A system and method of controlling the treatment of water systems comprises multiple feeders for separately feeding treatment products, in the form of concentrated, non-hazardous, liquids with a single active ingredient, to a water system to treat various issues, such as corrosion and biofilms. A sensor verifies delivery of the treatment product to the water system. A controller controls activation of each feeder to control a feed rate according to programmed functions. The controller receives signals from sensors, which can be used as inputs in calculating feed rates or feeder activation times according to the programed functions and can alter treatment product feed rates based on real time data regarding water system chemistry or flow rates. The controller can send and receive data, signals, alerts, alarms or changes in programming to or from remote users, remote computers, or a water system controller.

Corrosion inhibitor compositions are provided that can include a mixture of one or more alkaline earth metals, one or more organic phosphates, one or more inorganic phosphates, optionally a dispersant, and hydroxyphosphono acetic acid and/or salts thereof and/or derivatives of hydroxyphosphono acetic acid and/or salts thereof. Methods of mitigating or inhibiting corrosion of metal surfaces are also disclosed. The methods can include the steps of adding a corrosion inhibitor composition as described in the present disclosure to a medium in contact with the metal surface and optionally to the metal surface before it is contacted by the medium.

Methods and compositions for inhibiting corrosion of metal surfaces in aggressive fluids, including fluids with high total dissolved solids content. The treatment composition can include a stannous corrosion inhibitor and optionally an additive that enhances the corrosion inhibition properties of the stannous component. The additive may include organic compounds having at least one heteroatom.

Formation of CaSO.sub.4 and Fe.sub.2O.sub.3 containing deposits is reduced in a pressure oxidation autoclave and/or adjacent circuits during pressure oxidation of gold-containing ore. The gold-containing ore is combined with water to create an aqueous slurry that is heated and introduced into the autoclave. The method includes providing a scale inhibitor that is free of an organic polymer and includes an inorganic phosphate according to formula (I), (XPO.sub.3).sub.m, wherein X is Na, K, H, or combinations thereof, and m is at least about 6, an inorganic phosphate according to formula (II), Y.sub.n+2P.sub.nO.sub.3n+1, wherein Y is Na, K, H, an organic phosphonate; or combinations thereof, and n is at least about 6. The method includes the step of combining the scale inhibitor and at least one of the gold-containing ore, the water, and the aqueous slurry to reduce scale.

The invention provides a method of inhibiting corrosion of a metal in an industrial water system, the method comprising: (i) treating water of the industrial water system with a corrosion inhibiting-effective amount of a phosphorus-based treatment program comprising a phosphorus-based compound to provide a first treated industrial water, and (ii) treating the first treated industrial water with a corrosion inhibiting-effective amount of a metal-containing treatment program to provide a second treated industrial water, to inhibit corrosion of metal in the system.

An additive comprising one or more C.sub.3-C.sub.12 hydroxycarboxylic acids and/or one or more C.sub.3-C.sub.12 hydroxycarboxylic acid salts may be added to an aqueous system having galvanized metallurgy or a carbon steel surface in an effective amount to passivate a galvanized coating on the metallurgy or to decrease white rust formation or other types of corrosion upon the galvanized metallurgy or carbon steel surface in an aqueous system. In a non-limiting embodiment, the C.sub.3-C.sub.12 hydroxycarboxylic acid or the C.sub.3-C.sub.12 hydroxycarboxylic acid salt additive may utilize the zinc in the galvanized coating to achieve passivation. The passivation may occur while the system is shut down or in service. The aqueous system may be or include a cooling tower, a cooling water system, and combinations thereof. The additive may be used with or in the absence of a phosphorous-containing compound.

The present invention provides an industrial wastewater recovery apparatus (100) aiming at Zero Liquid Discharge (ZLD). The apparatus (100) provides two stages in pre-heating the spiral coil pipe (103) containing wastewater and also conserves the heat by using the two heat exchangers (104, 105). The apparatus (100) agitates the surface wastewater to increase the rate of evaporation for faster heating. The apparatus (100) provides two stages in condensation of distilled water and also provides real-time monitoring of the water quality. The apparatus (100) provides automatic cleaning in the various parts during the operations. Further, a plurality of IoT sensor (201) monitor the real time parameters of the industrial wastewater recovery apparatus (100) and data is available to the user on the electronic display device (204).

A composition for corrosion control in aqueous systems, the composition providing a formulation of a concentrated aluminum corrosion inhibitor; and (i) a polycarboxylic acid polymer, (ii) a sulfonic acid polymer, (iii) a combination of a polycarboxylic acid and a polysulfonic acid, (iv) an organic phosphonate, (v) a combination of a phosphonate and a polycarboxylic acid, or (vi) a combination of a phosphonate and a polysulfonic acid. A method for corrosion control in aqueous systems, the method providing a concentrated formulation, the concentrated formulation having an aluminum corrosion inhibitor and (i) a polycarboxylic acid polymer, (ii) a sulfonic acid polymer, (iii) a combination of a polycarboxylic acid and a polysulfonic acid, (iv) an organic phosphonate, (v) a combination of a phosphonate and a polycarboxylic acid, or (vi) a combination of a phosphonate and a polysulfonic acid; and delivering the concentrated formulation to an aqueous stream.

Inhibitors and methods for reducing or inhibiting corrosion and/or scale of metals in aqueous systems are provided. Inhibitor compositions may include a polymer and hydrophosphorylated polycarboxylic acids, such as 1-(hydroxyhydrophosphoryl)butane-1,2,3,4-tetracarboxylic acid. The compositions may include other components, such as zinc, molybdate, silicate, cerium, among others. The disclosed hydrophosphorylated polycarboxylic acids are stable in the presence of biocides.

The present invention relates to the use of phospho-tartaric acid and/or the salts thereof for the treatment of water in water-conducting systems.