Disclosed is a technology based upon the nesting of tubes to provide chemical reactors or chemical reactors with built in heat exchanger. As a chemical reactor, the technology provides the ability to manage the temperature within a process flow for improved performance, control the location of reactions for corrosion control, or implement multiple process steps within the same piece of equipment. As a chemical reactor with built in heat exchanger, the technology can provide large surface areas per unit volume and large heat transfer coefficients. The technology can recover the thermal energy from the product flow to heat the reactant flow to the reactant temperature, significantly reducing the energy needs for accomplishment of a process.

The present invention is directed to a method and system for enhancing the production of ammonia from gaseous hydrogen and nitrogen. Advantageously, the method and system does not emit carbon gases during production. The method and system enhances the production of ammonia compared to traditional Haber-Bosch reactions.

Process for the synthesis of ammonia comprising the steps of reforming of a hydrocarbon feedstock into a raw product gas, purification of said raw product gas obtaining a make-up synthesis gas, conversion of said synthesis gas into ammonia; said purification includes shift conversion of carbon monoxide into carbon dioxide and the reforming process requires a heat input which is at least partially recovered from at least one of said step of shift conversion, which is carried out with a peak temperature of at least 450 C., and said step of conversion into ammonia.

Method for improving efficiency of an existing ammonia synthesis gas plant or a new ammonia synthesis gas plant by establishing a combination of secondary steam reforming using oxygen from electrolysis of water for the production of ammonia synthesis gas.

A catalytic bed for a chemical reactor, said catalytic bed having an annular-cylindrical geometry and comprising at least one collector made with a gas-permeable cylindrical wall, containing at least a first catalyst and a second catalyst, wherein the second catalyst has a finer particle size than the first catalyst, and wherein the first catalyst forms a layer of catalyst adjacent to and in contact with said collector.

A chemical plant comprising a refrigeration system including an absorption refrigeration unit, and a steam system including one or more steam producers, steam users, and at least one steam condenser, wherein a heat exchanger is arranged to intercept at least part of a steam flow directed to said steam condenser, and said heat exchanger transfers heat to a working fluid of said absorption refrigeration unit to provide at least part of a heat input required for operation of said refrigeration system.

Embodiments of the disclosure provide an apparatus and process for producing ammonia. The apparatus includes a reactor having (i) an inlet to receive an inlet gas comprising nitrogen and hydrogen, (ii) a catalyst and an absorbent disposed within an internal volume of the reactor, the catalyst configured to convert the nitrogen and hydrogen to a reaction mixture including ammonia, unreacted nitrogen, and unreacted hydrogen, the absorbent configured to selectively absorb a portion of the ammonia in the reactor during formation of the reaction mixture, and (iii) an outlet to discharge the reaction mixture from the reactor.

Disclosed is a technology based upon the nesting of tubes to provide chemical reactors or chemical reactors with built in heat exchanger. As a chemical reactor, the technology provides the ability to manage the temperature within a process flow for improved performance, control the location of reactions for corrosion control, or implement multiple process steps within the same piece of equipment. As a chemical reactor with built in heat exchanger, the technology can provide large surface areas per unit volume and large heat transfer coefficients. The technology can recover the thermal energy from the product flow to heat the reactant flow to the reactant temperature, significantly reducing the energy needs for accomplishment of a process.

A method and device for producing ammonia from a syngas in a heterogeneous gas catalysis process in at least two reaction devices connected in series. Each reaction device includes at least two catalyst beds through which the syngas is conducted and in which an at least partial conversion of the syngas into the product gas is carried out. At least one first heat exchanger is provided in the first reaction device, and the fresh syngas is pre-heated in the first heat exchanger. The syngas exiting the first catalyst bed and which includes the product and non-converted reactants is cooled before entering the second catalyst bed. According to an embodiment of the invention, the pre-heating process is carried out in a first heat exchanger arranged between the first and the second catalyst bed. Thus, synthesis conversion can be increased without substantially increasing the process gas quantity.

In one aspect, the disclosure relates to relates to heterogeneous catalysts useful for the synthesis of ammonia under microwave irradiation, processes for preparing the disclosed heterogeneous catalysts, and processes for synthesizing ammonia using the heterogeneous catalysts with microwave irradiation. In various aspects, the disclosed heterogeneous catalysts comprise: a metal selected from Group 7, Group 8, Group 9, Group 10, Group 11, or combinations thereof; a metal oxide support; and optionally a promoter material. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.