Nanoplatelets are prepared from a 3D layered material by: providing a dispersion of the 3D layered material, pressurising the dispersion, rapidly depressurising the dispersion to create shear forces that exfoliate the 3D layered material into nanoplatelets; and/or providing a dispersion of the 3D layered material, forming a first flow of the dispersion along a first flowpath in a first direction, forming a second flow of the dispersion along a second flowpath in a second direction by reversing the first flow or by forming the second flow in a second flowpath, wherein the second flowpath is substantially reverse and non-coaxial with the first flowpath, whereby shear forces between material in the first flowpath and material in the second flowpath exfoliate the 3D layered material into nanoplatelets. Also provided are apparatuses for carrying out the invention and nanoplatelets obtained by the invention.

Embodiments described herein relate generally to the large scale production of functionalized graphene. In some embodiments, a method for producing functionalized graphene includes combining a crystalline graphite with a first electrolyte solution that includes at least one of a metal hydroxide salt, an oxidizer, and a surfactant. The crystalline graphite is then milled in the presence of the first electrolyte solution for a first time period to produce a thinned intermediate material. The thinned intermediate material is combined with a second electrolyte solution that includes a strong oxidizer and at least one of a metal hydroxide salt, a weak oxidizer, and a surfactant. The thinned intermediate material is then milled in the presence of the second electrolyte solution for a second time period to produce functionalized graphene.

Embodiments described herein relate generally to the large scale production of functionalized graphene. In some embodiments, a method for producing functionalized graphene includes combining a crystalline graphite with a first electrolyte solution that includes at least one of a metal hydroxide salt, an oxidizer, and a surfactant. The crystalline graphite is then milled in the presence of the first electrolyte solution for a first time period to produce a thinned intermediate material. The thinned intermediate material is combined with a second electrolyte solution that includes a strong oxidizer and at least one of a metal hydroxide salt, a weak oxidizer, and a surfactant. The thinned intermediate material is then milled in the presence of the second electrolyte solution for a second time period to produce functionalized graphene.

Provided is a metal matrix nanocomposite comprising: (a) a metal or metal alloy as a matrix material; and (b) multiple graphene sheets that are dispersed in said matrix material, wherein said multiple graphene sheets are substantially aligned to be parallel to one another and are in an amount from 0.1% to 95% by volume based on the total nanocomposite volume; wherein the multiple graphene sheets contain single-layer or few-layer graphene sheets selected from pristine graphene, graphene oxide, reduced graphene oxide, graphene fluoride, graphene chloride, graphene bromide, graphene iodide, hydrogenated graphene, nitrogenated graphene, doped graphene, chemically functionalized graphene, or a combination thereof and wherein the chemically functionalized graphene is not graphene oxide. The metal matrix exhibits a combination of exceptional tensile strength, modulus, thermal conductivity, and/or electrical conductivity.

A method is disclosed for preparation of nitrogen-doped graphene having these steps: a) providing a dispersion of fluorinated graphite; b) subjecting the dispersion of fluorinated graphite to sonication and/or mechanical treatment and/or thermal treatment; c) contacting the product from step b) with an azide reagent at a temperature within the range of 40 to 200° C.; d) separating the solid product formed in step c) from the mixture; e) dialyzing the product obtained in step d) against water. A nitrogen-doped graphene containing at least 8.9 at. % of nitrogen and up to 16.6 at. % of fluorine is yielded, wherein the at. % are relative to the total atoms present in the sample and determined by X-ray photoelectron spectroscopy (XPS) using an Al-Kα source; and having a density above 1.2 g/cm3 when pressed at 80 kN for 1 min. This nitrogen-doped graphene is particularly useful as a supercapacitor material.

A graphene composite film is produced for application to the anode of a battery. A graphene dispersion is peeled off of a graphite solvent mixture ultrasonically. The graphene material is then mixed with organic amine salt to be charged. Electrophoretic deposition is used to turn the graphene into a film. The film is then passed through a heat treatment to remove the organic amine salt. The resulting film is a highly conductive graphene film with a two-dimensional structure.

A graphene composite film is produced for application to the anode of a battery. A graphene dispersion is peeled off of a graphite solvent mixture ultrasonically. The graphene material is then mixed with organic amine salt to be charged. Electrophoretic deposition is used to turn the graphene into a film. The film is then passed through a heat treatment to remove the organic amine salt. The resulting film is a highly conductive graphene film with a two-dimensional structure.

A process for producing a highly conducting film of conductor-bonded graphene sheets that are highly oriented, comprising: (a) preparing a graphene dispersion or graphene oxide (GO) gel; (b) depositing the dispersion or gel onto a supporting solid substrate under a shear stress to form a wet layer; (c) drying the wet layer to form a dried layer having oriented graphene sheets or GO molecules with an inter-planar spacing d.sub.002 of 0.4 nm to 1.2 nm; (d) heat treating the dried layer at a temperature from 55° C. to 3,200° C. for a desired length of time to produce a porous graphitic film having pores and constituent graphene sheets or a 3D network of graphene pore walls having an inter-planar spacing d.sub.002 less than 0.4 nm; and (e) impregnating the porous graphitic film with a conductor material that bonds the constituent graphene sheets or graphene pore walls to form the conducting film.

A process for producing a highly conducting film of conductor-bonded graphene sheets that are highly oriented, comprising: (a) preparing a graphene dispersion or graphene oxide (GO) gel; (b) depositing the dispersion or gel onto a supporting solid substrate under a shear stress to form a wet layer; (c) drying the wet layer to form a dried layer having oriented graphene sheets or GO molecules with an inter-planar spacing d.sub.002 of 0.4 nm to 1.2 nm; (d) heat treating the dried layer at a temperature from 55° C. to 3,200° C. for a desired length of time to produce a porous graphitic film having pores and constituent graphene sheets or a 3D network of graphene pore walls having an inter-planar spacing d.sub.002 less than 0.4 nm; and (e) impregnating the porous graphitic film with a conductor material that bonds the constituent graphene sheets or graphene pore walls to form the conducting film.

Methods and reactors for electrochemically expanding a parent material and expanded parent materials are described. Current methods of expanding parent materials incompletely-expand parent material, requiring expensive and time-consuming separation of expanded parent material from unexpanded parent materials. This problem is addressed by the methods and reactor for electrochemically expanding a parent material described herein, which during operation maintain electrical connectivity between the parent material and an electrical power source. The resulting materials described herein have a greater proportion of expanded parent material relative to unexpanded parent material compared to those made according to others methods.