogen content. A first part of the first mixture is returned to the raw anode gas downstream of the electrolysis and upstream of the catalytic conversion, and the gas product containing oxygen is formed using at least a second part of the first mixture. The invention also relates to a plant for carrying out a method of this type.

A flow cell for reducing carbon dioxide may include a first chamber having a gold coated gas diffusion layer working electrode, a reference electrode, and a water-in-salt electrolyte comprising a super concentrated aqueous solution of lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI). A second chamber adjacent the first chamber has a gold coated gas diffusion layer counter electrode and the water-in-salt electrolyte. The second chamber being separated from the first chamber by a proton exchange membrane. A reservoir coupled to each of the first and the second chambers with a pump contains a volume of the water-in-salt electrolyte and a head space.

A flow cell for reducing carbon dioxide may include a first chamber having a gold coated gas diffusion layer working electrode, a reference electrode, and a water-in-salt electrolyte comprising a super concentrated aqueous solution of lithium bis-(trifluoromethanesulfonyl)imide (LiTFSI). A second chamber adjacent the first chamber has a gold coated gas diffusion layer counter electrode and the water-in-salt electrolyte. The second chamber being separated from the first chamber by a proton exchange membrane. A reservoir coupled to each of the first and the second chambers with a pump contains a volume of the water-in-salt electrolyte and a head space.

To make it possible to detect whether leakage is external leakage or cross leakage in a water electrolyzer, a valve installed in an oxygen-side path, and a valve installed in a hydrogen-side path are closed; a water electrolysis reaction at a water electrolytic cell is progressed, and leakage in the oxygen-side path and leakage in the hydrogen-side path are determined based on the change in an internal pressure; and a differential pressure is made between the oxygen-side path and the hydrogen-side path, and leakage from a solid polymer electrolyte membrane is determined based on the change in the differential pressure.

To make it possible to detect whether leakage is external leakage or cross leakage in a water electrolyzer, a valve installed in an oxygen-side path, and a valve installed in a hydrogen-side path are closed; a water electrolysis reaction at a water electrolytic cell is progressed, and leakage in the oxygen-side path and leakage in the hydrogen-side path are determined based on the change in an internal pressure; and a differential pressure is made between the oxygen-side path and the hydrogen-side path, and leakage from a solid polymer electrolyte membrane is determined based on the change in the differential pressure.

A portable hydrogen-oxygen generator includes a housing having a detachable upper cover and a bottom cover. An electrolytic cell module is arranged in the housing. The electrolytic cell module has a hydrogen generation chamber and an oxygen generation chamber. A cathode electrode plate and an anode electrode plate are respectively arranged in the hydrogen generation chamber and the oxygen generation chamber, and the bottoms of the two generation chambers are communicated for electrolyte circulation. A hydrogen outlet part and an oxygen outlet part detachably arranged on the upper cover and respectively corresponding to the hydrogen generation chamber and the oxygen generation chamber. A filtering film for removing water is arranged between the hydrogen/oxygen outlet part and the electrolytic cell module. A power supply module is arranged on the bottom cover of the housing to supply electric energy to the cathode electrode plate and the anode electrode plate.

A portable hydrogen-oxygen generator includes a housing having a detachable upper cover and a bottom cover. An electrolytic cell module is arranged in the housing. The electrolytic cell module has a hydrogen generation chamber and an oxygen generation chamber. A cathode electrode plate and an anode electrode plate are respectively arranged in the hydrogen generation chamber and the oxygen generation chamber, and the bottoms of the two generation chambers are communicated for electrolyte circulation. A hydrogen outlet part and an oxygen outlet part detachably arranged on the upper cover and respectively corresponding to the hydrogen generation chamber and the oxygen generation chamber. A filtering film for removing water is arranged between the hydrogen/oxygen outlet part and the electrolytic cell module. A power supply module is arranged on the bottom cover of the housing to supply electric energy to the cathode electrode plate and the anode electrode plate.

The present invention describes an electrochemical system (1) to electrochemically reduce carbon monoxide (CO) into liquid methanol and gaseous H.sub.2, comprising an electrochemical cell with an anodic compartment with an anode (2) with a current collector (2A), at least a catalyst to electrochemically oxidize H.sub.2O, and a cathodic compartment with a cathodic electrolyte solution comprising the solvent (3), and a cathodic supporting electrolyte, the solvent (3) being water at basic pH of between 10.5 and 13.5, the reagent CO; a cathode (4) which comprises, on a current collector (4A) which is electrochemically inert, at least a cobalt molecular catalyst (4B) to electrochemically reduce CO into liquid methanol and the gas H.sub.2, a power supply (5) providing the energy necessary to trigger the electrochemical reactions involving the reagent.

The present invention describes an electrochemical system (1) to electrochemically reduce carbon monoxide (CO) into liquid methanol and gaseous H.sub.2, comprising an electrochemical cell with an anodic compartment with an anode (2) with a current collector (2A), at least a catalyst to electrochemically oxidize H.sub.2O, and a cathodic compartment with a cathodic electrolyte solution comprising the solvent (3), and a cathodic supporting electrolyte, the solvent (3) being water at basic pH of between 10.5 and 13.5, the reagent CO; a cathode (4) which comprises, on a current collector (4A) which is electrochemically inert, at least a cobalt molecular catalyst (4B) to electrochemically reduce CO into liquid methanol and the gas H.sub.2, a power supply (5) providing the energy necessary to trigger the electrochemical reactions involving the reagent.