Compositions comprising a sol-gel derived glass, the sol-gel derived glass comprising two main components, the main components comprising a borate component and an alkaline earth metal component. Methods of making the compositions comprising combining precursor solutions containing boron ions, with alkaline earth metal ions to form a solution; gelling the solution to form a gel; drying the gel; and calcining the dried gel.

Compositions comprising a sol-gel derived glass, the sol-gel derived glass comprising two main components, the main components comprising a borate component and an alkaline earth metal component. Methods of making the compositions comprising combining precursor solutions containing boron ions, with alkaline earth metal ions to form a solution; gelling the solution to form a gel; drying the gel; and calcining the dried gel.

The present disclosure relates to a method for producing a solid electrolyte comprising lithium-ion conductive glass-ceramics. The method includes the steps of: providing at least one lithium ion conductor having a ceramic phase content and amorphous phase content; providing a powder of said at least one lithium ion conductor, the powder having a polydispersity index between 0.5 and 1.5, more preferably between 0.8 and 1.3, and most preferably between 0.85 and 1.15; and at least one of a) incorporating the powder into a polymer electrolyte or a polyelectrolyte and b) forming an element using the powder.

A borate glass includes from 25.0 mol % to 70.0 mol % B.sub.2O.sub.3; from 0.0 mol % to 10.0 mol % SiO.sub.2; from 0.0 mol % to 15.0 mol % Al.sub.2O.sub.3; from 3.0 mol % to 15.0 mol % Nb.sub.2O.sub.5; from 0.0 mol % to 12.0 mol % alkali metal oxides; from 0.0 mol % to 5.0 mol % ZnO; from 0.0 mol % to 8.0 mol % ZrO.sub.2; from 0.0 mol % to 15.0 mol % TiO.sub.2; less than 0.5 mol % Bi.sub.2O.sub.3; and less than 0.5 mol % P.sub.2O.sub.5. The optical borate glass includes a sum of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2 from 35.0 mol % to 76.0 mol %, a sum of CaO+MgO from 0.0 mol % to 35.5 mol %. The borate glass has a refractive index, measured at 587.6 nm, of greater than 1.70, a density of less than 4.50 g/cm.sup.3, and an Abbe number, V.sub.D, from 20.0 to 47.0.

A borate glass includes from 25.0 mol % to 70.0 mol % B.sub.2O.sub.3; from 0.0 mol % to 10.0 mol % SiO.sub.2; from 0.0 mol % to 15.0 mol % Al.sub.2O.sub.3; from 3.0 mol % to 15.0 mol % Nb.sub.2O.sub.5; from 0.0 mol % to 12.0 mol % alkali metal oxides; from 0.0 mol % to 5.0 mol % ZnO; from 0.0 mol % to 8.0 mol % ZrO.sub.2; from 0.0 mol % to 15.0 mol % TiO.sub.2; less than 0.5 mol % Bi.sub.2O.sub.3; and less than 0.5 mol % P.sub.2O.sub.5. The optical borate glass includes a sum of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2 from 35.0 mol % to 76.0 mol %, a sum of CaO+MgO from 0.0 mol % to 35.5 mol %. The borate glass has a refractive index, measured at 587.6 nm, of greater than 1.70, a density of less than 4.50 g/cm.sup.3, and an Abbe number, V.sub.D, from 20.0 to 47.0.

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La.sup.3+ component; more than 0% and up to 75% of a Ga.sup.3+ component; and 5 to 75% of a Nb.sup.5+ component, in which a total amount of the La.sup.3+ component, Ga.sup.3+ component, and Nb.sup.5+ component is 60 to 100%.

Provided is optical glass containing, in terms of mol % of cations: 10 to 60% of a La.sup.3+ component; more than 0% and up to 75% of a Ga.sup.3+ component; and 5 to 75% of a Nb.sup.5+ component, in which a total amount of the La.sup.3+ component, Ga.sup.3+ component, and Nb.sup.5+ component is 60 to 100%.

A joint joins an alloy member to a ceramic member via a glass joining agent, which is joined to the alloy member by a material bonded joint and to the ceramic member by a further material bonded joint. The glass joining agent is made of a glass having a melting point below 800° C.; a coefficient of thermal expansion of at least 9-10.sup.−6 K.sup.−1 and a bismuth content of at least 10%. The alloy member has a coefficient of thermal expansion of at least 9-10.sup.−6 K.sup.−1. The ceramic member has a maximum coefficient of thermal expansion of 8-10.sup.−6 K.sup.−1. The material bonded joint defines a mixing region that is a partial region of the ceramic member, and the bismuth content in the mixing region is higher than that of the ceramic member outside the mixing region.

A glass article contains: in mol %, more than 0% to 70% of La.sub.2O.sub.3, 0% to 80% of B.sub.2O.sub.3, 0% to 40% of SiO.sub.2, 0% to 80% of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2, 0% to 85% of Gd.sub.2O.sub.3+Ga.sub.2O.sub.3+Y.sub.2O.sub.3+Yb.sub.2O.sub.3+ZrO.sub.2+TiO.sub.2+Nb.sub.2O.sub.5+Ta.sub.2O.sub.5+WO.sub.3, 0% to 15% of MgO+CaO+SrO+BaO, 0% to 35% of ZnO, and more than 0% to 5% of CuO.

A glass article contains: in mol %, more than 0% to 70% of La.sub.2O.sub.3, 0% to 80% of B.sub.2O.sub.3, 0% to 40% of SiO.sub.2, 0% to 80% of B.sub.2O.sub.3+Al.sub.2O.sub.3+SiO.sub.2, 0% to 85% of Gd.sub.2O.sub.3+Ga.sub.2O.sub.3+Y.sub.2O.sub.3+Yb.sub.2O.sub.3+ZrO.sub.2+TiO.sub.2+Nb.sub.2O.sub.5+Ta.sub.2O.sub.5+WO.sub.3, 0% to 15% of MgO+CaO+SrO+BaO, 0% to 35% of ZnO, and more than 0% to 5% of CuO.