The invention concerns a method for treating a hydrocarbon feed gas stream containing at least CO.sub.2 and H.sub.2S to recover a high quality purified CO.sub.2 gas stream, comprising a. Separating said hydrocarbon feed gas stream into a sweetened hydrocarbon gas stream, and an acid gas stream; b. Introducing said gas stream into a Claus unit, c. Introducing the tail gas into a hydrogenation reactor and then into a quench contactor of the Tail Gas Treatment Unit (TGTU); d. Contacting said tail gas stream with a non-selective amine-based solvent into a non-selective acid gas absorption unit of the TGTU; e. Sending the off gas to an incinerator; f. Contacting said enriched gas stream (vii) with a selective H.sub.2S-absorption solvent into a selective H.sub.2S-absorption unit thereby recovering a highly purified CO.sub.2 gas stream and a H.sub.2S-enriched gas stream, as well as the device for carrying said method.

A method to recover sulfur comprising the steps of feeding an acid gas stream to a combustion furnace, condensing the cooled furnace stream to produce a first gas stream, feeding the first gas stream to a first adsorber comprises a molecular sieve, feeding the first hot dry gas stream to a first catalytic reactor, cooling the first catalytic outlet stream in a first condenser, feeding the second gas stream to a second adsorber, feeding the second hot dry gas stream to a second catalytic reactor, cooling the second catalytic outlet stream in a second condenser, introducing the third gas stream to a third adsorber, feeding the third hot dry gas stream to a third catalytic reactor to produce a third catalytic outlet stream, and cooling the third catalytic outlet stream in a third condenser to produce a third sulfur stream and a tail gas stream.

The invention relates to a method for treating a hydrocarbon feed gas stream containing CO.sub.2 and H.sub.2S to recover a purified CO.sub.2 gas stream (vii), comprising: a. Separating said feed gas stream into a sweetened gas stream (i), and an acid gas stream (ii); b. Introducing stream (ii) into a Claus unit wherein an oxygen-rich stream is used as a combustive agent in the Claus furnace, thereby recovering a liquid stream of elemental sulfur (iii) and a tail gas stream (iv); c. Introducing the stream (iv) into a Tail Gas Treatment Unit (TGTU) thereby separating said tail gas stream into a CO.sub.2 enriched gas stream (v), and a stream enriched in sulfur compounds (vi); d. Compressing stream (v) exiting the TGTU; e. Passing the compressed CO.sub.2 enriched gas through a CO.sub.2 purification unit thereby recovering a purified CO.sub.2 gas stream (vii), and the device for carrying out said method.

A method for removing sulfur-containing compounds from a sulfur recovery unit (SRU) tail gas stream includes the steps of introducing the SRU tail gas stream to a reducing unit to produce a membrane feed, the reducing unit configured to reduce the sulfur-containing compounds to hydrogen sulfide, introducing the membrane feed to a hydrogen sulfide membrane unit, the hydrogen sulfide membrane unit comprising a membrane, wherein the membrane feed comprises hydrogen sulfide, allowing the membrane feed to contact a feed side of the membrane such that hydrogen sulfide permeates through the membrane to a permeate side, and collecting the retentate gases that fail to permeate through the membrane to produce a stack feed, wherein the stack feed comprises retentate gases.

A sulfur recovery unit (SRU) and method including converting hydrogen sulfide to elemental sulfur via the SRU having a reaction furnace and three catalytic reactors including a first catalytic reactor, a second catalytic reactor, and a third catalytic reactor disposed operationally in series, wherein catalyst in the first catalytic reactor consists of alumina catalyst, and wherein catalyst in the second catalytic reactor consists of a first layer of alumina catalyst, a second layer of hydrogenation catalyst, and a third layer of titania catalyst.

