A method of producing an optical fiber preform includes: an alkali-metal-doped silica glass body forming step of forming an alkali-metal-doped silica glass body doped with an alkali metal; a silica glass body forming step of forming a silica glass body to be at least a portion of a core portion around the alkali-metal-doped silica glass body such that the silica glass body contacts the alkali-metal-doped silica glass body; and a diffusing step of diffusing the alkali metal from the alkali-metal-doped silica glass body to the silica glass body by a heat treatment.

The optical fiber offered is capable of not only restraining the attenuation due to glass defects, but also reducing the increase of manufacturing cost. The optical fiber is made of silica glass and includes a core and a cladding. The cladding encloses the core and has a refractive index smaller than that of the core. When the core is divided into inner core and outer core at half of the radius of the core, the average chlorine concentration of the inner core is larger than that of the outer core. The core includes any of the alkali metal group.

Methods for manufacturing fluorine-doped glass preforms for optical fibers are disclosed. An exemplary method includes exposing a soot preform to an atmosphere containing a fluorine-containing gas in a first elongated chamber of a first furnace. The first elongated chamber typically has a single isothermal hot zone, which may be maintained at a doping temperature of about 800 C. to 1200 C., to obtain a fluorine-doped soot preform. The exemplary method further includes dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas in a second elongated chamber of a second furnace. The second elongated chamber typically has an upper hot zone, which may be maintained at a dehydration temperature of about 1000 C. to 1350 C., and a lower hot zone, which may be maintained at a consolidation temperature of about 1500 C. to 1650 C. Dehydration of the fluorine-doped soot preform typically occurs in the upper hot zone of the second furnace. The exemplary method further includes consolidating the fluorine-doped soot preform within the lower hot zone of the second furnace to form a fluorine-doped glass preform.

A co-doped optical fiber is provided having an attenuation of less than about 0.17 dB/km at a wavelength of 1550 nm. The fiber includes a core in the fiber having a graded refractive index profile with an alpha of greater than 5. The fiber also includes a cladding in the fiber that surrounds the core addition, the core includes silica that is co-doped with two or more halogens.

An optical fiber includes: a core; and a cladding layer disposed on an outer circumference of the core. A Cl concentration in the cladding layer is 0.029 wt % to 0.098 wt %. In the optical fiber, 210 dB/km is satisfied at a wavelength of 430 nm where 1 is a value of transmission loss before exposure of the optical fiber to hydrogen and 2 is a value of transmission loss after the exposure.

A method of forming an optical fiber, including: exposing a soot core preform to a dopant gas at a pressure of from 1.5 atm to 40 atm, the soot core preform comprising silica, the dopant gas comprising a first halogen doping precursor and a second halogen doping precursor, the first halogen doping precursor doping the soot core preform with a first halogen dopant and the second halogen precursor doping the soot core preform with a second halogen dopant; and sintering the soot core preform to form a halogen-doped closed-pore body, the halogen-doped closed-pore body having a combined concentration of the first halogen dopant and the second halogen dopant of at least 2.0 wt %.

Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration and sintering halogen-doped silica to a closed-pore state in a gas-phase environment that has a low partial pressure of impermeable gases. Impermeable gases are difficult to remove from halogen-doped fiber preforms and lead to defects in optical fibers drawn from the preforms. A low partial pressure of impermeable gases in the sintering environment leads to a low concentration of impermeable gases and a low density of gas-phase voids in densified halogen-doped silica. Preforms with fewer defects result.

A method of manufacturing a glass core preform for an optical fibre comprising: providing a porous soot core preform having an outer surface) and a central hole extending axially therethrough; dehydrating the porous soot core preform at a first temperature by exposing the outer surface of the preform to an atmosphere containing chlorine, and simultaneously consolidating the soot core preform and closing the central hole at a second temperature higher than the first temperature to form a glass core preform, wherein consolidating and closing comprises sequentially alternating flowing chlorine containing gas into the central hole and reducing the internal pressure of the central hole.

An optical preform manufacturing process is disclosed in which an alkali dopant is deposited between an optical fiber core rod and an optical fiber cladding jacket. Depositing the alkali dopant between the core rod and the cladding jacket permits diffusion of the alkali dopants into the core during fiber draw when the core and the cladding are at their respective transition (or vitrification) temperatures. Introduction of the alkali dopants between the core rod and the cladding jacket also permits decoupling of the alkali doping process from one or more of other optical preform manufacturing processes. The optical preform manufacturing process can also include placing alkali dopants between an optical fiber inner cladding jacket and an optical fiber outer cladding jacket to reduce the glass viscosity during fiber draw.

A method of forming an optical element is provided. The method includes producing silica-based soot particles using chemical vapor deposition, the silica-based soot particles having an average particle size of between about 0.05 m and about 0.25 m. The method also includes forming a soot compact from the silica-based soot particles and doping the soot compact with a halogen in a closed system by contacting the silica-based soot compact with a halogen-containing gas in the closed system at a temperature of less than about 1200 C.