The design of a metal inert anode is proposed, it is made in the form of a perforated structure with through-openings, in particular formed by longitudinal and transverse anode elements intersecting each other and limited by the lateral sides of the intersecting anode elements, and contains vertical or inclined fins that protrude from the bath and are integrated with the anode elements or a current conductor. As a result, it ensures a reduction in the voltage drop in the anode and in the bubble layer under the anode, a reduction in the anode overvoltage and anode consumption, an increase in current efficiency and the reliability of the cryolite-alumina crust, which leads to an increase in the anode service life and promotes the formation of a reliable and durable cryolite-alumina crust above the melt surface, which improves process efficiency.

The present document describes an electrolytic cell comprising a protective layer comprising elemental copper covering at least in part or all of a refractory material assembly covering an interior surface thereof. Also described is a copper oxide containing composition comprising copper oxide and any one of a reducing agent and a binder. Also described is a method of protecting a refractory material assembly covering an interior surface of an electrolytic cell, comprising covering at least in part, or all of the refractory material assembly with a copper sheet, a structure comprising elemental copper, a copper oxide, an elemental copper comprising composite material, a copper oxide containing composition and combinations thereof, to provide a protective layer comprising elemental copper.

The present document describes an electrolytic cell comprising a protective layer comprising elemental copper covering at least in part or all of a refractory material assembly covering an interior surface thereof. Also described is a copper oxide containing composition comprising copper oxide and any one of a reducing agent and a binder. Also described is a method of protecting a refractory material assembly covering an interior surface of an electrolytic cell, comprising covering at least in part, or all of the refractory material assembly with a copper sheet, a structure comprising elemental copper, a copper oxide, an elemental copper comprising composite material, a copper oxide containing composition and combinations thereof, to provide a protective layer comprising elemental copper.

A method for detecting a thermite reaction in an electrolytic cell comprising an anode assembly of one or more metal-oxide-containing anodes is disclosed. Each anode assembly is powered by a current provided through a distinct anode rod for each anode assembly. The method comprises: measuring a voltage drop using a pair of voltage probes located on the anode rod, the voltage drop corresponding to a current flow in the anode assembly; processing the voltage drop by computing at least one of the voltage drop derivative, the voltage drop variance, and the derivative of the voltage drop variance; and detecting a thermite reaction based on the results of the signal processing, before mitigating and/or suppressing the thermite reaction by adjusting the operational parameters of the electrolytic cell. This method is particularly advantageous as it reduces the number of voltage drops necessary for detecting a thermite reaction by a factor of 10.

A method for detecting a thermite reaction in an electrolytic cell comprising an anode assembly of one or more metal-oxide-containing anodes is disclosed. Each anode assembly is powered by a current provided through a distinct anode rod for each anode assembly. The method comprises: measuring a voltage drop using a pair of voltage probes located on the anode rod, the voltage drop corresponding to a current flow in the anode assembly; processing the voltage drop by computing at least one of the voltage drop derivative, the voltage drop variance, and the derivative of the voltage drop variance; and detecting a thermite reaction based on the results of the signal processing, before mitigating and/or suppressing the thermite reaction by adjusting the operational parameters of the electrolytic cell. This method is particularly advantageous as it reduces the number of voltage drops necessary for detecting a thermite reaction by a factor of 10.

An apparatus, also named transfer box or TB, for conveying an anode assembly outside of an electrolyte cell is described. An apparatus, also named cell preheater lifting beam or CPLB, for conveying an anode assembly or a cell pre-heater outside of an electrolyte cell is also disclosed. TB and CPLB are conjointly used for starting up the electrolytic cell or for replacing a spent anode assembly while maintaining the production of non-ferrous metal, such as aluminum or aluminium. The thermal insulation of the TB allows maintaining the anode temperature homogeneity and preventing thermal shocks when introducing the inert anodes into the hot electrolytic bath. TN and CPLB allow accurate positioning of anode assemblies or cell-preheaters over the electrolysis cell before achieving mechanical and electrical connections of the anode assembly or the cell pre-heater to the electrolysis cell. Several related methods for the operation of an electrolytic cell are also disclosed.

An apparatus, also named transfer box or TB, for conveying an anode assembly outside of an electrolyte cell is described. An apparatus, also named cell preheater lifting beam or CPLB, for conveying an anode assembly or a cell pre-heater outside of an electrolyte cell is also disclosed. TB and CPLB are conjointly used for starting up the electrolytic cell or for replacing a spent anode assembly while maintaining the production of non-ferrous metal, such as aluminum or aluminium. The thermal insulation of the TB allows maintaining the anode temperature homogeneity and preventing thermal shocks when introducing the inert anodes into the hot electrolytic bath. TN and CPLB allow accurate positioning of anode assemblies or cell-preheaters over the electrolysis cell before achieving mechanical and electrical connections of the anode assembly or the cell pre-heater to the electrolysis cell. Several related methods for the operation of an electrolytic cell are also disclosed.

An apparatus, also named transfer box or TB, for conveying an anode assembly outside of an electrolyte cell is described. An apparatus, also named cell preheater lifting beam or CPLB, for conveying an anode assembly or a cell pre-heater outside of an electrolyte cell is also disclosed. TB and CPLB are conjointly used for starting up the electrolytic cell or for replacing a spent anode assembly while maintaining the production of non-ferrous metal, such as aluminum or aluminium. The thermal insulation of the TB allows maintaining the anode temperature homogeneity and preventing thermal shocks when introducing the inert anodes into the hot electrolytic bath. TN and CPLB allow accurate positioning of anode assemblies or cell-preheaters over the electrolysis cell before achieving mechanical and electrical connections of the anode assembly or the cell pre-heater to the electrolysis cell. Several related methods for the operation of an electrolytic cell are also disclosed.

An apparatus, also named transfer box or TB, for conveying an anode assembly outside of an electrolyte cell is described. An apparatus, also named cell preheater lifting beam or CPLB, for conveying an anode assembly or a cell pre-heater outside of an electrolyte cell is also disclosed. TB and CPLB are conjointly used for starting up the electrolytic cell or for replacing a spent anode assembly while maintaining the production of non-ferrous metal, such as aluminum or aluminium. The thermal insulation of the TB allows maintaining the anode temperature homogeneity and preventing thermal shocks when introducing the inert anodes into the hot electrolytic bath. TN and CPLB allow accurate positioning of anode assemblies or cell-preheaters over the electrolysis cell before achieving mechanical and electrical connections of the anode assembly or the cell pre-heater to the electrolysis cell. Several related methods for the operation of an electrolytic cell are also disclosed.

In one embodiment, the disclosed subject matter relates to an electrolytic cell that has: a cell reservoir; a cathode support retained on a bottom of the cell reservoir, wherein the cathode support contacts at least one of: a metal pad and a molten electrolyte bath within the cell reservoir, wherein the cathode support includes: a body having a support bottom, which is configured to be in communication with the bottom of the electrolysis cell; and a support top, opposite the support bottom, having a cathode attachment area configured to retain a at least one cathode plate therein.