SETR tail gas treating process refers to an innovative process consist of the adsorbent and regeneration reactors. The SETR reactor stands for Super Enhanced Tail gas Recovery switching between adsorption and regeneration mode and the STER reactors are located after the tail gas incineration before the stack replacing any type of the caustic scrubber system. The SETR innovative process is not a sub dew point process where the bed become saturated with sulfur, instead, the SETR process are fixed bed reactors that requires heat up and cool down for the SO2 adsorption-based Claus tail gas process. The adsorption mode operates at cold temperature to adsorb the SO2. The regenerator mode operates at hot temperature to regenerate the SO2 by adding a slip stream of the H2S and air from the SRU to the SETR reactor that contains adsorbed SO2 to promote the Claus reaction. In the SETR reactors H2S to react with the adsorbed SO2 in the bed with oxygen the outlet of the hot reactor is recycled to the SRU thermal or catalytic section. The gas stream from the adsorbed cold reactor flows to the stack and it is SO2 free and zero emission is achieved.

A process and apparatus for recovering sulphur from a hydrogen sulphide containing gas stream are disclosed. A gas stream containing hydrogen sulphide gas is passed into an apparatus having a first thermal-reaction-region and a first catalytic region and reacting a portion of the hydrogen sulphide gas to sulphur dioxide and water and reacting a further portion to form sulphur vapor and water vapor to form a resultant-gas-mixture of water vapor, sulphur vapor, sulphur dioxide and hydrogen sulphide and passing a portion to the first catalytic-region whereby at least a portion of the hydrogen sulphide is reacted in the presence of a catalyst to form further sulphur vapor and water vapor and condensing at least a portion of sulphur vapor to form liquid sulphur and passing at least a portion of the liquid sulphur to a sulphur pit.

A horizontal sulfur condenser may include an exterior casing with a plurality of condenser tubes arranged longitudinally within the casing, a liquid sulfur reservoir at a longitudinal end within the exterior casing, and an internal baffle that protrudes into the liquid sulfur reservoir from the surface. The lowest of the plurality of condenser tubes is parallel to a wall of the exterior casing. A Claus process gas inlet is proximate a first end of the plurality of condenser tubes, which are arranged horizontally but are positioned vertically above the sulfur reservoir. A liquid sulfur outlet is located at the liquid sulfur surface. The baffle creates multiple chambers above the sulfur reservoir, such as a first chamber defined by the exterior casing and the baffle to receive condensed Claus sulfur in the liquid reservoir, and a second chamber defined by the exterior casing and the baffle to receive degassed liquid sulfur.

A method to recover sulfur comprising the steps of feeding an acid gas stream to a combustion furnace, condensing the cooled furnace stream to produce a first gas stream, feeding the first gas stream to a first adsorber comprises a molecular sieve, feeding the first hot dry gas stream to a first catalytic reactor, cooling the first catalytic outlet stream in a first condenser, feeding the second gas stream to a second adsorber, feeding the second hot dry gas stream to a second catalytic reactor, cooling the second catalytic outlet stream in a second condenser, introducing the third gas stream to a third adsorber, feeding the third hot dry gas stream to a third catalytic reactor to produce a third catalytic outlet stream, and cooling the third catalytic outlet stream in a third condenser to produce a third sulfur stream and a tail gas stream.

The invention concerns a method for treating a hydrocarbon feed gas stream containing at least CO.sub.2 and H.sub.2S to recover a high quality purified CO.sub.2 gas stream, comprising a. Separating said hydrocarbon feed gas stream into a sweetened hydrocarbon gas stream, and an acid gas stream; b. Introducing said gas stream into a Claus unit, c. Introducing the tail gas into a hydrogenation reactor and then into a quench contactor of the Tail Gas Treatment Unit (TGTU); d. Contacting said tail gas stream with a non-selective amine-based solvent into a non-selective acid gas absorption unit of the TGTU; e. Sending the off gas to an incinerator; f. Contacting said enriched gas stream (vii) with a selective H.sub.2S-absorption solvent into a selective H.sub.2S-absorption unit thereby recovering a highly purified CO.sub.2 gas stream and a H.sub.2S-enriched gas stream, as well as the device for carrying said method.