An additive for increasing an early activity index of nickel slag and a preparation method thereof, belonging to the field of additive technologies, are provided. The preparation method includes: successively adding maleic anhydride and triethanolamine to a reactor; setting the heating temperature to 50° C. for reaction, where a large amount of heat is released during the reaction; when the reaction temperature decreases to 60° C. after heat is released in the reaction, allowing triethanolamine maleate to react with a solution of bromine in carbon tetrachloride; adding water to the mixture, where the weight percentage content of the added water is 60%; separating and removing carbon tetrachloride from water; and conducting uniform stirring to obtain the additive. A molar ratio of the maleic anhydride, the triethanolamine, and bromine is (0.2-1):1:(0.2-1), and a molar ratio of the maleic anhydride to the bromine is 1:1.

The present invention discloses a copper slag-fly ash geopolymer, a preparation method thereof, and use thereof, belongs to the technical field of geopolymer. The preparation method of copper-fly ash geopolymer provided by the application comprises the steps of: mixing the copper slag, fly ash and alkali activator solution, obtaining a slurry; proceeding polymerization to the slurry, obtaining a copper slag-fly ash geopolymer. The fly ash and copper slag are used as raw materials in the application, which greatly improve the utilization rate of the industrial waste residue. The advantages line in that no need for additional addition of inorganic reinforcing filler, low production cost, simple operation and competency for industrial production. Moreover, the copper slag-fly ash geopolymer has good compressive strength, and can solidify the heavy metal ions in copper slag at the same time, thus reducing the environmental pollution.

The present invention discloses a copper slag-fly ash geopolymer, a preparation method thereof, and use thereof, belongs to the technical field of geopolymer. The preparation method of copper-fly ash geopolymer provided by the application comprises the steps of: mixing the copper slag, fly ash and alkali activator solution, obtaining a slurry; proceeding polymerization to the slurry, obtaining a copper slag-fly ash geopolymer. The fly ash and copper slag are used as raw materials in the application, which greatly improve the utilization rate of the industrial waste residue. The advantages line in that no need for additional addition of inorganic reinforcing filler, low production cost, simple operation and competency for industrial production. Moreover, the copper slag-fly ash geopolymer has good compressive strength, and can solidify the heavy metal ions in copper slag at the same time, thus reducing the environmental pollution.

Mortar with small autogenous shrinkage strain and a method for producing the same are provided.

Mortar has binder and fine aggregate, wherein the binder includes cement and fine mineral powder, and the mortar is formed by being mixed with water. The fine aggregate is air granulated ferronickel slag, and weight ratio of water to a combination of the binder and the fine aggregate is 7.0% or more and 9.0% or less. Such mortar can be produced by mixing binder, fine aggregate and water.

Mortar with small autogenous shrinkage strain and a method for producing the same are provided.

Mortar has binder and fine aggregate, wherein the binder includes cement and fine mineral powder, and the mortar is formed by being mixed with water. The fine aggregate is air granulated ferronickel slag, and weight ratio of water to a combination of the binder and the fine aggregate is 7.0% or more and 9.0% or less. Such mortar can be produced by mixing binder, fine aggregate and water.

An additive for increasing an early activity index of nickel slag and a preparation method thereof, belonging to the field of additive technologies, are provided. The preparation method includes: successively adding maleic anhydride and triethanolamine to a reactor; setting the heating temperature to 50 C. for reaction, where a large amount of heat is released during the reaction; when the reaction temperature decreases to 60 C. after heat is released in the reaction, allowing triethanolamine maleate to react with a solution of bromine in carbon tetrachloride; adding water to the mixture, where the weight percentage content of the added water is 60%; separating and removing carbon tetrachloride from water; and conducting uniform stirring to obtain the additive. A molar ratio of the maleic anhydride, the triethanolamine, and bromine is (0.2-1):1:(0.2-1), and a molar ratio of the maleic anhydride to the bromine is 1:1.

An additive for increasing an early activity index of nickel slag and a preparation method thereof, belonging to the field of additive technologies, are provided. The preparation method includes: successively adding maleic anhydride and triethanolamine to a reactor; setting the heating temperature to 50 C. for reaction, where a large amount of heat is released during the reaction; when the reaction temperature decreases to 60 C. after heat is released in the reaction, allowing triethanolamine maleate to react with a solution of bromine in carbon tetrachloride; adding water to the mixture, where the weight percentage content of the added water is 60%; separating and removing carbon tetrachloride from water; and conducting uniform stirring to obtain the additive. A molar ratio of the maleic anhydride, the triethanolamine, and bromine is (0.2-1):1:(0.2-1), and a molar ratio of the maleic anhydride to the bromine is 1:1.

The present invention provides an apparatus and a method for producing cement through flue gas desulfurization, and specifically provides an apparatus and a method for simultaneously producing magnesium sulfate cement during a magnesium oxide based flue gas desulfurization process. The apparatus of the present invention includes a flue gas desulfurization equipment, a concentration equipment, a crystallization equipment, a centrifugation equipment, a drying equipment, a waste ash supplying equipment, a slag material supplying equipment, a mixing equipment, etc. By adopting the apparatus and method of the present invention, the problems in the present conventional cement production such as high energy cost, severe damage to the environment and so on can be solved, and the problems like high production cost of ordinary magnesium sulfate cement and high transportation cost of supplies thereby causing incapability in a large scale market spreading and application can also be solved.

The present invention provides an apparatus and a method for producing cement through flue gas desulfurization, and specifically provides an apparatus and a method for simultaneously producing magnesium sulfate cement during a magnesium oxide based flue gas desulfurization process. The apparatus of the present invention includes a flue gas desulfurization equipment, a concentration equipment, a crystallization equipment, a centrifugation equipment, a drying equipment, a waste ash supplying equipment, a slag material supplying equipment, a mixing equipment, etc. By adopting the apparatus and method of the present invention, the problems in the present conventional cement production such as high energy cost, severe damage to the environment and so on can be solved, and the problems like high production cost of ordinary magnesium sulfate cement and high transportation cost of supplies thereby causing incapability in a large scale market spreading and application can also be solved.

Provided is a concrete composition, including: blast furnace slag; at least any one of expansive additive and cement; and water, wherein a unit water content of the water is 130 kg/m.sup.3 or less; wherein a content of the cement is 22% by mass or less relative to the blast furnace slag, and wherein a slump flow value of the concrete composition is 40 cm or greater.