Patent classifications
C01B32/33
Production of carbon fiber from asphaltenes
There is provided a process and system for producing carbon fiber products. The process can involve deasphalting a heavy hydrocarbon feedstock, which can contain native asphaltenes, to produce a solid asphaltene particulate material, which can be further treated to produce the carbon fiber products. In some implementations, the solid asphaltene particulate material can be extruded in the presence of a polymer. In some implementations, the solid asphaltene particulate material can be chemically treated with a chemical agent including a Lewis acid, an oxidizing agent and/or a reducing agent before extrusion. In some implementations, the process can further produce activated carbon fibers.
Production of carbon fiber from asphaltenes
There is provided a process and system for producing carbon fiber products. The process can involve deasphalting a heavy hydrocarbon feedstock, which can contain native asphaltenes, to produce a solid asphaltene particulate material, which can be further treated to produce the carbon fiber products. In some implementations, the solid asphaltene particulate material can be extruded in the presence of a polymer. In some implementations, the solid asphaltene particulate material can be chemically treated with a chemical agent including a Lewis acid, an oxidizing agent and/or a reducing agent before extrusion. In some implementations, the process can further produce activated carbon fibers.
Sulfur-doped porous carbon derived from heavy hydrocarbons and methods for production thereof
Sulfur-crosslinked olefins, particularly sulfur-crosslinked heavy hydrocarbon products having one or more sulfur-crosslinked olefin moieties, may undergo pyrolysis to form sulfur-doped porous carbon having high BET surface area values. Pyrolysis to form the sulfur-doped porous carbon may be particularly efficacious in the presence of a hydroxide base. BET surface areas up to 2000 m.sup.2/g or even higher may be obtained. Such sulfur-doped porous carbon may be prepared by combining a heavy hydrocarbon product with sulfur, heating to a first temperature state to form a liquefied reaction mixture containing a sulfur-crosslinked heavy hydrocarbon, homogeneously mixing a hydroxide base with the liquefied reaction mixture, and pyrolyzing the sulfur-crosslinked heavy hydrocarbon to form sulfur-doped porous carbon.
Sulfur-doped porous carbon derived from heavy hydrocarbons and methods for production thereof
Sulfur-crosslinked olefins, particularly sulfur-crosslinked heavy hydrocarbon products having one or more sulfur-crosslinked olefin moieties, may undergo pyrolysis to form sulfur-doped porous carbon having high BET surface area values. Pyrolysis to form the sulfur-doped porous carbon may be particularly efficacious in the presence of a hydroxide base. BET surface areas up to 2000 m.sup.2/g or even higher may be obtained. Such sulfur-doped porous carbon may be prepared by combining a heavy hydrocarbon product with sulfur, heating to a first temperature state to form a liquefied reaction mixture containing a sulfur-crosslinked heavy hydrocarbon, homogeneously mixing a hydroxide base with the liquefied reaction mixture, and pyrolyzing the sulfur-crosslinked heavy hydrocarbon to form sulfur-doped porous carbon.
PRODUCTION OF CARBON FIBER FROM ASPHALTENES
There is provided a process and system for producing carbon fiber products. The process can involve deasphalting a heavy hydrocarbon feedstock, which can contain native asphaltenes, to produce a solid asphaltene particulate material, which can be further treated to produce the carbon fiber products. In some implementations, the solid asphaltene particulate material can be extruded in the presence of a polymer. In some implementations, the solid asphaltene particulate material can be chemically treated with a chemical agent including a Lewis acid, an oxidizing agent and/or a reducing agent before extrusion. In some implementations, the process can further produce activated carbon fibers.
PRODUCTION OF CARBON FIBER FROM ASPHALTENES
There is provided a process and system for producing carbon fiber products. The process can involve deasphalting a heavy hydrocarbon feedstock, which can contain native asphaltenes, to produce a solid asphaltene particulate material, which can be further treated to produce the carbon fiber products. In some implementations, the solid asphaltene particulate material can be extruded in the presence of a polymer. In some implementations, the solid asphaltene particulate material can be chemically treated with a chemical agent including a Lewis acid, an oxidizing agent and/or a reducing agent before extrusion. In some implementations, the process can further produce activated carbon fibers.
BIO-OIL LIGHT FRACTION-BASED BREAD-SHAPED POROUS ACTIVATED CARBON, METHOD FOR PREPARING THE SAME AND USE THEREOF
A bio-oil light fraction-based bread-shaped porous activated carbon, a method for preparing the same and use thereof are provided. A light fraction prepared by fast pyrolysis of a biomass coupled with molecular distillation is selected as a precursor; an activator is directly mixed with the light fraction and stirred to obtain a homogeneous liquid; then, the homogeneous liquid is subjected to one-step carbonization and activation at a two-stage temperature in an inert atmosphere; after the activation, the obtained solid was washed and filtered, the activator reaction products and impurities are removed, and then dried to obtain the activated carbon used as an electrode carbon material of a supercapacitor. The method fully utilizes the rich micromolecule compounds such as water, acids, ketones, aldehydes, monophenols and the like in the obtained light fraction, and the micromolecule compounds and water can interact with the activator.
BIO-OIL LIGHT FRACTION-BASED BREAD-SHAPED POROUS ACTIVATED CARBON, METHOD FOR PREPARING THE SAME AND USE THEREOF
A bio-oil light fraction-based bread-shaped porous activated carbon, a method for preparing the same and use thereof are provided. A light fraction prepared by fast pyrolysis of a biomass coupled with molecular distillation is selected as a precursor; an activator is directly mixed with the light fraction and stirred to obtain a homogeneous liquid; then, the homogeneous liquid is subjected to one-step carbonization and activation at a two-stage temperature in an inert atmosphere; after the activation, the obtained solid was washed and filtered, the activator reaction products and impurities are removed, and then dried to obtain the activated carbon used as an electrode carbon material of a supercapacitor. The method fully utilizes the rich micromolecule compounds such as water, acids, ketones, aldehydes, monophenols and the like in the obtained light fraction, and the micromolecule compounds and water can interact with the activator.
PROCESS FOR THE CONTROL OF SOFTENING POINTS OF PETROLEUM HYDROCARBON MATERIALS
The present disclosure relates to a method of treating hydrocarbon materials with thermoplastic nature that are liquid at room temperature or become liquid upon heating, to increase their softening point temperature up to 400° C. The method includes the steps of mixing a sulfur-containing gaseous catalyst with the hydrocarbon material in an environmentally controlled reactor, Heating the mixture to a temperature between 280° C. and 480° C. in a flowing gas environment and holding the mixture at this temperature for a period of time from 2 hours to 5 hours and stirring the mixture and maintaining stirring until the hydrocarbon material becomes solid.
PROCESS FOR THE CONTROL OF SOFTENING POINTS OF PETROLEUM HYDROCARBON MATERIALS
The present disclosure relates to a method of treating hydrocarbon materials with thermoplastic nature that are liquid at room temperature or become liquid upon heating, to increase their softening point temperature up to 400° C. The method includes the steps of mixing a sulfur-containing gaseous catalyst with the hydrocarbon material in an environmentally controlled reactor, Heating the mixture to a temperature between 280° C. and 480° C. in a flowing gas environment and holding the mixture at this temperature for a period of time from 2 hours to 5 hours and stirring the mixture and maintaining stirring until the hydrocarbon material becomes solid.