Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration, sintering halogen-doped silica to a closed-pore state, and subjecting the closed-pore silica body to a thermal treatment process and/or a pressure treatment process. The temperature of thermal treatment is sufficiently high to facilitate reaction of unreacted doping precursor trapped in voids or interstices of the glass structure, but is below temperatures conducive to foaming. Core canes or fibers drawn from halogen-doped silica subjected to the thermal treatment and/or pressure treatment show improved optical quality and possess fewer defects. The thermal treatment and/or pressure treatment is particularly advantageous when used for silica doped with high concentrations of halogen.

One of embodiments relates to an optical fiber in which an alkali metal element is efficiently doped to its core to suppress transmission loss from increasing. A mean concentration or a concentration distribution of the alkali metal element is adjusted such that 0.48 or less is obtained as an weighted value obtained by weighting a distribution of field intensity of guided light at a wavelength of 1550 nm, with respect to a radial direction distribution of a ratio I.sub.D2/I.sub.ω3 of an intensity I.sub.D2 of Raman scattering light by a silica three-membered ring structure and an intensity I.sub.ω3 of Raman scattering light by a Si—O stretching vibration, in a cross-sectional region having a diameter of 20 μm.

One of embodiments relates to an optical fiber in which an alkali metal element is efficiently doped to its core to suppress transmission loss from increasing. A mean concentration or a concentration distribution of the alkali metal element is adjusted such that 0.48 or less is obtained as an weighted value obtained by weighting a distribution of field intensity of guided light at a wavelength of 1550 nm, with respect to a radial direction distribution of a ratio I.sub.D2/I.sub.ω3 of an intensity I.sub.D2 of Raman scattering light by a silica three-membered ring structure and an intensity I.sub.ω3 of Raman scattering light by a Si—O stretching vibration, in a cross-sectional region having a diameter of 20 μm.

Multi-core optical fiber ribbons and methods for making multi-core optical fiber ribbons are described herein. In one embodiment, a multi-core optical fiber ribbon includes at least two core members formed from silica-based glass and oriented in parallel with one another in a single plane. Adjacent core members have a center-to-center spacing ≧15 microns and a cross-talk between adjacent core members is ≦−25 dB. In this embodiment each core member is single-moded with an index of refraction n.sub.c, and a core diameter d.sub.c. In an alternative embodiment, each core member is multi-moded and the center-to-center spacing between adjacent core members is ≧25 microns. A single cladding layer is formed from silica-based glass and surrounds and is in direct contact with the core members. The single cladding layer is substantially rectangular in cross section with a thickness ≦400 microns and an index of refraction n.sub.cl<n.sub.c.

A method of producing bi-modal particles includes the steps of igniting a first precursor gas using a primary burner thereby producing a first plurality of particles of a first size, fluidly transporting the first plurality of particles down a particle tube, igniting a second precursor gas using a secondary burner thereby producing a second plurality of particles of a second size, flowing the second plurality of particles into the first plurality of particles, and capturing the first and second plurality of particles.

One aspect relates to a method for the production of synthetic quartz glass. Moreover, one aspect relates to a polyalkylsiloxane compound, which includes certain specifications with respect to chlorine content, metallic impurities content, and residual moisture, as well as the use thereof for the production of synthetic quartz glass. One aspect also relates to a synthetic quartz glass that can be obtained according to the method of one embodiment.

A method for manufacturing an optical fiber preform including a core part and a cladding part is disclosed. The method includes: adding an alkali metal to an inner surface of a silica-based glass pipe; etching the inner surface of the silica-based glass pipe to which the alkali metal is added; making a glass rod by collapsing the silica-based glass pipe after the etching; and making an optical fiber preform using the glass rod. The silica-based glass pipe is heated in the adding such that a surface temperature of the silica-based glass pipe falls within a temperature range of 1500° C. or higher to lower than 2000° C.

A method for manufacturing an optical fiber preform including a core part and a cladding part is disclosed. The method includes: adding an alkali metal to an inner surface of a silica-based glass pipe; etching the inner surface of the silica-based glass pipe to which the alkali metal is added; making a glass rod by collapsing the silica-based glass pipe after the etching; and making an optical fiber preform using the glass rod. The silica-based glass pipe is heated in the adding such that a surface temperature of the silica-based glass pipe falls within a temperature range of 1500° C. or higher to lower than 2000° C.

A method of producing a glass preform including: forming a porous glass soot configured by an inner deposition soot deposited on a start material and an outer deposition soot deposited outside the inner deposition soot; and sintering, after the forming, the porous glass soot while doping with fluorine to form a glass body including an inner glass portion and an outer glass layer. An amount of the fluorine, with which the inner deposition soot is doped at the sintering, is equal to or more than 0 g/cm.sup.3 and less than an amount of the fluorine with which the outer deposition soot is doped.

An optical fiber preform includes: a core formed of silica glass which does not contain Ge, wherein the core has at least one of characteristics in spectrometry of (1) an absorption peak is present at a wavelength of 240 nm to 255 nm, and (2) a wavelength at which an ultraviolet transmittance is 50% or lower is longer than 170 nm.