A manufacturing method of micro-nano structure antireflective coating layer and a display apparatus thereof are described. The method includes providing a substrate, forming a silicon oxide layer on the substrate, forming a graphene layer with a hexagonal honeycomb lattice on the silicon oxide layer, and forming a bottom surface of the antireflective coating layer in the nucleation points by serving the graphene layer as a growing base layer, wherein a diffusion length and an atomic mass of diffusion atoms of the antireflective coating layer are decreased with time by a gradient growing manner to form a upper surface of the antireflective coating layer.

In certain example embodiments, a coated article includes a carbon-doped zirconium based layer before heat treatment (HT). The coated article is heat treated sufficiently to cause the carbon-doped zirconium oxide and/or nitride based layer to result in a carbon-doped zirconium oxide based layer that is scratch resistant and/or chemically durable. The doping of the layer with carbon (C) has been found to improve wear resistance.

A coated glazing includes a transparent glass substrate, and a coating located on the glass substrate. The coating is provided with at least the following layers in sequence starting from the glass substrate: a first layer having a refractive index of more than 1.6, an optional second layer having a refractive index that is less than the refractive index of the first layer, a third layer based on tin dioxide doped with antimony, niobium and/or neodymium, and a fourth layer based on titanium dioxide, wherein the fourth layer is photocatalytic.

Provided is an antireflection film having excellent abrasion resistance. In the antireflection film, a hydrogenated carbon film as a first layer is formed on a surface of an optical substrate. A MgF.sub.2 film as a second layer having a lower refractive index than the first layer is formed on the first layer. Likewise, a third layer formed of the hydrogenated carbon film, a fourth layer formed of the MgF.sub.2 film, and a fifth layer formed of the hydrogenated carbon film are formed. During the formation of the hydrogenated carbon film, a mixed gas of argon and hydrogen is supplied to a vacuum chamber such that some of CC bonds in the film are replaced with CH bonds. Due to the CH bonds, an antireflection film having excellent abrasion resistance and adhesiveness and having a low refractive index can be obtained.

Absorbing layers of a low-emissivity (low-E) coating are designed to cause the coating to have a reduced film side reflectance which is advantageous for aesthetic purposes. In certain embodiments, the absorbing layers are metallic or substantially metallic (e.g., NiCr or NiCrN.sub.x) and are positioned in order to reduce or prevent oxidation of the absorbing layers during optional heat treatment (e.g., thermal tempering, heat bending, and/or heat strengthening). Coated articles according to certain example embodiments of this invention may be used in the context of insulating glass (IG) window units, other types of windows, etc.

Provided is an antireflection film having excellent abrasion resistance.

In the antireflection film, a hydrogenated carbon film as a first layer is formed on a surface of an optical substrate. A MgF.sub.2 film as a second layer having a lower refractive index than the first layer is formed on the first layer. Likewise, a third layer formed of the hydrogenated carbon film, a fourth layer formed of the MgF.sub.2 film, and a fifth layer formed of the hydrogenated carbon film are formed. During the formation of the hydrogenated carbon film, a mixed gas of argon and hydrogen is supplied to a vacuum chamber such that some of CC bonds in the film are replaced with CH bonds. Due to the CH bonds, an antireflection film having excellent abrasion resistance and adhesiveness and having a low refractive index can be obtained.

Glass (1) for vehicles includes a light blocking region (A2) in which a far-infrared ray transmission region (B) provided with an opening and a far-infrared ray transmission member arranged in the opening, and a visible light transmission region (C) transmitting visible light are formed. The opening is formed between an upper edge part (1a) of the glass (1) and a first position (P1) in a first direction from the upper edge part (1a) toward a lower edge part (1b) of the glass (1), the first position (P1) is a position at which a distance from the upper edge part (1a) is 30% of a length from the upper edge part (1a) to the lower edge part (1b), and between a second position (P2) and a third position (P3) in a second direction from a side edge part (1c) toward a side edge part (1d) of the glass (1) for vehicles. A length (L2a) in the second direction from the second position (P2) to the third position (P3) is 55% of a length (L2) from the side edge part (1c) to the side edge part (1d), and a length of the longest straight line among straight lines connecting optional two points within a surface on a vehicle exterior side is equal to or smaller than 80 mm.

A method of making a heat treated (HT) or heat treatable coated article. A method of making a coated article includes a step of heat treating a glass substrate coated with at least layer of or including carbon (e.g., diamond-like carbon (DLC)) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer of or including zinc oxide. Treating the zinc oxide inclusive release layer with plasma including oxygen (e.g., via ion beam treatment) improves thermal stability and/or quality of the product. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be entirely or partially removed.

A method of forming a diamond coated glass structure includes providing a glass substrate having a first and a second side. The second side can be covered in whole or in part with a coating capable of reducing ion exchange. The substrate can be bent to form the first side as convex and the second side as concave. A CVD diamond layer can be deposited on the convex first side of the substrate and at least a portion of the substrate chemically modified through ion exchange. After removal of the stress, the stresses due to applied diamond layers and chemical modification through ion exchange can balance, providing a substantially flat diamond coated glass structure.

In this invention, processes which can be used to achieve stable doped carbon nanotubes are disclosed. Preferred CNT structures and morphologies for achieving maximum doping effects are also described. Dopant formulations and methods for achieving doping of a broad distribution of tube types are also described.