Patent classifications
C01B32/33
METHOD FOR PREPARING POROUS CARBON MATERIAL BY USING COAL TAR GENERATED IN COG PROCESS
A method for preparing a porous carbon material by using coal tar generated in a coke oven gas (COG) process is provided. The method includes: removing quinoline insoluble (QI) by mixing tetrahydrofuran (THF) with coal tar generated in a COG purification process; distilling coal tar by adding a phenolic resin to the QI-removed coal tar, and heating the same at a temperature of 100 C. to 330 C.; carbonizing the distilled coal tar by heating the same at 350 C. to 600 C.; mixing a carbide after the carbonization step and the coal tar, which has been distilled before the carbonization, and grinding/granulating the same; mixing the ground/granulated carbide and the coal tar, which has been distilled before the carbonization, with a pore forming agent, and heat treating the same at 300 C. to 500 C.; and forming pores by making the heat treated carbon material come into contact with water vapor at 700 C. to 1000 C.
SULFUR-DOPED POROUS CARBON DERIVED FROM HEAVY HYDROCARBONS AND METHODS FOR PRODUCTION THEREOF
Sulfur-crosslinked olefins, particularly sulfur-crosslinked heavy hydrocarbon products having one or more sulfur-crosslinked olefin moieties, may undergo pyrolysis to form sulfur-doped porous carbon having high BET surface area values. Pyrolysis to form the sulfur-doped porous carbon may be particularly efficacious in the presence of a hydroxide base. BET surface areas up to 2000 m.sup.2/g or even higher may be obtained. Such sulfur-doped porous carbon may be prepared by combining a heavy hydrocarbon product with sulfur, heating to a first temperature state to form a liquefied reaction mixture containing a sulfur-crosslinked heavy hydrocarbon, homogeneously mixing a hydroxide base with the liquefied reaction mixture, and pyrolyzing the sulfur-crosslinked heavy hydrocarbon to form sulfur-doped porous carbon.
SULFUR-DOPED POROUS CARBON DERIVED FROM HEAVY HYDROCARBONS AND METHODS FOR PRODUCTION THEREOF
Sulfur-crosslinked olefins, particularly sulfur-crosslinked heavy hydrocarbon products having one or more sulfur-crosslinked olefin moieties, may undergo pyrolysis to form sulfur-doped porous carbon having high BET surface area values. Pyrolysis to form the sulfur-doped porous carbon may be particularly efficacious in the presence of a hydroxide base. BET surface areas up to 2000 m.sup.2/g or even higher may be obtained. Such sulfur-doped porous carbon may be prepared by combining a heavy hydrocarbon product with sulfur, heating to a first temperature state to form a liquefied reaction mixture containing a sulfur-crosslinked heavy hydrocarbon, homogeneously mixing a hydroxide base with the liquefied reaction mixture, and pyrolyzing the sulfur-crosslinked heavy hydrocarbon to form sulfur-doped porous carbon.
Production of activated carbon
The disclosure provides a system and method for production of activated carbon from a coal-originating particulate feed material. Feed material and activating gas are introduced into a reaction chamber, the activating gas being introduced at a velocity above the average terminal velocity of particles within the feed material. Feed material is then entrained in the activating gas such that a recirculating flow path for the feed material is established within the reaction chamber. Activated material may then be recovered from the chamber.
Production of activated carbon
The disclosure provides a system and method for production of activated carbon from a coal-originating particulate feed material. Feed material and activating gas are introduced into a reaction chamber, the activating gas being introduced at a velocity above the average terminal velocity of particles within the feed material. Feed material is then entrained in the activating gas such that a recirculating flow path for the feed material is established within the reaction chamber. Activated material may then be recovered from the chamber.
METHOD FOR MANUFACTURING ACTIVATED CARBON FOR ELECTRODE MATERIAL
The present invention relates to a method for manufacturing activated carbon for electrode material, and, more specifically, to activated carbon having alkali metal content of 50 ppm or less for electrode material, and to a method for manufacturing the activated carbon. The activated carbon according to the present invention can lower the activation agent content, and thus is stable and can provide improved performance
Activated carbon
There is provided an activated carbon having a high total trihalomethane filtration capacity, even in water treatment by passing water at a high superficial velocity (SV). In the activated carbon of the present invention, a pore volume A of pores with a size of 1.0 nm or less, of pore volumes calculated by the QSDFT method, is 0.3 cc/g or more, and a pore volume B of pores with a size of 3.0 nm or more and 3.5 nm or less, of pore volumes calculated by the QSDFT method, is 0.009 cc/g or more.
PETROLEUM COKE TREATMENT APPARATUS, PROCESS, AND TREATMENT SYSTEM
An apparatus, a process and a system for treating petroleum coke are provided. The apparatus includes an activation unit that is an annular furnace reactor. The system includes a first reactor, the apparatus as a second reactor, a washing and separating unit, a cooling unit, a dissolving and separating unit, a washing and drying unit, optionally a regenerating unit, optionally a drying and calcining unit and optionally an evaporation-crystallization unit. The process for producing carbon materials uses the system for treating petroleum coke. The apparatus, the process and the system can achieve continuous production, and have advantages of high activation efficiency and stable properties of the resultant carbon material products.
PETROLEUM COKE TREATMENT APPARATUS, PROCESS, AND TREATMENT SYSTEM
An apparatus, a process and a system for treating petroleum coke are provided. The apparatus includes an activation unit that is an annular furnace reactor. The system includes a first reactor, the apparatus as a second reactor, a washing and separating unit, a cooling unit, a dissolving and separating unit, a washing and drying unit, optionally a regenerating unit, optionally a drying and calcining unit and optionally an evaporation-crystallization unit. The process for producing carbon materials uses the system for treating petroleum coke. The apparatus, the process and the system can achieve continuous production, and have advantages of high activation efficiency and stable properties of the resultant carbon material products.
MAGNETIC FIELD ENHANCED PLASMA FOR MATERIALS PROCESSING
A method, system and equipment (31) for activating biochar (29) includes flowing a reactive gas into a chamber (33; 305), using an electrical field to create a plasma (75) in the chamber, using a magnetic field (105) to increase density of the plasma and activating biochar with the plasma in the chamber. Use of inductive magnetic coil(s) (131) with an essentially closed loop magnetic field, and/or a permanent magnet(s) (101; 317) are also provided in a further aspect of the present method and apparatus. Another aspect causes magnetic densification of one or multiple plasmas in a chamber (305) to treat a previously produced layer of thin film (303).