C01B32/174

Carbon nanotube dispersion and method for preparing the same

The present invention relates to a carbon nanotube dispersion including carbon nanotubes, a polymer dispersant containing an amine, a phenolic compound including two or more aromatic rings, and an aqueous solvent, wherein the polymer dispersant and the phenolic compound including two or more aromatic rings are included in a weight ratio of 100:1 to 100:90, and having low viscosity and a small change of viscosity over time.

ALKENE-DETECTION GAS SENSOR AND SYSTEM USING THE SAME
20220404303 · 2022-12-22 ·

[Object] To provide a compact and reusable alkene-detection gas sensor that detects an alkene and a system using the same.

[Solving Means] An alkene-detection gas sensor that detects an alkene in a sample gas according to the present invention includes: a first reaction unit that contains a palladium catalyst and oxidizes an alkene in a sample gas to convert the alkene into an aldehyde and/or a ketone; a second reaction unit that contains hydroxylamine salts and reacts with the aldehyde and/or ketone converted in the first reaction unit to generate an acid; and a response unit that includes an electrode supporting a semiconductor material of which an electrical resistance value changes by the generated acid, in which the palladium catalyst, the hydroxylamine salts, and the semiconductor material are separated from each other.

ALKENE-DETECTION GAS SENSOR AND SYSTEM USING THE SAME
20220404303 · 2022-12-22 ·

[Object] To provide a compact and reusable alkene-detection gas sensor that detects an alkene and a system using the same.

[Solving Means] An alkene-detection gas sensor that detects an alkene in a sample gas according to the present invention includes: a first reaction unit that contains a palladium catalyst and oxidizes an alkene in a sample gas to convert the alkene into an aldehyde and/or a ketone; a second reaction unit that contains hydroxylamine salts and reacts with the aldehyde and/or ketone converted in the first reaction unit to generate an acid; and a response unit that includes an electrode supporting a semiconductor material of which an electrical resistance value changes by the generated acid, in which the palladium catalyst, the hydroxylamine salts, and the semiconductor material are separated from each other.

METHOD FOR PRODUCING SEMICONDUCTING SINGLE-WALLED CARBON NANOTUBE DISPERSION
20220402761 · 2022-12-22 · ·

In one aspect, provided is a method for producing a semiconducting single-walled carbon nanotube dispersion. This method allows semiconducting single-walled carbon nanotubes to be separated from a single-walled carbon nanotube mixture containing semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes in an aqueous medium, and yet requires only an easily available separation agent and a simple operation.

One aspect of the present disclosure relates to a method for producing a semiconducting single-walled carbon nanotube dispersion. The method includes (A) preparing a single-walled carbon nanotube dispersion to be separated that contains single-walled carbon nanotubes composed of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes, an aqueous medium, and a copolymer containing a constitutional unit A derived from a monomer represented by the following formula (1) and a constitutional unit B derived from a monomer represented by the following formula (3), and (B) centrifuging the single-walled carbon nanotube dispersion to be separated and then collecting a supernatant containing the semiconducting single-walled carbon nanotubes from the centrifuged single-walled carbon nanotube dispersion.


CH.sub.2=CH−COOM  (1)


CH.sub.2=CR.sup.5−COO−(CH.sub.2CH.sub.2O).sub.q−H  (3)

METHOD FOR PRODUCING SEMICONDUCTING SINGLE-WALLED CARBON NANOTUBE DISPERSION
20220402761 · 2022-12-22 · ·

In one aspect, provided is a method for producing a semiconducting single-walled carbon nanotube dispersion. This method allows semiconducting single-walled carbon nanotubes to be separated from a single-walled carbon nanotube mixture containing semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes in an aqueous medium, and yet requires only an easily available separation agent and a simple operation.

One aspect of the present disclosure relates to a method for producing a semiconducting single-walled carbon nanotube dispersion. The method includes (A) preparing a single-walled carbon nanotube dispersion to be separated that contains single-walled carbon nanotubes composed of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes, an aqueous medium, and a copolymer containing a constitutional unit A derived from a monomer represented by the following formula (1) and a constitutional unit B derived from a monomer represented by the following formula (3), and (B) centrifuging the single-walled carbon nanotube dispersion to be separated and then collecting a supernatant containing the semiconducting single-walled carbon nanotubes from the centrifuged single-walled carbon nanotube dispersion.


