Provided is a chlorine dioxide generation device, suitable for long-term storage, discharging a chlorine dioxide-generating mixture that remains at an object of interest when used to thereby stably exhibit the effect of chlorine dioxide. A chlorine dioxide generation device, comprising: a first container containing a first composition comprising a chlorite and fumed silica; a second container containing a second composition comprising an acidic substance and fumed silica; an outer container housing the first container and the second container; a mixing section that mixes the first composition released from the first container and the second composition released from the second container to produce a mixed composition; and a discharging section that discharges the mixed composition produced by mixing in the mixing section.

A chlorine dioxide gas generator (100) is provided which capable of efficiently generating and gasifying a chlorine dioxide solution within a short period of time without accidental leakage, facilitating fumigation, and facilitating washing of the interior of the generator within a short period of time. The chlorine dioxide gas generator (100) includes a separation tank (20) that separates a chlorine dioxide gas (30b) from a chlorine dioxide solution (30a) generated in the reactor (10), the separation tank (20) including a separation cylinder (21), downwardly convex trays (22), upwardly convex tray covers (23), nubs (24) packed between the trays (22) and tray covers (23), a liquid supply pipe (25) communicating with an upper portion of the separation cylinder (21), and an air-mixture cylinder (27) that forms an air-mixture space (27a) around the separation cylinder (21) on a waste liquid chamber (26).

This invention relates to aqueous solutions that contain chlorine dioxide, particularly ultrapure aqueous solutions of chlorine dioxide that can be used, for example, in the field of human and veterinary medicine to disinfect surfaces, devices and instruments, as well as a process for producing such aqueous solutions of chlorine dioxide. In particular, this invention is a process for producing an aqueous solution of chlorine dioxide in which a previously produced aqueous solution of chlorine dioxide is treated so that an ultrapure aqueous solution of chlorine dioxide is obtained. The invented process can be applied to all previously produced aqueous solutions of chlorine dioxide, regardless of the process used to produce these. The invented process can be used in particular to produce ultrapure aqueous solutions of chlorine dioxide much more easily and inexpensively from previously produced aqueous solutions of chlorine dioxide. Surprisingly, it was discovered that the aqueous solutions of chlorine dioxide produced using the invented process show a high level of purity and a surprisingly high level of stability.

A composition for generating chlorine dioxide comprises active ingredients, a suitable hydrophobic compound, and a suitable super absorbent compound. A suitable hydrophobic compound will, among other characteristics, repel the solvent for at least the initial 30 seconds of exposure thereto. A suitable super absorbent compound will, among other characteristics, absorb at least 75 times its weight in solvent and will not gel until the chlorine-dioxide generating reaction is substantially complete.

An apparatus for preparing aqueous chlorine dioxide solutions is described, comprising (a) a reactor (1), (b) a first reservoir unit (8) comprising a first reactant for preparation of chlorine dioxide, the first reactant being in solid form, having an inlet (15) for water and a separate outlet (21), the first reservoir unit (8) being exchangeable, (c) a second reservoir unit (4) for storing a second reactant for preparation of chlorine dioxide. Additionally described are an exchangeable reservoir unit for such an apparatus, a kit comprising or consisting of one or more exchangeable reservoir units and a process for preparing a chlorine dioxide-containing solution usable directly for water treatment.

Preparation of an aqueous chlorine dioxide solution that reaches a first chlorine dioxide concentration during a first time period, and reaches a terminal concentration thereafter. A dilute solution of aqueous sodium chlorite or chlorate with predetermined concentration is produced, which yields the terminal chlorine dioxide concentration once an acid activator is added. The dilute solution is transferred through a conduit into a sanitization zone. The acid activator is injected into the conduit at a rate and concentration selected to reach the first chlorine dioxide concentration at the end of the first time period, with a flow rate such that the activated dilute solution of aqueous sodium chlorite has passed through the conduit prior to reaching the first chlorine dioxide concentration, which thereby limits exposure of the conduit to levels less than the first chlorine dioxide concentration.

Disclosed are devices, systems, and methods for producing broad spectrum disinfectants using a colloidal suspension of chlorine dioxide in deionized water, and more particularly, producing chlorine dioxide compositions that clean, disinfect and/or sterilize in one step with no harmful byproducts.

Methods, kits, cartridges, and compounds related to generating chlorine dioxide by exposing ClO.sub.2.sup.− to at least one of an iron porphyrin catalyst or an iron porphyrazine catalyst are described.

The present invention relates to a method of preparing chlorine dioxide (ClO.sub.2) from hydrochloric acid (HCl) and sodium chlorite (NaClO.sub.2) in the presence of water (H.sub.2O). The invention has for its object to further develop the method such that it is more economical to install and operate. The object is achieved when the hydrochloric acid is used in aqueous solution at a concentration of 27 to 33 wt %, the sodium chlorite is used in aqueous solution at a concentration of 22 to 27 wt % and the molar ratio of hydrochloric acid used to sodium chlorite used is between 2.14 and 4.2.

A chlorine dioxide gas generating agent pack includes a chlorine dioxide gas generating agent containing a mixture of chlorite powder, gas generation control agent powder, moisture-absorbent powder, water-absorbent resin powder, and activating agent powder; and a gas-permeable film container permeable to water vapor and chlorine dioxide gas and containing the chlorine dioxide gas generating agent. This chlorine dioxide gas generating agent pack is suitable for being carried to a region where sterilization, disinfection and deodorization are required.