The present invention relates to sheet silicate lamellae of a 2:1 sheet silicate with a high aspect ratio, to a method for producing these sheet silicate lamellae and to an aqueous dispersion which comprises the sheet silicate lamellae. The present invention further relates to the use of the sheet silicate lamellae of the invention for producing a composite material, and also to a corresponding composite material comprising or obtainable using the sheet silicate lamellae, more particularly for use as a diffusion barrier or as a flame retardant.

A stable dispersion of exfoliated layer substances is prepared through interlayer exfoliation of a layered compound. A dispersion including quaternary ammonium ions (A) each having a total carbon atom number of 15 to 45 and one or two C.sub.10-20 alkyl groups, and an anionic surfactant (B) having an ammonium ion, wherein plate-like particles (C) having an average thickness of 0.7 to 40 nm, an average major-axis length of 100 to 600 nm, an average minor-axis length of 50 to 300 nm, and a ratio of average major-axis length to average minor-axis length of 1.0 to 10.0 are dispersed in a liquid medium, and the plate-like particles (C) in the dispersion have an average particle diameter of 10 to 600 nm as measured by dynamic light scattering, and a transparent substrate using the dispersion.

An organoclay composition comprising a mineral clay mixture which has been treated with a combination of quaternary ammonium salts, said mixture comprising: mineral clay (a) comprising about 15 to about 60 wt. %, based on the weight of the mineral clay mixture, of sepiolite; mineral clay (b) comprising about 40 to about 85 wt. % based on the weight of the mineral clay mixture, of montmorillonite; an alkyl or alkenyl quaternary ammonium salt and an alkoxylated quaternary ammonium salt.

An organoclay composition comprising a mineral clay mixture which has been treated with a combination of quaternary ammonium salts, said mixture comprising: mineral clay (a) comprising about 15 to about 60 wt. %, based on the weight of the mineral clay mixture, of sepiolite; mineral clay (b) comprising about 40 to about 85 wt. % based on the weight of the mineral clay mixture, of montmorillonite; an alkyl or alkenyl quaternary ammonium salt and an alkoxylated quaternary ammonium salt.

According to the present disclosure, a method of forming an exfoliated or intercalated filler material is provided, wherein the said method comprises the steps of mixing particles of filler material such as montmorillonite (MMT), mica, layered double hydroxide (LDH), and attapulgite (AT) dispersed in an aqueous medium with cationic acrylate monomers to form modified particles comprising positively charged ions, dispersing the modified particles in organic medium to form a dispersion, contacting said dispersion with an organo-silicate such as tetraethyl orthosilicate (TEOS) and a functionalizing agent comprising an organo-silane such as aminopropyltrimethoxysilane (APTMS), in the presence of a basic catalyst to form a layer of silica on the modified particles. The present disclosure also relates to an exfoliated or intercalated filler material obtained by the said method as well as a method of forming a resin/clay nanocomposite.

According to the present disclosure, a method of forming an exfoliated or intercalated filler material is provided, wherein the said method comprises the steps of mixing particles of filler material such as montmorillonite (MMT), mica, layered double hydroxide (LDH), and attapulgite (AT) dispersed in an aqueous medium with cationic acrylate monomers to form modified particles comprising positively charged ions, dispersing the modified particles in organic medium to form a dispersion, contacting said dispersion with an organo-silicate such as tetraethyl orthosilicate (TEOS) and a functionalizing agent comprising an organo-silane such as aminopropyltrimethoxysilane (APTMS), in the presence of a basic catalyst to form a layer of silica on the modified particles. The present disclosure also relates to an exfoliated or intercalated filler material obtained by the said method as well as a method of forming a resin/clay nanocomposite.

The present invention is directed to processes for preparing a silicone surfactant intercalated clay and a polymer-clay nanocomposite. The processes use silicone surfactants having a molecular weight in the range of 10,000 to 100,000 Dalton to achieve fully exfoliating clay structures. Using these macromolecular silicone surfactants, along with the engineered control of the processing pH and drying stress conditions, this invention provides simple and low-cost methods of making a fully-exfoliated polymer-clay nanocomposite.

Insulation panel made from an insulation panel precursor comprising at least one modified layered silicate.

Insulation panel made from an insulation panel precursor comprising at least one modified layered silicate.

This invention deals with effect pigment comprising a colored hectorite which is produced by ion exchange process of an initial hectorite with a cationic dye, wherein the initial hectorite can be represented by the formula

K.sub.z/n[Li.sub.xMg.sub.(3.0(x+y)ySi.sub.4O.sub.10F.sub.2](I); wherein n is the charge of K and z=x+2y with 0.2<z<0.8; x=0-0.8; y=0-0.4; K is a cation chosen from a first group consisting of Li.sup.+, Na.sup.+, K.sup.+, NH.sub.4.sup.+, Rb.sup.+, Cs.sup.+, Mg.sup.2+, Ca.sup.2+, Ba.sup.2+ or mixtures thereof or from a second group consisting of alkylammonium salts with 2 to 8 C-atoms, wherein the alkyl can be branched or linear, or from a mixture of cations from the first and the second group and represents not occupied octahedral lattice sites.

Furthermore, these colored hectorites can have a coating thereon comprising at least one layer with a high index of refraction >1.8 or a semitransparent metal and optionally an outer protective layer.