C03C3/068

GLASS-CERAMICS WITH HIGH ELASTIC MODULUS AND HARDNESS
20230265009 · 2023-08-24 ·

A composition includes 30 mol % to 60 mol % SiO.sub.2; 15 mol % to 40 mol % Al.sub.2O.sub.3; 5 mol % to 25 mol % Y.sub.2O.sub.3; 5 mol % to 15 mol % TiO.sub.2; and 0.1 mol % to 15 mol % RO, such that RO is a sum of MgO, CaO, SrO, and BaO.

SUPPORTING GLASS SUBSTRATE

Suppressing deflection and reducing weight are to be achieved. A supporting glass substrate has a ratio of a Young's modulus (GPa) to a density (g/cm.sup.3) that is 37.0 (GPa.Math.cm.sup.3/g) or more and the ratio has a value larger than a ratio calculation value, the ratio calculation value being a ratio of a Young's modulus (GPa) calculated from a composition to a density (g/cm.sup.3). The ratio calculation value is represented by the following expression: α=2.Math.Σ{(V.sub.i.Math.G.sub.i)/M.sub.i.Math.X.sub.i}, where, in the expression, V.sub.i is a filling parameter of a metal oxide contained in the supporting glass substrate, G.sub.i is a dissociation energy of a metal oxide contained in the supporting glass substrate, M.sub.i is a molecular weight of a metal oxide contained in the supporting glass substrate, and X.sub.i is a molar ratio of a metal oxide contained in the supporting glass substrate.

Aluminoborosilicate glass and preparation method and application thereof

The present invention relates to the field of glass manufacturing, and discloses aluminoborosilicate glass, and a preparation method and an application thereof. Based on the total weight of components in the composition of the glass, the glass comprises: 33-60 wt % SiO.sub.2, 3-10 wt % Al.sub.2O.sub.3, 10-30 wt % B.sub.2O.sub.3, 1-15 wt % ZnO+TiO.sub.2+Sc.sub.2O.sub.3, and 7-27 wt % alkaline-earth oxide RO, wherein RO is at least one of MgO, CaO, SrO and BaO, and 0.001 wt %≤Sc.sub.2O.sub.3≤1 wt%. The aluminoborosilicate glass provided in the present invention has advantages including low density, high index of refraction, low thermal expansion coefficient, high thermostability, high flexibility, and easy bending, etc.

High refractive index optical borate glass

A borate glass includes from 25.0 mol % to 70.0 mol % B.sub.2O.sub.3; from 0.0 mol % to 10.0 mol % SiO.sub.2; from 0.0 mol % to 15.0 mol % Al.sub.2O.sub.3; from 3.0 mol % to 15.0 mol % Nb.sub.2O.sub.5; from 0.0 mol % to 12.0 mol % alkali metal oxides; from 0.0 mol % to 5.0 mol % ZnO; from 0.0 mol % to 8.0 mol % ZrO.sub.2; from 0.0 mol % to 15.0 mol % TiO.sub.2; less than 0.5 mol % Bi.sub.2O.sub.3; and less than 0.5 mol % P.sub.2O.sub.5. The optical borate glass includes a sum of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2 from 35.0 mol % to 76.0 mol %, a sum of CaO+MgO from 0.0 mol % to 35.5 mol %. The borate glass has a refractive index, measured at 587.6 nm, of greater than 1.70, a density of less than 4.50 g/cm.sup.3, and an Abbe number, V.sub.D, from 20.0 to 47.0.

High refractive index optical borate glass

A borate glass includes from 25.0 mol % to 70.0 mol % B.sub.2O.sub.3; from 0.0 mol % to 10.0 mol % SiO.sub.2; from 0.0 mol % to 15.0 mol % Al.sub.2O.sub.3; from 3.0 mol % to 15.0 mol % Nb.sub.2O.sub.5; from 0.0 mol % to 12.0 mol % alkali metal oxides; from 0.0 mol % to 5.0 mol % ZnO; from 0.0 mol % to 8.0 mol % ZrO.sub.2; from 0.0 mol % to 15.0 mol % TiO.sub.2; less than 0.5 mol % Bi.sub.2O.sub.3; and less than 0.5 mol % P.sub.2O.sub.5. The optical borate glass includes a sum of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2 from 35.0 mol % to 76.0 mol %, a sum of CaO+MgO from 0.0 mol % to 35.5 mol %. The borate glass has a refractive index, measured at 587.6 nm, of greater than 1.70, a density of less than 4.50 g/cm.sup.3, and an Abbe number, V.sub.D, from 20.0 to 47.0.

