The present application refers to a process for preparing of nanostructured metal oxides such as cobalt oxide and transition metal incorporated cobalt oxides and nickel aluminium oxides and nickel metal supported on aluminium oxide using plant material such as spent tea leaves as a hard template and the use of such catalysts for water oxidation.

The present invention relates to an electrochemical advanced oxidation process combined with a membrane in which electrode reactions and membrane filtration occur simultaneously, a water treatment device based on the electrochemical advanced oxidation process, and a water treatment system using the water treatment device. The electrochemical advanced oxidation process includes: providing a membrane electro-oxidation tank where electrodes are combined with a membrane; accommodating wastewater containing pollutants in the membrane electro-oxidation tank; and supplying power to the electrodes to decompose the pollutants and simultaneously separating particles through the membrane (water treatment). The electrodes are arranged downstream of the membrane. Gases released from the electrodes induce a vertical flow of the fluid to improve the contact efficiency between a reactive solution and the electrodes and remove the pollutants attached to the surface of the membrane. According to the present invention, a mechanism of decomposing pollutants using the electrodes and a mechanism of separating particles through the membrane take place simultaneously, enabling effective removal of the pollutants. The electrodes are arranged downstream of the membrane. With this arrangement, gases are produced from the electrodes to improve the electrolysis reactivity and the filtration efficiency of the membrane.

A boron doped diamond electrode and its preparation method and application, the electrode is deposited with a boron or nitrogen doped diamond layer or a boron or nitrogen doped diamond layer composite layer on the surface of the electrode substrate, or after a transition layer is disposed on the surface of the substrate, a boron or nitrogen doped diamond layer or a composite layer of boron or nitrogen doped diamond layer is disposed on the surface of transition layer. The preparation method is depositing or plating a boron or nitrogen doped diamond layer on the surface of the electrode substrate, or providing a transition layer on the surface of the electrode substrate, and then depositing or plating a boron or nitrogen doped diamond layer or a composite layer of boron or nitrogen doped diamond layer on the surface of the transition layer.

The present invention discloses a filter material for a culture system, and a preparation method and use thereof. The filter material comprises an anode material and a cathode material, wherein the anode material is an active metal, and the cathode material is an inactive metal or a conductive non-metal. The filter material can significantly improve the water quality in the culture system, be used for in-situ treatment of the water body in the culture system and be convenient to use. The filter material does not require additional application of voltage or current, and thus is safer. At the same time, the filter material has a long service life and does not need to be changed frequently. In addition, the preparation method of the filter material is simple, efficient, and environmentally friendly, and is advantageous for large-scale production.

A device for generating hydrogen gas, treated water, and metal-containing nanoparticles. The device includes a vessel containing an electrolyte solution having a preferably iron anode and a preferably copper cathode. A renewable energy source is connected to the anode and the cathode. A valve for disbursing the hydrogen is connected to the hydrogen chamber.

The present invention relates to a bio-electrochemical system (BES) and a method of in-situ production and removal of H.sub.2O.sub.2 using such a bio-electrochemical system (BES). Further, the invention relates to a method for in-situ control of H .sub.2O.sub.2 content in an aqueous system of advanced oxidation processes (AOPs) involving in-situ generation of hydroxyl radical (OH) by using such a bio-electrochemical system (BES) and to a method for treatment of wastewater and water disinfection. The bio-electrochemical system (BES) according to the invention comprises: an aqueous cathode compartment comprising a first cathode and a second cathode, an aqueous anode compartment comprising an anode at least partly covered in biofilm, wherein the first cathode is connected to a first circuit and the second cathode is connected to a second circuit, wherein the first and the second circuit are connected to the system by an external switch.

Wastewater containing scale components, organic substances, inorganic ions, and the like, such as human effluent, generated in a closed system space, such as a nuclear shelter, a hazardous shelter, a space station or a moon-Mars mission manned spacecraft, or a lunar base is efficiently treated by a simple structural apparatus, so that water is recovered. After a hardness component is removed from water to be treated, such as human effluent, by a softening device, and heat exchange is performed between softening treated water and electrolysis treated water by a heat exchanger, by a high-temperature and high-pressure electrolysis device, organic substances, urea, ammonia, and the like are removed by electrolysis performed under high-temperature and high-pressure conditions. After the electrolysis treated water is processed by a deaeration treatment using a deaeration membrane device, a desalting treatment is performed by acid/alkali manufacturing electrodialysis devices and provided in series at two stages.

The invention provides an electrode comprising a substrate and a coating on the substrate. The coating comprises a plurality of layers, including the following layers in sequence moving outwardly from the substrate: a base layer comprising an oxide of a valve metal; a lower layer comprising an oxide of a platinum group metal and/or an oxide of a precious metal; and a mixed oxide primary layer comprising both: (i) an oxide of a platinum group metal and/or an oxide of a precious metal, and (ii) an oxide of a valve metal and/or an oxide of a group 15 metal. The base layer is devoid of any platinum group metal oxide, and the lower layer is devoid of any valve metal oxide. The present invention also provides methods of manufacturing such electrodes. Also provide are methods of using an electrochemical cell equipped with a certain multilayer coated electrode.

A device for sewage treatment comprises a treatment tank, a power and electric control unit, a gas supply and tail gas recovery unit and a circular reaction treatment unit; the treatment tank is provided with a liquid inlet, a liquid outlet, a gas intake port and a tail gas exhaust port; the gas supply and tail gas recovery unit is communicated with the treatment tank through the gas intake port; the tail gas exhaust port is communicated with the gas supply and tail gas recovery unit; the circular reaction treatment unit comprises an external circulating device and a reaction treatment element arranged inside the treatment tank.

Illustrative embodiments employ catholyte scrubbers to provide higher concentrations of ozone in ozonated water than was possible in prior art systems and methods. Moreover, some embodiments employ scrubbers to increase the efficiency of production of ozonated water by producing such higher concentrations of ozone in ozonated water using the same amount, or less, power than prior art systems and methods. Some embodiments employ scrubbers to enable production of water with higher concentrations of ozone, and/or ozonated water in which the concentration of ozone decays more slowly, as compared to prior art methods.