A process for treating an H.sub.2S- and CO.sub.2-comprising fluid stream, in which a) the fluid stream is treated in a first absorber at a pressure of 10 to 150 bar with a first substream of a regenerated H.sub.2S-selective absorbent to obtain a treated fluid stream and an H.sub.2S-laden absorbent; b) the H.sub.2S-laden absorbent is heated by indirect heat exchange with regenerated H.sub.2S-selective absorbent; c) the heated HS-laden absorbent is decompressed to a pressure of 1.2 to 10 bar in a low-pressure decompression vessel to obtain a first CO.sub.2-rich offgas and a partly regenerated absorbent; d) the partly regenerated absorbent is regenerated in a desorption column to obtain an H.sub.2S-rich offgas and regenerated absorbent; e) the H.sub.2S-rich offgas is fed to a Claus unit and the offgas from the Claus unit is fed to a hydrogenation unit to obtain hydrogenated Claus tail gas; f) the hydrogenated Claus tail gas and the first CO.sub.2-rich offgas are treated in a second absorber at a pressure of 1 to 4 bar with a second substream of the regenerated H.sub.2S-selective absorbent to obtain a second CO.sub.2-rich offgas and a second H.sub.2S-laden absorbent; and g) the second H.sub.2S-laden absorbent is guided into the first absorber. Also described is a plant suitable for performance of the process. The process is notable for a low energy requirement.

Embodiments of the disclosure provide a method and a Claus tail gas treatment system for sulfur recovery. A tail gas stream is fed to a hydrogenation reactor to produce a hydrogenated gas stream by converting sulfur-containing compounds to hydrogen sulfide. The hydrogenated gas stream is fed to a quench tower to produce a quenched gas stream by condensing and recovering liquid water via a water condensate stream. The quenched gas stream is fed to a first stage adsorption unit to produce a first outlet gas stream by separating water via a first byproduct stream from hydrogen sulfide, carbon dioxide, and nitrogen. The first outlet stream is fed to a second stage adsorption unit to produce a second outlet gas stream by separating carbon dioxide and nitrogen via a second byproduct stream. The second outlet stream includes hydrogen sulfide. The second outlet stream can be fed to a Claus unit.

The invention relates to a gas scrubbing process for purifying crude synthesis gas with methanol as a physical absorption medium, wherein an acid gas comprising at least hydrogen sulfide (H.sub.2S) is produced. The acid gas is produced in a hot regenerator arranged downstream of an absorption apparatus and subsequently separated from gaseous methanol in an acid gas separator by cooling and condensation. The acid gas separator has a condensation region and an absorption region, wherein both regions are separated from one another by a gas-permeable tray. This has the result that impurities such as hydrogen cyanide and/or ammonia outgassing from a first acid gas substream are not reabsorbed in the condensation region of the acid gas separator, thus avoiding an accumulation of impurities in the hot regenerator or other parts of the gas scrubbing plant. The invention further relates to an acid gas separator and to the use of the acid gas separator according to the invention in a process according to the invention.

The present invention is directed to a process for the removal of aromatic hydrocarbons from a lean acid gas containing less than 20 mol. % of H.sub.2S, comprising: a) contacting the lean acid gas stream (1) with a H.sub.2S-selective liquid absorbent solution (29) in a first absorption zone (2) to produce a gas stream depleted in H.sub.2S (3) and an absorbent solution enriched in H.sub.2S (4), b) introducing the absorbent solution (4) into a non-thermic stripping zone (8) where it is contacted with a stripping gas stream (7) to obtain an absorbent solution depleted in C.sub.4.sup.+ aliphatic and aromatic hydrocarbons (9) and a stripping gas stream enriched in aromatic and C.sub.4.sup.+ aliphatic hydrocarbons (10), c) contacting the stripping gas stream (10) obtained in step b) with a H.sub.2S-selective liquid absorbent solution (28) in a second absorption zone (12) to obtain a stripping gas stream depleted in H.sub.2S (13), and an absorbent solution enriched in H.sub.2S (14) d) introducing the absorbent solution (9) obtained in step b) into a desorption zone (16) wherein the H.sub.2S-selective liquid absorbent solution (17) is recovered and a lean acid gas is produced.

To provide an inorganic solid material that has a hydrogen sulfide sustained releasability at ordinary temperature in the air atmosphere and is capable of being handled safely and a method for producing the same, and a method for generating hydrogen sulfide using the material. A layered double hydroxide having HS? and/or Sk2? (wherein k represents a positive integer) intercalated among layers (sulfide ion-containing LDH) is produced, and the sulfide ion-containing LDH is hermetically housed in a packaging material to provide a package. In generating hydrogen sulfide, the packaging material of the package is opened, and the sulfide ion-containing LDH is exposed to the air atmosphere to sustainably release hydrogen sulfide.

Techniques for generating electric power for well site operations include processing a hydrocarbon fluid produced from a subterranean formation, through a wellbore, and to a terranean surface into at least one acid gas; processing the at least one acid gas into hydrogen; generating, with the hydrogen, electrical power from a hydrogen engine; and providing the generated electrical power for use or storage to power at least one electrically-operated machine to perform at least one well site operation.

A method for recovering sulfur from an acid gas feed is provided. The method comprising the steps of mixing the acid gas feed and an absorption process outlet stream to form a combined Claus feed, introducing the combined Claus feed and a sulfur dioxide enriched air feed to a Claus process to produce a Claus outlet gas stream, introducing the Claus outlet gas stream to a thermal oxidizer, treating the thermal oxidizer outlet stream in a gas treatment unit to produce a dehydrated stream, introducing the dehydrated stream to a membrane sweeping unit to produce a sweep membrane residue stream and a sulfur dioxide enriched air feed, introducing a sweep air stream to a permeate side of the membrane sweeping unit, and introducing the sweep membrane residue stream to a sulfur dioxide absorption process to produce the absorption process outlet stream and a stack feed.

A method and a system to form hydrogen while removing sulfur from an acid gas stream are provided. An exemplary system includes a reaction furnace including a porous burner, an inlet for an oxygen stream into the porous burner, an inlet for the acid gas stream into the porous burner, and a plurality of inlets on the reaction furnace for injecting an inert coolant.

Systems and methods for separating CO.sub.2 and H.sub.2S from a natural gas stream are provided herein. The system includes a first loop of co-current contacting systems configured to remove H.sub.2S and CO.sub.2 from a natural gas stream and a second loop of co-current contacting systems configured to remove the H.sub.2S from the CO.sub.2.

This invention relates to processes for selective removal of contaminants from effluent gases. A sulfur dioxide absorption/desorption process for selective removal and recovery of sulfur dioxide from effluent gases utilizes a buffered aqueous absorption solution comprising weak inorganic or organic acids or salts thereof, to selectively absorb sulfur dioxide from the effluent gas. Absorbed sulfur dioxide is subsequently stripped to regenerate the absorption solution and produce a sulfur dioxide-enriched gas. A process for simultaneous removal of sulfur dioxide and nitrogen oxides (NO.sub.x) from effluent gases and recovery of sulfur dioxide utilizes a buffered aqueous absorption solution including a metal chelate to absorb sulfur dioxide and NO.sub.x from the gas and subsequently reducing absorbed NO.sub.x to form nitrogen. A process to control sulfate salt contaminant concentration in the absorption solution involves partial crystallization and removal of sulfate salt crystals.