Patent classifications
C01B2203/0244
Liquid fuel CPOX reformer and fuel cell systems, and methods of producing electricity
Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongated tube having a gas-permeable wall with internal and external surfaces. The wall encloses an unobstructed gaseous flow passageway. At least a portion of the wall has CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the CPOX reactor unit.
MEMBRANE MODULES FOR HYDROGEN SEPARATION AND FUEL PROCESSORS AND FUEL CELL SYSTEMS INCLUDING THE SAME
Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same are disclosed herein. The membrane modules include a plurality of membrane packs. Each membrane pack includes a first hydrogen-selective membrane, a second hydrogen-selective membrane, and a fluid-permeable support structure positioned between the first hydrogen-selective membrane and the second hydrogen-selective membrane. In some embodiments, the membrane modules also include a permeate-side frame member and a mixed gas-side frame member, and a thickness of the permeate-side frame member may be less than a thickness of the mixed gas-side frame member. In some embodiments, the support structure includes a screen structure that includes two fine mesh screens. The two fine mesh screens may include a plain weave fine mesh screen and/or a Dutch weave fine mesh screen. The fine mesh screens may be selected to provide at most 100 micrometers of undulation in the hydrogen-selective membranes.
Power generation system and method of operating power generation system
A power generation system includes: a combustor operative to combust a fuel; a power generator operative to utilize energy obtained from the combustor when generating electric power; a fuel supplier operative to supply the fuel to the combustor; an air supplier operative to supply combustion air to the combustor; a discharged gas passage through which a discharged gas from the combustor flows; a CO detector operative to detect CO in the discharged gas; a temperature detector operative to detect a temperature of the discharged gas; and control circuitry operative to, when the discharged gas is flowing through the discharged gas passage, perform at least one of an operation of detecting a structural abnormality of the discharged gas passage based on a difference between detected temperatures of the temperature detector relative to a difference between heated amounts of the discharged gas heated by a heater and an operation of detecting the structural abnormality of the discharged gas passage based on the difference between the detected temperatures of the temperature detector relative to a difference between outputs of at least one of the fuel supplier and the air supplier.
Process and plant for producing a synthesis gas product stream having an adjustable H.SUB.2./CO ratio and a pure hydrogen stream
Proposed are a process and a plant for producing a synthesis gas product stream having an adjustable H.sub.2/CO ratio and a pure hydrogen stream, wherein it is provided according to the invention that a substream of a deacidified synthesis gas stream is supplied to a membrane separation plant fitted with a hydrogen-selective membrane and the remaining substream is supplied to a pressure swing adsorption plant, wherein the latter affords a pure hydrogen stream and a fuel gas stream. The hydrogen-enriched permeate stream obtained from the membrane separation is likewise supplied to the pressure swing adsorption plant, thus enhancing the yield of pure hydrogen. The hydrogen-depleted retentate stream obtained from the membrane separation is discharged as a synthesis gas product stream and if of a suitable composition may be utilized as oxo gas.
Method for preparing synthetic fuel from natural gas of stranded gas field and associated gas from oil and gas fields by GTL-FPSO process
The present invention relates to a method for preparing a synthetic fuel on a vessel above a stranded gas field or an oil & gas field by a GTL-FPSO process, more particularly to a method for preparing a synthetic fuel with superior economic feasibility, productivity and efficiency using a compact GTL (gas to liquid) apparatus that can be used for a stranded gas field or an oil & gas field and an FPSO (floating production, storage and offloading) process under a condition optimized for the ratio of carbon dioxide in the stranded gas field or the oil & gas field and an apparatus for the same.
Hydrocarbon recovery from Fischer-Tropsch off-gas
The invention pertains to a method for processing a Fischer-Tropsch off-gas wherein Fischer-Tropsch off-gas is contacted with a wash fluid in a scrubber, and wherein the wash fluid is recycled in a closed loop with a dedicated scrubber, stripper and splitter. The wash fluid preferably is kerosene or LDF. The C.sub.3+ hydrocarbons that are recovered from the off-gas are, together with other Fischer-Tropsch product, subjected to hydrocracking or hydrocracking/hydroisomerization. Additionally, hydrogen is recovered from the off-gas.
PROCESS FOR PRODUCTION OF AMMONIA AND DERIVATIVES, IN PARTICULAR UREA
A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas engine; power produced by said gas engine; is transferred to at least one power user of the process, such as a compressor; heat is re-covered from exhaust gas of said gas engine;, and at least part of said heat may be recovered as low-grade heat available at a temperature not greater than 200° C., to provide process heating to at least one thermal user of the process, such as CO2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.
PROCESS FOR THE PRODUCTION OF UREA FORMALDEHYDE CONCENTRATE
Parallel co-production process for the production of methanol and urea product from a hydrocarbon containing feed-stock by means of autothermal reforming, intermediary methanol and ammonia formation and conversion of the ammonia to urea product and catalytic oxidation of the methanol to formaldehyde.
PROCESS FOR THE PRODUCTION OF UREA FORMALDEHYDE CONCENTRATE
Parallel co-production process for the production of methanol and urea product from a hydrocarbon containing feed-stock by means of primary and secondary reforming, intermediary methanol and ammonia formation and conversion of the ammonia to urea product and catalytic oxidation of methanol to formaldehyde.
PROCESS AND PLANT FOR PRODUCING HYDROCARBONS WITH REDUCED CO2-FOOTPRINT AND IMPROVED HYDROGEN INTEGRATION
Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.