CH.sub.2=CH−COOM  (1)


CH.sub.2=CR.sup.5−COO−(CH.sub.2CH.sub.2O).sub.q−H  (3)

ELECTROPHOTOGRAPHIC BELT, ELECTROPHOTOGRAPHIC IMAGE FORMING APPARATUS, METHOD OF PRODUCING ELECTROPHOTOGRAPHIC BELT, AND VARNISH
20220404750 · 2022-12-22 ·

Provided is an electrophotographic belt having an endless shape including a base layer, wherein the base layer includes a polyimide film containing polyimide serving as a binder resin and a carbon nanotube, wherein the polyimide has an imidization ratio of 80% or more, wherein the carbon nanotube has at least one resin selected from the group consisting of: polyphenylsulfone; polysulfone; and polyethersulfone present on at least part of a surface thereof. The base layer has a tensile strength of 200 MPa or more in each of a peripheral direction thereof and a direction perpendicular to the peripheral direction.

METHOD FOR PRODUCING SEMICONDUCTING SINGLE-WALLED CARBON NANOTUBE DISPERSION
20220388848 · 2022-12-08 · ·

In one aspect, provided is a method for producing a semiconducting single-walled carbon nanotube dispersion. This method allows semiconducting single-walled carbon nanotubes to be separated from a single-walled carbon nanotube mixture containing semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes in an aqueous medium, and yet requires only an easily available separation agent and a simple operation.

One aspect of the present disclosure relates to a method for producing a semiconducting single-walled carbon nanotube dispersion. The method includes (A) preparing a single-walled carbon nanotube dispersion to be separated that contains single-walled carbon nanotubes composed of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes, an aqueous medium, and a nonionic polymer containing a constitutional unit A derived from a monomer represented by the following formula (1), and (B) centrifuging the single-walled carbon nanotube dispersion to be separated and then collecting a supernatant containing the semiconducting single-walled carbon nanotubes from the centrifuged single-walled carbon nanotube dispersion. A content of the constitutional unit A in all constitutional units of the polymer is 2 mol % or more. The polymer is water soluble.


CH.sub.2═CR.sup.1—COO—(EO).sub.p(PO).sub.q—R.sup.2   (1)

METHOD FOR PRODUCING SEMICONDUCTING SINGLE-WALLED CARBON NANOTUBE DISPERSION
20220388848 · 2022-12-08 · ·

In one aspect, provided is a method for producing a semiconducting single-walled carbon nanotube dispersion. This method allows semiconducting single-walled carbon nanotubes to be separated from a single-walled carbon nanotube mixture containing semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes in an aqueous medium, and yet requires only an easily available separation agent and a simple operation.

One aspect of the present disclosure relates to a method for producing a semiconducting single-walled carbon nanotube dispersion. The method includes (A) preparing a single-walled carbon nanotube dispersion to be separated that contains single-walled carbon nanotubes composed of semiconducting single-walled carbon nanotubes and metallic single-walled carbon nanotubes, an aqueous medium, and a nonionic polymer containing a constitutional unit A derived from a monomer represented by the following formula (1), and (B) centrifuging the single-walled carbon nanotube dispersion to be separated and then collecting a supernatant containing the semiconducting single-walled carbon nanotubes from the centrifuged single-walled carbon nanotube dispersion. A content of the constitutional unit A in all constitutional units of the polymer is 2 mol % or more. The polymer is water soluble.


CH.sub.2═CR.sup.1—COO—(EO).sub.p(PO).sub.q—R.sup.2   (1)

SPHERICAL PARTICLES COMPRISING CARBON NANOMATERIAL-GRAFT-POLYMER AND METHODS OF PRODUCTION AND USES THEREOF

Highly spherical particles may comprise a thermoplastic polymer grafted to a carbon nanomaterial (CNM-g-polymer), wherein the particles have an aerated density of about 0.5 g/cm.sup.3 (preferably about 0.55 g/cm.sup.3) to about 0.8 g/cm.sup.3. Said CNM-g-polymer particles may be useful in a variety of applications including selective laser sintering additive manufacturing methods.

CARBON NANOTUBE DISPERSION LIQUID FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY, RESIN COMPOSITION USING THE SAME, MIXTURE SLURRY, ELECTRODE FILM, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY

A carbon nanotube dispersion liquid for nonaqueous electrolyte secondary battery is a carbon nanotube dispersion liquid containing carbon nanotubes, a dispersant and a solvent, and is characterized in satisfying (1) to (3) below: (1) the average outer diameter of the carbon nanotubes ranging from more than 3 nm to 25 nm; (2) the BET surface area of the carbon nanotubes ranging from 150 m.sup.2/g to 800 m.sup.2/g; and (3) the fiber length of the carbon nanotubes in the carbon nanotube dispersion liquid ranging from 0.8 μm to 3.5 μm.