A system and method for nitridizing a glass article includes supplying a source of a nitridizing gas including gaseous NH.sub.3 to a glass article supported within a furnace assembly and heating the glass article. In some embodiments, the system includes a handle assembly configured to support the glass article within the furnace assembly and a gas supply conduit carried by the handle and configured to supply the nitridizing gas to the glass article. In some embodiments, a method of nitridizing a glass article includes supplying the nitridizing gas such that a residence time of the nitridizing gas at temperatures greater than 500° C. corresponds to a predetermined time period. In some embodiments, a method of nitridizing a glass article includes supplying the nitridizing gas such that the glass articles is exposed to the nitridizing gas within a contact time t.sub.c.

An optical fiber includes: a core; and a cladding layer disposed on an outer circumference of the core. A Cl concentration in the cladding layer is 0.029 wt % to 0.098 wt %. In the optical fiber, Δ2−Δ1≤0 dB/km is satisfied at a wavelength of 430 nm where Δ1 is a value of transmission loss before exposure of the optical fiber to hydrogen and Δ2 is a value of transmission loss after the exposure.

The present invention relates to a method for manufacturing a preform for optical fibers, which method comprises the sequential steps of: i) deposition of non-vitrified silica layers on the inner surface of a hollow substrate tube; ii) deposition of vitrified silica layers inside the hollow substrate tube on the inner surface of the non-vitrified silica layers deposited in step i); iii) removal of the hollow substrate tube from the vitrified silica layers deposited in step ii) and the non-vitrified silica layers deposited in step i) to obtain a deposited tube; iv) optional collapsing said deposited tube obtained in step iii) to obtain a deposited rod comprising from the periphery to the center at least one inner optical cladding and an optical core; v) preparation of an intermediate layer by the steps of: * deposition of non-vitrified silica layers on the outside surface of the deposited tube obtained in step iii) or deposited rod obtained in step iv) with a flame hydrolysis process in an outer reaction zone using glass-forming precursors, and subsequently; * drying and consolidating said non-vitrified silica layers into a vitrified fluorine-doped silica intermediate cladding layer; and * in case preceding step iv) was omitted collapsing; to provide a solid rod comprising from the periphery to the center the intermediate layer, at least one inner optical cladding and an optical core; wherein a fluorine-comprising gas is used during the deposition and/or drying and/or consolidating and wherein the intermediate layer has a ratio between the outer diameter of the intermediate cladding layer (C) to the outer diameter of the optical core (A) that is at least 3.5; vi) deposition of natural silica on the outside surface of the intermediate cladding layer of the solid rod obtained in step v) by melting natural silica particles in an outer deposition zone to produce an outer cladding whereby a preform is obtained.

An optical preform manufacturing process is disclosed in which an alkali dopant is deposited between an optical fiber core rod and an optical fiber cladding jacket. Depositing the alkali dopant between the core rod and the cladding jacket permits diffusion of the alkali dopants into the core during fiber draw when the core and the cladding are at their respective transition (or vitrification) temperatures. Introduction of the alkali dopants between the core rod and the cladding jacket also permits decoupling of the alkali doping process from one or more of other optical preform manufacturing processes. The optical preform manufacturing process can also include placing alkali dopants between an optical fiber inner cladding jacket and an optical fiber outer cladding jacket to reduce the glass viscosity during fiber draw.

A method for manufacturing an optical fiber preform includes generating glass particles from a glass raw material gas in a flame obtained by combustion of a combustible gas supplied to a burner and depositing the glass particles on an outer circumference of a silica glass pipe to form a hollow porous glass preform, inserting a rod into the silica glass pipe, transparently vitrifying the porous glass preform by heating the porous glass preform after inserting the rod to obtain a transparent glass preform, drawing out the rod from the silica glass pipe after the porous glass preform is transparently vitrified, and removing the silica glass pipe from the transparent glass preform by etching after drawing out the rod.

Provided is an optical fiber glass preform in which a starting rod and a dummy glass are hardly separated from each other, and a method for manufacturing the glass preform. In the optical fiber glass preform, the dummy glass is fitted into one end of the starting rod, and a part of the dummy glass and the starting rod are surrounded by a clad glass. In the manufacturing method, at the time of connecting the starting rod and the dummy glass, a shape is adjusted in such a manner that an iron is brought into contact with a connection portion and is moved from a starting rod side toward a dummy glass side with appliance of a load.

A method of producing an optical fiber preform includes a silica glass body forming step of forming a silica glass body to be at least a portion of a core portion. The method includes an alkali-metal-doped silica glass body forming step of forming an alkali-metal-doped silica glass body doped with an alkali metal around the silica glass body such that the alkali-metal-doped silica glass body contacts the silica glass body. The method further includes a diffusing step of diffusing the alkali metal from the alkali-metal-doped silica glass body to the silica glass body by a heat treatment.

According to embodiments, a method of making a microstructured glass article includes bundling M bare optical fibers in a fiber bundle, wherein M is an integer greater than 100. Thereafter, the fiber bundle may be inserted in a cavity of a soot preform. The soot preform may have a density of less than or equal to 1.5 g/cm.sup.3 and comprise silica-based glass soot. The soot preform and inserted fiber bundle may then be consolidated to form a microstructured glass article preform. The microstructured glass article preform may then be drawn into the microstructured glass article comprising M core elements embedded in a cladding matrix.

According to embodiments, a method of making a micro structured glass article 100 includes bundling M bare optical fibers in a fiber bundle, wherein M is an integer greater than 100. Thereafter, the fiber bundle may be inserted in a cavity of a soot preform. The soot preform may have a density of less than or equal to 1.5 g/cm3 and comprise silica-based glass soot. The soot preform and inserted fiber bundle may then be consolidated to form a microstructured glass article preform. The micro structured glass article preform may then be drawn into the microstructured glass article 100 comprising M core elements 102 embedded in a cladding matrix 104.

A method for elongating a glass preform for an optical fiber is provided for producing a glass rod having a smaller diameter by elongating the glass preform having a large diameter, the method including: when the glass preform having a tapered transparent glass portion at one end of a straight body of the glass preform and a tapered portion including an opaque glass portion at another end is elongated, prior to the elongating, cutting a part of the tapered portion including the opaque glass portion, wherein a cut surface of the part is a lower end of the glass preform; and welding the cut surface of the tapered portion to a pulling dummy connected to a pulling mechanism in a elongating apparatus, wherein the cut surface is circular and has an outer diameter ranging from 135 mm to 160 mm.