The invention discloses residual gas heat exchange combustion-supporting system based on a methanol-water mixture reforming hydrogen production system and a method thereof, wherein the residual gas heat exchange combustion-supporting system comprises a reformer, a heat exchange tube and an air intake device: the reformer is provided with a reforming chamber, a separating device, a combustion chamber and an exhaust vent, the residual gas produced by the reformer is discharged from the exhaust vent to the first delivery passage of the heat exchange, tube; the heat exchange tube has coaxial double-layer first and second delivery passages. The invention enables to fully reclaim the heat from the residual gas discharged by the reformer, so that the outside air is warmed before entering the reformer, which in turn makes the warmed outside air attain a very good combustion-supporting effect.

A hydrogen-selective membrane including a metal leaf applied to a substrate. A system and method for fabricating a hydrogen-selective membrane, including applying a metal leaf to a substrate, annealing the metal leaf, applying a hydrogen-permeable metal to the annealed metal leaf on the substrate, and annealing the hydrogen-permeable metal and the annealed metal leaf to give an alloy of the hydrogen-permeable metal and the metal leaf. A system and method for repairing a hydrogen-selective membrane having defects including applying a metal leaf to an external surface of membrane material of the hydrogen-selective membrane, annealing the metal leaf and metal of the membrane material to form an alloy of the metal leaf and the metal to repair the defects.

A method for synthesizing ammonia for agricultural fertilizers employs water (H2O) as the source of hydrogen (H2) in ammonia (NH3) synthesis, and gathers carbon monoxide (CO) as a limiting reagent for combining in a WGS (Water-Gas-Shift) reaction for producing hydrogen. The WGS reaction employs CO with the water to produce Carbon Dioxide (CO2) and H2, consuming undesirable CO from other industrial applications. A by-product of the process includes generating 1.5 mole of CO2 for each mole of ammonia synthesized. An intermediate step consumes 3 moles of hydrogen for each mole of Nitrogen (N2). The use of methane gas is avoided as the process employs CO and the WGS reaction as an exclusive source of H2 without introducing methane (CH4). A downstream synthesis of ammonia can be done through a fuel cell to produce electricity for the ammonia synthesis for further sustainability.

The present invention provides a hydrogen-releasing film and a hydrogen-releasing laminated film that have high reliability as a safety valve since defects such as cracks do not occur before the internal pressure of an electrochemical element reaches a predetermined pressure. The hydrogen-releasing film contains an alloy having Pd as an essential metal, and the size of the crystal grains in the alloy is 0.028 m or more.

The present invention relates to a method for preparing a hydrogen separation membrane capable of preventing the plating of Pd inside a porous support and a porous shielding layer when a separation membrane is prepared; a hydrogen separation membrane prepared therefrom; and a use thereof. In addition, the present invention relates to a device for preparing a hydrogen separation membrane; and a method for preparing a hydrogen separation membrane using the device, and in particular, relates to a device for preparing a hydrogen separation membrane capable of stably growing a Pd-containing separation membrane for hydrogen gas separation as a plating solution grows from the upper surface of a porous support to a uniform thickness by simply shielding the lower surface of the porous support when a hydrogen separation membrane is prepared using an electroless plating method. Furthermore, the present invention relates to a device for preparing a hydrogen separation membrane, and in particular, relates to a device for preparing a hydrogen separation membrane capable of stably growing a composite membrane for hydrogen gas separation as a plating solution grows from the top of a porous support to a uniform thickness by simply shielding the bottom of the porous support.

A system and a method for producing hydrogen are provided. An exemplary method includes desulphurizing a natural gas stream to form a sweet gas stream, converting higher hydrocarbons in the sweet gas stream to methane to form a methane stream, and converting a portion of the methane in the methane stream to a methane/syngas stream. A further portion of the methane in the methane/syngas stream is converted to form a syngas stream. The syngas stream is converted to a raw hydrogen stream and hydrogen is separated from the raw hydrogen stream.

A system and a method for producing hydrogen are provided. An exemplary method for producing hydrogen. The method includes desulfurizing a natural gas stream to form a sweet gas stream, converting higher hydrocarbons in the sweet gas stream to methane to form a methane stream, converting a portion of the methane in the methane stream to a syngas stream in a membrane reformer, and separating a portion of hydrogen from the syngas stream as a permeate stream from the membrane reformer. The retentate stream from the membrane reformer is fed to an autothermal reformer to form an oxidized stream. The membrane reformer is heated with the oxidizer stream.

A method of making a gas separation membrane by providing a plating vessel with a volume of plating solution of gas-selective metal ions into which is placed a porous support. The plating solution is circulated over a surface of the porous support while maintaining conditions within the plating vessel so as to promote the electroless deposition. The circulation rate of the plating solution is such as to enhance the metal deposition onto the surface of the porous support in the formation of the gas separation membrane.

Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure. In some embodiments, the devices may include a permeate frame having at least one membrane support structure that spans at least a substantial portion of an open region and that is configured to support at least one foil-microscreen assembly.

The disclosure relates to adapters, systems, and methods to connect a metal component and a ceramic component. The systems and methods generally include a metal header, a header seal and a zirconia toughened alumina (ZTA) header.