Substrate for flexible device and method for producing the same

A substrate for flexible device. The substrate has a nickel-plated metal sheet having a nickel-plating layer formed on at least one surface of a metal sheet or a nickel-based sheet, and a glass layer of an electrically-insulating layered bismuth-based glass on a surface of the nickel-plating layer or the nickel-based sheet. An oxide layer having a roughened surface is formed on the surface of the nickel-plating layer or the surface of the nickel-based sheet, and the bismuth-based glass contains 70 to 84% by weight of Bi.sub.2O.sub.3, 10 to 12% by weight of ZnO, and 6 to 12% by weight of B.sub.2O.sub.3. Also disclosed is a method for producing the substrate for flexible device, a substrate for an organic EL device, a sheet used as a substrate for flexible device, a method for producing the sheet and a bismuth-based lead-free glass composition.

Substrate for flexible device and method for producing the same

A substrate for flexible device. The substrate has a nickel-plated metal sheet having a nickel-plating layer formed on at least one surface of a metal sheet or a nickel-based sheet, and a glass layer of an electrically-insulating layered bismuth-based glass on a surface of the nickel-plating layer or the nickel-based sheet. An oxide layer having a roughened surface is formed on the surface of the nickel-plating layer or the surface of the nickel-based sheet, and the bismuth-based glass contains 70 to 84% by weight of Bi.sub.2O.sub.3, 10 to 12% by weight of ZnO, and 6 to 12% by weight of B.sub.2O.sub.3. Also disclosed is a method for producing the substrate for flexible device, a substrate for an organic EL device, a sheet used as a substrate for flexible device, a method for producing the sheet and a bismuth-based lead-free glass composition.

OPTICAL GLASS, OPTICAL ELEMENT INCLUDING OPTICAL GLASS, AND OPTICAL APPARATUS

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La.sup.3+ component; more than 0% and up to 75% of a Ga.sup.3+ component; and 5 to 75% of a Nb.sup.5+ component, in which a total amount of the La.sup.3+ component, Ga.sup.3+ component, and Nb.sup.5+ component is 60 to 100%.

OPTICAL GLASS, OPTICAL ELEMENT INCLUDING OPTICAL GLASS, AND OPTICAL APPARATUS

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La.sup.3+ component; more than 0% and up to 75% of a Ga.sup.3+ component; and 5 to 75% of a Nb.sup.5+ component, in which a total amount of the La.sup.3+ component, Ga.sup.3+ component, and Nb.sup.5+ component is 60 to 100%.

Glass with High Refractive Index for Fiber Optic Imaging Element with Medium-Expansion and Fabrication Method Therefor

The present invention discloses a glass with high refractive index for fiber optic imaging elements with medium-expansion and fabrication method therefor, the glass comprising the following components in percentage by weight: SiO.sub.2 5-9%, Al.sub.2O.sub.3 0-1%, B.sub.2O.sub.3 23-28%, CaO 0-3%, BaO 6-12%, La.sub.2O.sub.3 30-34%, Nb.sub.2O.sub.5 4-8%, Ta.sub.2O.sub.5 0-1%, Y.sub.2O.sub.3 0-1%, ZnO 4-9%, TiO.sub.2 4-8%, ZrO.sub.2 4-6%, SnO.sub.2 0-1%. The present invention further provides a fabrication method for the glass with a high refractive index, comprising: putting raw materials quartz sand, aluminum hydroxide, boric acid or boric anhydride, calcium carbonate, barium carbonate or barium nitrate, lanthanum oxide, niobium oxide, tantalum oxide, yttrium oxide, zinc oxide, titanium dioxide, zirconium oxide and stannic oxide, etc. into a platinum crucible according to the requirement of dosing, melting at a high temperature, cooling and fining, leaking and casting to form a glass rod, and then annealing, cooling and chilling the molded glass rod.