A method for treating a mold includes grinding an outer metal surface of a mold body of the mold with a first material; lapping the outer metal surface after the grinding with a second material that is finer than the first material; and polishing the outer metal surface after the lapping to achieve an average surface roughness (R.sub.a) less than or equal to about 0.15 m and a waviness height (W.sub.a) less than or equal to about 100 nm. A mold for shaping glass-based material can include a mold body having an outer metal surface, wherein the outer metal surface has an average surface roughness (R.sub.a) less than or equal to about 0.15 m and a waviness height (W.sub.a) less than or equal to about 100 nm.

Described are glass-forming molds made of a graphite mold body and a coating formed by atomic layer deposition, with the coating being made of alumina or a combination of alumina and yttria.

An optical element molding mold set includes a first mold and a second mold that are opposite to each other, and a third mold that is located on an outer periphery of a cavity between the first mold and the second mold, and an inner peripheral surface of the third mold has different friction coefficients between one side and another side in an opposite direction of the first mold and the second mold.

An amorphous alloy contains Ni and Nb and has a composition including at least one of: a composition containing Nb with a content in the range of 35.6 atomic % to 75.1 atomic %, Ir with a content in the range of 7.2 atomic % to 52.3 atomic %, and Ni with a content in the range of 4.0 atomic % to 48.5 atomic %; a composition containing Nb with a content in the range of 19.6 atomic % to 80.9 atomic %, Re with a content in the range of 7.4 atomic % to 59.2 atomic %, and Ni with a content in the range of 4.1 atomic % to 56.9 atomic %; and a composition containing Nb with a content in the range of 7.5 atomic % to 52.9 atomic %, W with a content in the range of 16.4 atomic % to 47.0 atomic %, and Ni with a content in the range of 22.0 atomic % to 53.3 atomic %.

An amorphous alloy contains Ni and Nb and has a composition including at least one of: a composition containing Nb with a content in the range of 35.6 atomic % to 75.1 atomic %, Ir with a content in the range of 7.2 atomic % to 52.3 atomic %, and Ni with a content in the range of 4.0 atomic % to 48.5 atomic %; a composition containing Nb with a content in the range of 19.6 atomic % to 80.9 atomic %, Re with a content in the range of 7.4 atomic % to 59.2 atomic %, and Ni with a content in the range of 4.1 atomic % to 56.9 atomic %; and a composition containing Nb with a content in the range of 7.5 atomic % to 52.9 atomic %, W with a content in the range of 16.4 atomic % to 47.0 atomic %, and Ni with a content in the range of 22.0 atomic % to 53.3 atomic %.

A mold for shaping glass-based material can include a mold body having a surface, wherein at least a portion of the mold body near the surface comprises at least about 90% by weight nickel and from about 0.2% to about 0.35% by weight manganese; and a nickel oxide layer on the surface of the mold body. The nickel oxide layer has first and second opposing surfaces wherein the first surface of the nickel oxide layer contacts and faces the surface of the mold body and the second surface of the nickel oxide layer includes a plurality of grains. The plurality of grains has an average grain size of about 150 m or less.

A process deciding method in a method of manufacturing an optical element by heating and press-molding an optical material to mold the optical element using a molding die on which a release film is formed, includes a basicity degree identifying process in which a degree of basicity of the optical material is identified; and a removing process determining process of determining whether to perform one or both of first removing process in which an oxidizing substance is removed and a second removing process in which a basic substance is removed from at least one of a surface of the optical material and a surface of the release film by comparing the degree of basicity of the optical material identified in the basicity degree identifying process with a predetermined reference value, before press-molding the optical material.

A mold with a multi-layer coating is disclosed. The mold may include a mold body having an outer surface and a multi-layer coating disposed on the outer surface. The multi-layer coating may include a diffusion barrier layer disposed on the outer surface of the mold body and an intermetallic layer disposed on the diffusion barrier layer, wherein the intermetallic layer comprises Ti, Al, and an additional metal selected from the group consisting of Zr, Ta, Nb, Y, Mo, Hf, and combinations thereof The diffusion barrier layer may restrict diffusion of metal from the mold body to the intermetallic layer.

A powder useful for making a mold utilized for shaping glass-based materials includes at least about 50% by weight nickel. Metal oxides that are not miscible with nickel may be dispersed within the powder in an amount in a range from about 0.2 to about 15% by volume. A mold made from the powder may have a mold body having a composition comprising at least 50% by weight nickel and a metal oxide that is not miscible with nickel in an amount in a range from about 0.2 to about 15% by volume, a nickel oxide layer on a surface of the mold body wherein the nickel oxide layer has first and second opposing surfaces, the first surface of the nickel oxide layer contacts and faces the surface of the mold body, the second surface of the nickel oxide layer includes a plurality of grains, and the plurality of grains has an average grain size of about 100 m or less.

Refractory glass-forming tools, including glass-forming molds incorporating protective metal nitride surface coatings, with optional alumina barrier layers disposed between the mold bodies and coating for high-temperature nitride coating stability, offering particular advantages for the manufacture by direct molding of optically finished glass products such as information display cover glasses from refractory alkali aluminosilicate glasses at molding temperatures up to and above 800 C.