Patent classifications
C01B39/085
ZEOLITE HAVING SPECIFIC RATIO OF DIVALENT COPPER IONS SUPPORTED THEREON, AND PREPARATION METHOD THEREFOR AND CATALYST COMPOSITION COMPRISING SAME
The present invention relates to zeolite containing Cu2+ (?) and Cu2+ (?) having different NO adsorption capacities loaded at a specific ratio, wherein the zeolite is chabazite (CHA)-type zeolite, particularly chabazite (CHA)-type zeolite loaded with divalent copper ions in which the NO adsorption area ratio of Cu2+ (?)/Cu2+ (?) after exposure to NO (nitrogen oxide) for 180 sec is 80% or more. In addition, the present invention relates to a method of preparing zeolite that is ion-exchanged in a slurry state and to a catalyst including the specified chabazite (CHA)-type zeolite.
Process for preparing a boron containing zeolitic material having MWW framework structure
A process for preparing an aluminum-free boron containing zeolitic material comprising the framework structure MWW (BMWW), comprising (a) hydrothermally synthesizing the BMWW from a synthesis mixture containing water, a silicon source, a boron source, and an MWW template compound obtaining the BMWW in its mother liquor, the mother liquor having a pH above 9; (b) adjusting the pH of the mother liquor, obtained in (a) and containing the BMWW, to a value in the range of from 6 to 9; (c) separating the BMWW from the pH-adjusted mother liquor obtained in (b) by filtration in a filtration device.
Molding for a hydrophobic zeolitic material and process for its production
The present invention relates to A process for the production of a molding, comprising (I) providing a zeolitic material; (II) mixing the zeolitic material provided in step (I) with one or more binders; (III) kneading of the mixture obtained in step (II); (IV) molding of the kneaded mixture obtained in step (III) to obtain one or more moldings; (V) drying of the one or more moldings obtained in step (IV); and (VI) calcining of the dried molding obtained in step (V); wherein the zeolitic material provided in step (I) displays a water adsorption ranging from 1 to 15 wt.-% when exposed to a relative humidity of 85%, as well as to a molding obtainable or obtained according to the inventive process in addition to a molding per se and to their respective use.
CHA-TYPE TITANOSILICATE SEPARATION MEMBRANE AND PRODUCTION METHOD THEREFOR AND GAS SEPARATION METHOD
The present invention provides a titanosilicate separation membrane which can also be used for separating a mixed gas containing a molecule having a relatively small size, has high durability in a high temperature environment, and has a high permeation rate and a high selectivity for a mixed gas containing water vapor. A titanosilicate separation membrane has a CHA-type titanosilicate crystal structure formed on a porous support, wherein aluminum is not substantially contained in the backbone of the titanosilicate crystal structure, and the titanosilicate crystal structure is constituted by silicon, oxygen, and titanium.
Method of synthesizing novel adsorbent titanosilicate material (UPRM-5) using NR4+ type cations
The invention employs tetrapropylammonium (TPA.sup.+) and tetrabutylammonium (TBA.sup.+) as structure directing agents (SDAs), respectively for the preparation of the flexible titanium silicate UPRM-5. Both UPRM-5 variants are detemplated and modified to include extraframework Sr.sup.2+ and produce materials for carbon dioxide adsorption.
Alumina silicate zeolite-type material having prolonged acid strength for use as a catalyst in selective catalytic reduction and process of making thereof
The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.
Zeolitic materials having a distinctive single crystal macroporosity and method for the production thereof
The invention relates to a zeolitic material comprising zeolitic monocrystals, each of which has a pore system encompassing at least one micropore system and at least one macropore system, and to a method for producing a zeolitic material of said type. In said method, porous oxide particles are converted into the zeolitic material in the presence of an organic template and steam.
Process for the preparation of an MWW zeolitic material comprising boron and titanium
A process for the preparation of a zeolitic material having an MWW framework structure and comprising boron and titanium, the process comprising (i) providing an aqueous synthesis mixture comprising a silica source, a boron source, a titanium source, and an MWW templating agent; (ii) heating the aqueous synthesis mixture to a temperature in the range of from 160 to 190 C.; (iii) subjecting the synthesis mixture (ii) to hydrothermal synthesis conditions, obtaining, in its mother liquor, a precursor of the zeolitic material; (iv) separating the precursor from its mother liquor; (v) calcining the separated precursor, obtaining the zeolitic material having an MWW framework structure and comprising boron and titanium.
Method of producing zeolite encapsulated nanoparticles
The invention therefore relates to a method for producing zeolite, zeolite-like or zeotype encapsulated metal nanoparticles, the method comprises the steps of: 1) Adding one or more metal precursors to a silica or alumina source; 2) Reducing the one or more metal precursors to form metal nanoparticles on the surface of the silica or alumina source; 3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the silica or alumina supported metal nanoparticles to form a carbon template coated zeolite, zeolite-like or zeotype precursor composition; 4a) Adding a structure directing agent to the carbon template coated zeolite, zeolite-like or zeotype precursor composition thereby creating a zeolite, zeolite-like or zeotype gel composition; 4b) Crystallising the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; 5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype encapsulated metal nanoparticles.
Method for producing zeolites and zeotypes
The invention relates to a method for producing zeolite, zeolite-like or zeotype particles comprising the steps of: 1) Adding one or more metal precursors to a silica or alumina source; 2) Reducing the one or more metal precursors to form metal nanoparticles on the surface of the silica or alumina source; 3) Passing a gaseous hydrocarbon, alkyl alcohol or alkyl ether over the silica or alumina supported metal nanoparticle to form a carbon template coated zeolite, zeolite-like or zeotype precursor composition; 4a) Adding a structure directing agent to the carbon template coated zeolite, zeolite-like or zeotype precursor composition thereby creating a zeolite, zeolite-like or zeotype gel composition; 4b) Crystallizing the zeolite, zeolite-like or zeotype gel composition by subjecting said composition to a hydrothermal treatment; 5) Removing the carbon template and structure directing agent and isolating the resulting zeolite, zeolite-like or zeotype particles.